| Project/Area Number |
19F19074
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| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 外国 |
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| Review Section |
Basic Section 26020:Inorganic materials and properties-related
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| Research Institution | National Institute for Materials Science |
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Principal Investigator |
目 義雄 国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, NIMS招聘研究員 (00354217)
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| Co-Investigator(Kenkyū-buntansha) |
JIANG BO 国立研究開発法人物質・材料研究機構, 機能性材料研究拠点, 外国人特別研究員
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| Project Period (FY) |
2019-04-25 – 2021-03-31
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| Project Status |
Completed (Fiscal Year 2020)
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| Budget Amount *help |
¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2020: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2019: ¥1,200,000 (Direct Cost: ¥1,200,000)
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| Keywords | mesoporous materials / nanoporous metal / membrane / electrocatalyst |
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| Outline of Research at the Start |
This project aims to create new avenues for large-scale and well-controlled synthesis of novel hierarchical nanoporous metals-based architectures and develop new conductive "membranes" for electrocatalysts. Several novel synthetic concepts will be proposed, and optimization of the catalytic activity will be accomplished by tuning the dimension, morphology and porous size in the architectures.
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| Outline of Annual Research Achievements |
We develop a sophisticated and controllable dual-reducing agent strategy to synthesize the mesoporous nickel–cobalt boron (NiCoB) amorphous alloy spheres (AASs) with adjustable compositions by using a soft template-directed assembly approach. The selective use of tetrabutylphosphonium bromide (Bu4PBr) is beneficial to generate well-defined mesopores. Our meso-Ni10.0Co74.5B15.5 AASs generate the highest catalytic performance for the hydrolytic dehydrogenation of ammonia borane (AB). Its high performance is attributed to the combination of optimal synergistic effects between Ni, Co, and B as well as the high surface area and the good mass transport efficiency due to the open mesopores.
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| Research Progress Status |
令和2年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
令和2年度が最終年度であるため、記入しない。
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