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Building theory for dynamics of thermoelastic martensitic transformation

Research Project

Project/Area Number 19H02418
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 26010:Metallic material properties-related
Research InstitutionNational Institute for Materials Science (2021)
Kyoto University (2019-2020)

Principal Investigator

NIITSU Kodai  国立研究開発法人物質・材料研究機構, 先端材料解析研究拠点, 主任研究員 (90733890)

Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2021: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2020: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2019: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Keywordsマルテンサイト変態 / 動力学 / 等温変態 / 熱活性化 / 構造相変態 / 熱活性化機構 / 超弾性 / 変態ダイナミクス / 熱力学 / 機能性材料 / 無拡散変態
Outline of Research at the Start

マルテンサイト(M)変態における熱活性化機構が見いだされて以来、M変態ダイナミクスの理論構築が求められている。これまで、等温変態については核生成の熱活性化過程の観点から考察がなされてきたが、①M変態の素過程が核生成と成長(界面掃引)によって記述されること、②そのそれぞれに対し熱活性化過程が考えられること、③正変態と逆変態では核生成の有無に違いがあること等、未検討の事象が多数あり、M変態ダイナミクスの理解は十分に進んでいない。
本研究では、核生成・成長の素過程とその熱的活性化過程の役割を明らかにすることで、等温変態を加味したM変態ダイナミクスの理論構築を目指す。

Outline of Final Research Achievements

The low-temperature behavior of the thermoelastic martensitic transformation was explained from the viewpoint of the thermal activation mechanism, and it became clear that the dimension of time plays an important role in understanding the transformation dynamics. By proposing a mathematical model of the thermal activation mechanism and obtaining a numerical solution, I obtained a TTT diagram that visualizes the isothermal transformation behavior and continuous cooling / heating transformation diagrams that visualize the transformation behavior under thermalization. Asymmetric isothermal transformation dynamics and non-ergodicity can be understood from these diagrams. These understandings can be reproduced accurately by the proposed mathematical model, and the original goal of constructing the basic theory of metamorphosis dynamics was achieved.

Academic Significance and Societal Importance of the Research Achievements

本研究成果により、マルテンサイト変態における熱活性化機構の物理的役割が明らかとなった。この役割は特に低温域で顕在化し、従来の理解から外れる変態挙動の主要因となる。その結果、形状記憶効果や超弾性効果は低温で得難くなることが分かり、同合金の低温応用を阻む根源的要因であることが明らかとなった。この課題を解決するためには熱活性化機構の影響を小さくする材料設計戦略を確立する必要があり、今後さらなる理解の深化を通して同合金の低温応用を目指した研究に役立てられると期待される。

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (43 results)

All 2022 2021 2020 2019 Other

All Journal Article (15 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 14 results,  Open Access: 3 results) Presentation (25 results) (of which Int'l Joint Research: 13 results,  Invited: 8 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 2 results)

  • [Journal Article] Geometrically stabilized skyrmionic vortex in FeGe tetrahedral nanoparticles2022

    • Author(s)
      Niitsu Kodai、Liu Yizhou、Booth Alexander C.、Yu Xiuzhen、Mathur Nitish、Stolt Matthew J.、Shindo Daisuke、Jin Song、Zang Jiadong、Nagaosa Naoto、Tokura Yoshinori
    • Journal Title

      Nature Materials

      Volume: 21 Issue: 3 Pages: 305-310

    • DOI

      10.1038/s41563-021-01186-x

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Magnetic flux in soft magnetic Fe-Si-B-P-Cu amorphous alloy containing nanocrystallites analyzed by electron holography2022

    • Author(s)
      Akase Zentaro、Kimura Kenta、Saito Tomohiro、Niitsu Kodai、Tanigaki Toshiaki、Iwasaki Yoh、Sharma Parmanand、Makino Akihiro、Shindo Daisuke
    • Journal Title

      Journal of Magnetism and Magnetic Materials

      Volume: 541 Pages: 168519-168519

    • DOI

      10.1016/j.jmmm.2021.168519

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase equilibria among Fe2Al5 and its higher-ordered phases2021

    • Author(s)
      Hamada Tetsuya、Higashi Masaya、Niitsu Kodai、Inui Haruyuki
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 22 Issue: 1 Pages: 373-385

