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Ball SAW trace moisture inverse gas chromatography for evaluation of highly pure stainless steel tubes

Research Project

Project/Area Number 19H02148
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 21030:Measurement engineering-related
Research InstitutionTohoku University

Principal Investigator

Tsuji Toshihiro  東北大学, 工学研究科, 助教 (70374965)

Project Period (FY) 2019-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Fiscal Year 2022: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2021: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2020: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2019: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Keywords弾性表面波センサ / アンダーサンプリング / 微量水分 / ステンレス配管 / 内面処理 / ガスクロマトグラフィ / ステンレス鋼 / 吸脱着特性
Outline of Research at the Start

本研究は、日本が世界をリードする革新的技術(青色発光ダイオード、有機EL、リチウムイオン電池など)に関する産業において重要なステンレス鋼配管の水分吸脱着特性の解明に着目し、高再現性の微量水分発生法と、弾性表面波(SAW)の超長距離伝搬を利用して微量水分を高感度かつ高速に計測可能なボールSAWセンサを組み合わせてインバースガスクロマトグラフィ(IGC)を構成し、配管材料システムの曲げ・溶接による初期吸脱着特性変化を定量化することにより、世界初の実用配管システム評価法の開発を行う研究である。

Outline of Final Research Achievements

Stainless steel tubes for highly pure gases are fundamental parts for controlling trace moisture in bulk gases in the field of innovative semiconductor devices and rechargeable batteries. An inverse gas chromatography (IGC) using a standard trace moisture as a probe gas and a ball SAW trace-moisture sensor as a detector was developed to reveal the affection by tubing techniques such as bending and welding. Rapid measurement method of IGC chromatogram was developed by shortening recording time less than 1 s and was applied for the measurement of the passing time of the probe gas through sample tubes. In bending-induced morphology, it was found that residual adsorbed water molecules would improve the desorption of the water molecules adsorbed on them although it could be difficult for them to desorb completely at room temperature. In welding morphology, the region might be detected in the case of severely oxidized even if the fraction of it was smaller than 5% of whole the tube.

Academic Significance and Societal Importance of the Research Achievements

弾性表面波素子の位相測定には長い波形が有用と考えられるが、BUS回路で得た短い波形でも十分な精度の情報が得られたことは縦軸分解能の向上もまた有用であることを表す。これは、繰り返し周波数の制約で平均化回数に限界があってもAD変換器のビット数で対処し得ることを実証した点で意義がある。そして、実用金属材料の清浄表面における曲げひずみ誘起組織と水分子の吸脱着を分析できる基盤が構築されたことは、単結晶のモデル材料で報告されていた酸化の影響がほとんどない不活性雰囲気において表面に露出したすべり面(最密充填面)が水分子の吸脱着を起こしやすい性質があることを実用的な材料でも初めて確認できた点に意義がある。

Report

(5 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (12 results)

All 2022 2021 2020 2019

All Journal Article (6 results) (of which Peer Reviewed: 4 results) Presentation (6 results) (of which Int'l Joint Research: 3 results)

  • [Journal Article] Fundamental study of nondestructive testing of inner surface of stainless-steel tubings by ball SAW trace moisture sensor2022

    • Author(s)
      Toshihiro Tsuji, Hideyuki Fukushi, Toru Oizumi, Nobuo Takeda, Takamitsu Iwaya, Shingo Akao, Yusuke Tsukahara , Kazushi Yamanaka, Yoshikazu Ohara, Tsuyoshi Mihara
    • Journal Title

      Proceedings of Symposium on Ultrasonics and Electronics

      Volume: 43

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Shortening interval of burst waveform undersampling measurement of ball SAW sensor for characterizing metal surface morphology2021

    • Author(s)
      Toshihiro Tsuji, Hideyuki Fukushi, Toru Oizumi, Nobuo Takeda, Takamitsu Iwaya, Shingo Akao, Yusuke Tsukahara, Kazushi Yamanaka, Yoshikazu Ohara, Tsuyoshi Mihara
    • Journal Title

      Proceedings of Symposium on Ultrasonics and Electronics

      Volume: 42

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 球状弾性表面波センサを用いる微量水分インバースガスクロマトグラフィの基礎検討2021

