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Mg-希土類系合金の微細組織と力学特性

Research Project

Project/Area Number 19F19775
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section外国
Review Section Basic Section 26040:Structural materials and functional materials-related
Research InstitutionThe University of Tokyo

Principal Investigator

阿部 英司  東京大学, 大学院工学系研究科(工学部), 教授 (70354222)

Co-Investigator(Kenkyū-buntansha) GUAN KAI  東京大学, 工学(系)研究科(研究院), 外国人特別研究員
Project Period (FY) 2019-11-08 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2021: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 2020: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 2019: ¥600,000 (Direct Cost: ¥600,000)
KeywordsMg合金 / 電子顕微鏡 / 微細組織 / 元素偏析 / 溶質クラスタリング
Outline of Research at the Start

The objective is to develop ultra-high strength Mg alloys through the co-additions of RE elements in them. In addition, the mechanism of co-addition responsible for influencing the mechanical properties of ultra-high strength Mg-RE-based alloys will be clarified.

Outline of Annual Research Achievements

Microstructures of several rare-earth (RE)-containing Mg alloys have been investigated systematically from micron-scale to atomic scale using electron microscopy. The major results focusing on unique long-period stacking/order (LPSO) atructures are summarized as follows.
1) Short-range order (SRO) solute clusters in the LPSO phases with an intrinsic-I (I1) type stacking faults (SFs), which have been uniquely formed in Mg-Co-Y alloys, are investigated. The Co3Y5 SRO cluster model embedded across the I1-type SFs has been successfully constructed to satisfy the observed electron diffraction, STEM images and computed energetic stabilities. The optimized Co3Y5 cluster configurations appear to be significantly deviated from the host Mg atom positions and consequently provide a significant gain for the energetic stability of the I1-type LPSO phases.
2)In a MgHo2.0Cu0.4Zr0.1 alloy, it is found that 18R, 14H and 24R LPSO phases coexist with fully coherent interfaces along step-like composition gradient in a blocky intermetallic compound distributed at grain boundaries. Importantly, the estimated chemical compositions of solute-enriched stacking-fault (SESF) in all LPSO variants are almost identical with the ideal SESF composition of 9M in-plane order, regardless of the type of LPSO phases. The results support the viewpoint that the robust L12-type SRO TM6RE8 clusters play an important role in governing LPSO phase formation.

Research Progress Status

令和3年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和3年度が最終年度であるため、記入しない。

Report

(3 results)
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (8 results)

All 2022 2021 2020

All Journal Article (3 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 3 results,  Open Access: 3 results) Presentation (5 results)

  • [Journal Article] Short-range order clusters in the long-period stacking/order phases with an intrinsic-I type stacking fault in Mg-Co-Y alloys2022

    • Author(s)
      Guan Kai、Egami Mariko、Egusa Daisuke、Kimizuka Hajime、Yamasaki Michiaki、Kawamura Yoshihito、Abe Eiji
    • Journal Title

      Scripta Materialia

      Volume: 207 Pages: 114282-114282

    • DOI

      10.1016/j.scriptamat.2021.114282

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Microstructures and mechanical properties of as-cast Mg-Sm-Zn-Zr alloys with varying Gd contents2021

    • Author(s)
      K. Guan, D. Egusa, E. Abe, J. Zhang, X. Qiu, Q. Yang, J. Meng
    • Journal Title

      Journal of Magnesium and Alloys

      Volume: - Issue: 5 Pages: 1220-1234

    • DOI

      10.1016/j.jma.2021.09.013

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Dilute long period stacking/order (LPSO)-variant phases along the composition gradient in a Mg-Ho-Cu alloy2021

    • Author(s)
      K. Guan, D. Egusa, E. Abe,
    • Journal Title

      Journal of Magnesium and Alloys

      Volume: - Issue: 6 Pages: 1573-1580

    • DOI

      10.1016/j.jma.2021.11.007

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Atomic-resolution observations of LPSO variants along the composition gradient in Mg-Ho-Cu alloys2021

    • Author(s)
      K. Guan, D. Egusa, Q. Yang and E. Abe
    • Organizer
      軽金属学会 第140回春期大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Microstructure evolution of Mg-Sm-Gd based alloys with ultra-high hardness2021

    • Author(s)
      K. Guan, D. Egusa, Q. Yang and E. Abe
    • Organizer
      日本金属学会2021年秋期第169回講演大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Atomic-resolution characterizations of deformation twins in Mg-Gd alloys2021

    • Author(s)
      K. Guan, D. Egusa, G. Garces, E. Abe
    • Organizer
      The 12th International Conference on Magnesium Alloys and their Applications (Mg2021)
    • Related Report
      2021 Annual Research Report
  • [Presentation] Microstructure of Deformation Twins in Mg-Gd Alloys2020

    • Author(s)
      K. Guan,D. Egusa,G. Garces,E. Abe
    • Organizer
      日本金属学会2020年秋期(第167回)講演大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Microstructures of twin-deformed Mg-Gd alloys with PLC effects2020

    • Author(s)
      K. Guan,D. Egusa,G. Garces,E. Abe
    • Organizer
      軽金属学会第139回秋期大会
    • Related Report
      2020 Annual Research Report

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Published: 2019-11-29   Modified: 2024-03-26  

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