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配向セルロースナノファイバーを内包する伸縮性の高引張強度エアロゲル

Research Project

Project/Area Number 19F19100
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section外国
Review Section Basic Section 40020:Wood science-related
Research InstitutionThe University of Tokyo

Principal Investigator

齋藤 継之  東京大学, 大学院農学生命科学研究科(農学部), 准教授 (90533993)

Co-Investigator(Kenkyū-buntansha) SUN ZHIFANG  東京大学, 農学生命科学研究科, 外国人特別研究員
Project Period (FY) 2019-04-25 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥2,400,000 (Direct Cost: ¥2,400,000)
Fiscal Year 2020: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2019: ¥1,200,000 (Direct Cost: ¥1,200,000)
Keywordsセルロースナノファイバー / エアロゲル / 異方性 / cellulose nanofibril / condensation / aerogel / tensile strength / orientation
Outline of Research at the Start

We envisage that, CNFs can be unidirectionally oriented using our established methods. A dispersion of oriented CNFs can be fixed via cross-linking the interfacial hydroxyl groups with divalent molecules, silica matrix or resorcinol-formaldehyde network. Thus obtained aerogels exhibit typically high porosity and excellent thermal insulating properties. In addition, strong interfacial interactions between cross-linked matrix and well-oriented CNFs render the resultant aerogels high tensile strength, thus addressing a fundamental and ground challenge in the field of aerogels.

Outline of Annual Research Achievements

We have discovered a new, facile, scalable and controllable method to get cellulose nanofibril colloids at any concentrations, using controlled condensation method. All of the condensed CNF materials are highly homogeneous. Further gelation of the condensed CNF hydrogels by protonation (H+) or coordination (Al3+) affords a series of transparent and strong hydrogels with water content of 70-90%, which exhibit tensile strength and modulus more than 9 MPa and 480 MPa, respectively. The water content, strength and modulus are very close or even superior to those of muscles and cartilages and would very promising in the biomedical applications. When dried by supercritical method, we obtained a series of CNF aerogels which is stretchable over 20%, with tensile strength and modulus reach 8 MPa and 100 MPa, respectively, yet still possess very low thermal conductivity at 19.3 mW/mK. Our aerogels, both strong and super-insulating, set a new region in the Ashby plots regarding strength and thermal conductivity.
We have submitted a patent regarding this project. The related manuscript is now under construction, and will submit to several major journals in materials science.

Research Progress Status

令和2年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和2年度が最終年度であるため、記入しない。

Report

(2 results)
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (3 results)

All 2021 2019

All Presentation (2 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Presentation] Controlled Condensation of Biopolymer Nanofibrils for High-Strength Soft Materials2019

    • Author(s)
      Zhifang Sun
    • Organizer
      The 2nd Riken-UT soft matter joint seminar
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Transparent and Superhydrophobic Aerogels via Surface Engineering of TEMPO-Oxidized Cellulose Nanofibers2019

    • Author(s)
      Zhifang Sun, Kazuho Daicho, Wataru Sakuma, Tsuguyuki Saito
    • Organizer
      The 1st National Cellulose Conference
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Patent(Industrial Property Rights)] 異方性を有する高濃度ゲル又は多孔性材料の製造方法2021

    • Inventor(s)
      齋藤継之、孫志方、大長一帆、藤澤秀次、石田康博
    • Industrial Property Rights Holder
      齋藤継之、孫志方、大長一帆、藤澤秀次、石田康博
    • Industrial Property Rights Type
      特許
    • Filing Date
      2021
    • Related Report
      2020 Annual Research Report

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Published: 2019-05-29   Modified: 2024-03-26  

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