    • Author(s)
      辻俊宏, 小原良和, 三原毅
    • Journal Title

      信学技報

      Volume: US2020-78 Pages: 7-12

    • Related Report
      2020 Annual Research Report
  • [Journal Article] ボール SAW ガスクロマトグラフによる食品のにおい物質 の分析2020

    • Author(s)
      岩谷隆光, 赤尾慎吾, 竹田宣生, 辻俊宏, 大泉透, 福士秀幸, 岡野達広, 菅原真希, 塚原祐輔, 山中一司
    • Journal Title

      圧電材料デバイスシンポジウム2020

      Volume: 2020 Pages: 57-62

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Background gas analysis with leaky attenuation in a trace moisture analyzer using a ball surface acoustic wave sensor2019

    • Author(s)
      Yamanaka Kazushi, Akao Shingo, Takeda Nobuo, Tsuji Toshihiro, Oizumi Toru, Fukushi, Hideyuki, Okano Tatsuhiro, Tsukahara Yusuke
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 58 Issue: SG Pages: SGGB04-SGGB04

    • DOI

      10.7567/1347-4065/ab0bac

    • NAID

      210000156760

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Separation and Detection of Odorous Compounds at Parts-Per-Billionby Volume Levels Using Ball SAW GasChromatograph2019

    • Author(s)
      Takamitsu Iwaya, Singo Akao, Nobuo Takeda, Toshihiro Tsuji, Toru Oizumi, Hideyuki Fukushi, Tatsuhiro Okano, Maki Sugawara, Yusuke Tsukahara, Kazushi Yamanaka
    • Journal Title

      Proceedings of the 40th Symposium on Ultrasonic Electronics

      Volume: 40

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] Fundamental study of nondestructive testing of inner surface of stainless-steel tubings by ball SAW trace moisture sensor2022

    • Author(s)
      Toshihiro Tsuji, Hideyuki Fukushi, Toru Oizumi, Nobuo Takeda, Takamitsu Iwaya, Shingo Akao, Yusuke Tsukahara , Kazushi Yamanaka, Yoshikazu Ohara, Tsuyoshi Mihara
    • Organizer
      Symposium on Ultrasonics and Electronics
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Shortening interval of burst waveform undersampling measurement of ball SAW sensor for characterizing metal surface morphology2021

    • Author(s)
      Toshihiro Tsuji, Hideyuki Fukushi, Toru Oizumi, Nobuo Takeda, Takamitsu Iwaya, Shingo Akao, Yusuke Tsukahara, Kazushi Yamanaka, Yoshikazu Ohara, Tsuyoshi Mihara
    • Organizer
      Symposium on Ultrasonics and Electronics
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ボールSAW微量水分センサを用いたステンレスガス配管曲げ組織の逆相ガスクロマトグラフィの基礎検討2021

    • Author(s)
      辻 俊宏、福士 秀幸、大泉 透、竹田 宣生
    • Organizer
      第82回応用物理学会秋季学術講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 球状弾性表面波センサを用いる微量水分インバースガスクロマトグラフィの基礎検討2021

    • Author(s)
      辻俊宏
    • Organizer
      一般社団法人電子情報通信学会超音波研究会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ボール SAW ガスクロマトグラフによる食品のにおい物質 の分析2020

    • Author(s)
      岩谷隆光, 赤尾慎吾, 竹田宣生, 辻俊宏, 大泉透, 福士秀幸, 岡野達広, 菅原真希, 塚原祐輔, 山中一司
    • Organizer
      圧電材料デバイスシンポジウム2020
    • Related Report
      2019 Annual Research Report
  • [Presentation] Separation and Detection of Odorous Compounds at Parts-Per-Billionby Volume Levels Using Ball SAW GasChromatograph2019

    • Author(s)
      Takamitsu Iwaya, Singo Akao, Nobuo Takeda, Toshihiro Tsuji, Toru Oizumi, Hideyuki Fukushi, Tatsuhiro Okano, Maki Sugawara, Yusuke Tsukahara, Kazushi Yamanaka
    • Organizer
      Symposium on Ultrasonic Electronics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research

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Published: 2019-04-18   Modified: 2024-01-30  

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