    • DOI

      10.1080/14686996.2021.1915691

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Element dependence of local disorder in medium-entropy alloy CrCoNi2021

    • Author(s)
      Hanasaki N.、Oda M.、Niitsu K.、Ehara K.、Murakawa H.、Sakai H.、Nitani H.、Abe H.、Sagayama H.、Uetsuka H.、Karube T.、Inui H.
    • Journal Title

      AIP Advances

      Volume: 11 Issue: 12 Pages: 125216-125216

    • DOI

      10.1063/5.0072766

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Inorganic process for wet silica-doping of calcium phosphate2021

    • Author(s)
      Sugiura Yuki、Niitsu Kodai、Saito Yasuko、Endo Takashi、Horie Masanori
    • Journal Title

      RSC Advances

      Volume: 11 Issue: 20 Pages: 12330-12335

    • DOI

      10.1039/d1ra00288k

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of annealing on hardness, yield strength and dislocation structure in single crystals of the equiatomic Cr-Mn-Fe-Co-Ni high entropy alloy2021

    • Author(s)
      Zhou Dengshan、Chen Zhenghao、Ehara Kazuki、Nitsu Kodai、Tanaka Katsushi、Inui Haruyuki
    • Journal Title

      Scripta Materialia

      Volume: 191 Pages: 173-178

    • DOI

      10.1016/j.scriptamat.2020.09.039

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Aesthetic Silver-Doped Octacalcium Phosphate Powders Exhibiting Both Contact Antibacterial Ability and Low Cytotoxicity2020

    • Author(s)
      Sugiura Yuki、Obika Hideki、Horie Masanori、Niitsu Kodai、Makita Yoji
    • Journal Title

      ACS Omega

      Volume: 5 Issue: 38 Pages: 24434-24444

    • DOI

      10.1021/acsomega.0c02868

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal activation of stress-induced martensitic transformation in Ni-rich Ti-Ni alloys2020

    • Author(s)
      Niitsu K.、Date H.、Kainuma R.
    • Journal Title

      Scripta Materialia

      Volume: 186 Pages: 263-267

    • DOI

      10.1016/j.scriptamat.2020.05.010

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature dependence of magnetic exchange stiffness in iron and nickel2020

    • Author(s)
      Niitsu Kodai
    • Journal Title

      Journal of Physics D: Applied Physics

      Volume: 53 Issue: 39 Pages: 39LT01-39LT01

    • DOI

      10.1088/1361-6463/ab9672

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multiple strengthening mechanisms in high strength ultrafine-grained Al?Mg alloys2020

    • Author(s)
      Wang Hao、Geng Hongwei、Zhou Dengshan、Niitsu Kodai、Mur?nsky Ondrej、Zhang Deliang
    • Journal Title

      Materials Science and Engineering: A

      Volume: 771 Pages: 138613-138613

    • DOI

      10.1016/j.msea.2019.138613

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Temperature dependence of exchange stiffness in an off-stoichiometric Ni2MnIn Heusler alloy2020

    • Author(s)
      Niitsu K.、Xu X.、Umetsu R. Y.、Kainuma R.、Harada K.
    • Journal Title

      Physical Review B

      Volume: 101 Issue: 1 Pages: 014443-014443

    • DOI

      10.1103/physrevb.101.014443

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Toward the quantitative the interpretation of hole-free phase plate images in a transmission electron microscope.2020

    • Author(s)
      Harada Ken、Malac Marek、Hayashida Misa、Niitsu Koudai、Shimada Keiko、Homeniuk Darren、Beleggia Marco
    • Journal Title

      Ultramicroscopy

      Volume: 209 Pages: 112875-112875

    • DOI

      10.1016/j.ultramic.2019.112875

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ti-Enriched Al <sub>2</sub>O <sub>3</sub>/Cu Interfaces in a Cu-Al <sub>2</sub>O <sub>3</sub> Alloy2019

    • Author(s)
      Zhou Dengshan、Jin Shenbao、Yang Chao、Niitsu Kodai、Sha Gang、Zhang Deliang
    • Journal Title

      SSRN Electronic Journal

      Volume: -

    • DOI

      10.2139/ssrn.3454925

    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Journal Article] Electron Holography on Fraunhofer Diffraction Using Double Slit2019

