| Budget Amount *help |
¥45,500,000 (Direct Cost: ¥35,000,000、Indirect Cost: ¥10,500,000)
Fiscal Year 2022: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
Fiscal Year 2021: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
Fiscal Year 2020: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
Fiscal Year 2019: ¥14,820,000 (Direct Cost: ¥11,400,000、Indirect Cost: ¥3,420,000)
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| Outline of Final Research Achievements |
In this study, based on the structures of the active centers of enzymes and the ideas obtained from the researches conducted by our group, fundamental research on the development of molecular catalysts was promoted with the aim of creating innovative catalysts for small molecule conversion reactions involving multi-electron transfer. Specifically, we synthesized and structurally characterized a series of pentanuclear cluster complexes with "multi-electron transfer ability" and "bond rearrangement ability," and evaluated their electronic states and catalytic ability for small-molecule conversion reactions. As a result, it was found that the electron transfer ability of the pentanuclear cluster complexes varies depending on the type of metal ions present in the complexes, and that some pentanuclear cluster complexes are active in various small-molecule conversion reactions.
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