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MPB機構とイオンオフセンター機構を同時に用いた医療用高性能圧電材料の創成

Research Project

Project/Area Number 19F19065
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section外国
Review Section Basic Section 26020:Inorganic materials and properties-related
Research InstitutionUniversity of Yamanashi

Principal Investigator

和田 智志  山梨大学, 大学院総合研究部, 教授 (60240545)

Co-Investigator(Kenkyū-buntansha) KIM SANGWOOK  山梨大学, 大学院総合研究部, 外国人特別研究員
Project Period (FY) 2019-04-25 – 2020-03-31
Project Status Discontinued (Fiscal Year 2019)
Budget Amount *help
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2019: ¥1,200,000 (Direct Cost: ¥1,200,000)
KeywordsMPB behaviors / structural engineering
Outline of Research at the Start

I founded that Bi ion off-centering was only associated in the material softening in the BF-BT ceramics. On base on this idea, if Ba ions are doped in the MPB composition of PZT ceramics, the piezoelectric constant enhanced with low dielectric constant by Pb ion off-centering can be obtained in the Ba doped PZT (PZT-Ba) ceramics by structural engineering (MPB + Pb ion off-centering). The material softening behaviors will be investigated by electrical properties. The Pb ion off-centering at 950 K and 300 K will be identified using structure refinement/MEM method.

Outline of Annual Research Achievements

The purpose of research project is to enhance piezoelectric property by the structural engineering on the basis of mechanism of material softening with ion off-centering and morpotropic phase boundary (MPB).
This research project was conducted by Prof. Satoshi Wada and Dr. Sangwook Kim in cooperation with each other in their specialized fields. This year, the research was conducted to enhance of the kp in PZT ceramics through structural engineering, and confirming its crystal structure to achieve the research objectives. The existence of MPB in the Ba and La co-doped PZT ceramics was confirmed by synchrotron radiation X-ray diffraction, which was measured in the SPring-8. Besides, it was confirmed that structure engineering (MPB + ion’s off-centering) is effective in improving the electrical properties by showing a significantly higher kp value of structure engineered ceramics.

Research Progress Status

令和元年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和元年度が最終年度であるため、記入しない。

Report

(1 results)
  • 2019 Annual Research Report
  • Research Products

    (3 results)

All 2019

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (2 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Thermal annealing induced recovery of damaged surface layer for enhanced ferroelectricity in Bi-based ceramics2019

    • Author(s)
      Nam Hyunwook、Kim Sangwook、Khanal Gopal Prasad、Fujii Ichiro、Ueno Shintaro、Wada Satoshi
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 58 Issue: SL Pages: SLLD04-SLLD04

    • DOI

      10.7567/1347-4065/ab37b5

    • NAID

      210000156856

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Role of Bi ion off-centering in Bi-based lead-free piezoelectric ceramics2019

    • Author(s)
      Sangwook Kim
    • Organizer
      2019 IEEE International Symposium on Applications of Ferroelectrics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Proposal of material design direction using material softening by ion’s off-centering for high performance piezoelectric ceramics2019

    • Author(s)
      Sangwook Kim
    • Organizer
      The 5th International Conference on Advanced Electromaterials
    • Related Report
      2019 Annual Research Report

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Published: 2019-05-29   Modified: 2024-03-26  

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