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Investigation and modeling of adsorption-desorption kinetics of surfactants at interface with deformation and oscillation

Research Project

Project/Area Number 19H02067
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 19010:Fluid engineering-related
Research InstitutionKansai University

Principal Investigator

Hosokawa Shigeo  関西大学, 社会安全学部, 教授 (10252793)

Co-Investigator(Kenkyū-buntansha) 冨山 明男  神戸大学, 工学研究科, 教授 (30211402)
林 公祐  神戸大学, 工学研究科, 准教授 (60455152)
Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2021: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2020: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Fiscal Year 2019: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Keywords流体工学 / 混相流 / 界面 / 界面活性剤 / 吸着・脱離 / 流体計測 / 流体力 / 時空間フィルタ流速計 / 吸着 / 液滴 / 時空感フィルタ流速計
Outline of Research at the Start

多くの工業分野,自然界において気泡や液滴を含む流れが見られるが,界面活性剤などの汚染物質が含まれる場合,気泡/液滴と周囲流体間の輸送現象が清浄系と異なることが知られている.しかし,変形しながら流動する界面への界面活性剤の吸着/脱離に関する知見は少なく,数値予測においても未検証のまま静的な系における吸脱着モデルが利用されている.本研究では,変形・変動する流動界面に適用できる高精度速度分布計測に基づく界面上界面活性剤濃度評価手法を開発数るとともに,本手法を用いて流動する界面への界面活性剤の吸着/脱離特性に及ぼす界面変形・変動を明らかするとともに,数値計算に利用できるモデルの開発を目指す.

Outline of Final Research Achievements

Bubbles and drops in a contaminated system can be found in many industrial applications and natural phenomena. The contaminants such as surface-active agents (surfactant) adsorb on the interface of bubbles or drops and change mass, momentum, and heat transfer characteristics. Although there are lots of knowledge and models of the adsorption-desorption kinetics for quiescent systems, those have rarely been validated for a moving interface due to the lack of experimental data. Hence, we experimentally investigated local viscous stress, pressure, and surfactant concentration at the moving interface of drops falling in a stagnant liquid containing surfactant based on the velocity distribution measured by spatiotemporal filter velocimetry (SFV). The SFV was extended to generalized coordinate systems to evaluate adsorption characteristics of deformed drops. We discussed the adsorption-desorption kinetics and the influence of the adsorption on the fluid force acting on the drop.

Academic Significance and Societal Importance of the Research Achievements

本研究の成果は、変形を伴う界面における界面活性剤濃度および界面に作用する粘性応力と圧力を評価できる計測手法を提供するとともに、実験データがほとんどなかった流動界面への界面活性剤の吸着・脱着特性に関する定量的データを提供するものであり、汚染系気泡・液滴の数値計算・モデルの検証および流動界面への吸着・脱離現象の解明に有益である。また、流動界面に対する吸着・脱離特性は従来の静的モデルではなく一般化Frumkin-Levichモデルにより概ね表現できる結果は数値予測精度向上に重要な知見である。さらに、本研究で開発した界面近傍速度分布および局所流体力測定法は、物体周囲流動の分析にも貢献するものである。

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (13 results)

All 2022 2021 2020 2019 Other

All Int'l Joint Research (1 results) Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results) Book (1 results)

  • [Int'l Joint Research] University of Sao Paulo(ブラジル)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Single Contaminated Drops Falling through Stagnant Liquid at Low Reynolds Numbers2022

    • Author(s)
      Hayashi Kosuke、Motoki Yuya、van der Linden Matheus J. A.、Deen Niels G.、Hosokawa Shigeo、Tomiyama Akio
    • Journal Title

      Fluids

      Volume: 7 Issue: 2 Pages: 55-55

    • DOI

      10.3390/fluids7020055

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 光学的流速計測と 計測結果からの流体情報抽出2022

    • Author(s)
      細川茂雄
    • Organizer
      日本機械学会RC286研究分科会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 汚染系単一球形液滴の数値計算に関する研究2021

    • Author(s)
      元木佑哉,林公祐,細川茂雄,冨山明男
    • Organizer
      日本流体力学会年会2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] 物質移動によるマイクロバブルの気泡径変化2021

    • Author(s)
      細川茂雄
    • Organizer
      京都大学微細気泡研究会ワークショップ
    • Related Report
      2021 Annual Research Report
  • [Presentation] 時空間フィルタ流速計による抗力評価の試み2020

    • Author(s)
      細川茂雄
    • Organizer
      日本機械学会RC277研究分科会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Spatiotemporal Filter Velocimetry, Fundamentals and Applications2019

    • Author(s)
      Shigeo Hosokawa
    • Organizer
      5th Multiphase Flow Journeys
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Optical Measurements for Validation of Numerical Simulation of Two-Phase Flow2019

    • Author(s)
      Shigeo Hosokawa
    • Organizer
      4th Workshop on Advances in CFD, LB and MD Modeling of Capillary Two-Phase Flows and Experimental Validation
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Viscous Stress and Pressure Acting on Interface of Contaminated Drop2019

    • Author(s)
      Shigeo Hosokawa, Gaku Shigekane, Kosuke Hayashi, Akio Tomiyama
    • Organizer
      10th International Conference on Multiphase Flow
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Evaluation of Drag Force Acting on a Contaminated Single Drop Based on Velocity Distribution2019

    • Author(s)
      Gaku Shigekane, Shigeo Hosokawa, Kosuke Hayashi, Akio Tomiyama
    • Organizer
      ASME - JSME - KSME Joint Fluids Engineering Conference 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Application of Spatiotemporal Filter Velocimetry to Evaluation of Drag Force Acting on Single Drop2019

    • Author(s)
      Gaku Shigekane, Shigeo Hosokawa, Kosuke Hayashi, Akio Tomiyama
    • Organizer
      The 11th International Symposium on Measurement Techniques for Multiphase Flow
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 速度分布計測に基づく液滴に作用する抗力の評価2019

    • Author(s)
      細川茂雄, 重兼楽, 林公祐, 冨山明男
    • Organizer
      理論応用力学講演会
    • Related Report
      2019 Annual Research Report
  • [Book] 技術資料 流体計測法(分担執筆:応用編第1章 1.7.2)2022

    • Author(s)
      細川茂雄
    • Total Pages
      6
    • Publisher
      丸善
    • ISBN
      9784888983266
    • Related Report
      2021 Annual Research Report

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Published: 2019-04-18   Modified: 2023-01-30  

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