    • Author(s)
      Harada Ken、Niitsu Kodai、Shimada Keiko、Kodama Tetsuji、Akashi Tetsuya、Ono Yoshimasa A.、Shindo Daisuke、Shinada Hiroyuki、Mori Shigeo
    • Journal Title

      Microscopy and Microanalysis

      Volume: 25 Issue: S2 Pages: 102-103

    • DOI

      10.1017/s1431927619001247

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron Holography and Magnetotransport Measurements Reveal Stabilized Magnetic Skyrmions in Fe1?xCoxSi Nanowires2019

    • Author(s)
      Mathur Nitish、Stolt Matthew J.、Niitsu Kodai、Yu Xiuzhen、Shindo Daisuke、Tokura Yoshinori、Jin Song
    • Journal Title

      ACS Nano

      Volume: 13 Issue: 7 Pages: 7833-7841

    • DOI

      10.1021/acsnano.9b02130

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] ミディアムエントロピー合金における局所構造2022

    • Author(s)
      花咲徳亮、小田昌治、古谷大樹、新津甲大、陳正昊、江原和輝、村川寛、酒井英明、仁谷浩明、阿部仁、佐賀山基、乾晴行
    • Organizer
      日本金属学会2022年春期講演大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Plastic Deformation of Single Crystals of a Cr-Co-Ni Equiatomic Medium Entropy Alloy2021

    • Author(s)
      Kodai Niitsu, Kazuki Ehara, Kyosuke Kishida, Haruyuki Inui
    • Organizer
      THERMEC'2020 International Conference on PROCESSING & MANUFACTURING OF ADVANCED MATERIALS
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnetic configuration under geometrical confinement2020

    • Author(s)
      KODAI NIITSU
    • Organizer
      8th INTERM 2021
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Plastic Deformation of Single Crystals of a Cr-Co-Ni Equiatomic Medium Entropy Alloy2020

    • Author(s)
      Ashif Equbal, Kazuki Ehara, Makoto Asakura, Kodai Niitsu, Kyosuke Kishida, Haruyuki Inui
    • Organizer
      2020 MRS fall meeting
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Phase equilibria and crystal structures of highly ordered intermetallic compounds of Fe2Al5 phases with the framework structure of η-Fe2Al5 phase2020

    • Author(s)
      Tetsuya Hamada, Ryutaro Sakai, Masaya Higashi, Kodai Niitsu, Haruyuki Inui
    • Organizer
      2020 MRS fall meeting
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Plastic deformation behavior and microstructural evolution of a Cr-Co-Ni medium entropy alloy2020

    • Author(s)
      Kodai Niitsu, Kazuki Ehara, Kyosuke Kishida, Haruyuki Inui
    • Organizer
      Thermec'2021
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fe, Ni薄膜内に導入される磁壁の幅とその温度依存性2020

    • Author(s)
      新津 甲大、原田 研、進藤 大輔
    • Organizer
      日本金属学会2020年春期(第166回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Magnetic texture under geometrical confinement2020

    • Author(s)
      Kodai Niitsu
    • Organizer
      7th INTERM 2020
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] η-Fe2Al5の高次規則相の結晶構造と相平衡2020

    • Author(s)
      濱田 鉄也、境 龍太郎、新津 甲大、乾 晴行
    • Organizer
      本金属学会2020年春期(第166回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Fe-Al B2相に導入した転位近傍の磁気特性2020

    • Author(s)
      新津 甲大、岩村 泰樹、乾 晴行
    • Organizer
      本金属学会2020年春期(第166回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Ti-Zr-Nb-Hf-Ta等原子量合金の低温圧縮変形挙動2020

    • Author(s)
      松浦 周太郎、岸田 恭輔、新津 甲大、乾 晴行
    • Organizer
      本金属学会2020年春期(第166回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Effect of nitrogen addition on the strength and ductility of CrCoNi equiatomic alloys2020

    • Author(s)
      李 楽、陳正昊、新津 甲大、乾 晴行
    • Organizer
      本金属学会2020年春期(第166回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] η-Fe2Al5単結晶マイクロピラーの塑性変形と変形組織観察2020

    • Author(s)
      王 小豊、陳 正昊、新津 甲大、岸田 恭輔、乾 晴行
    • Organizer
      本金属学会2020年春期(第166回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Materials Parameters in Designing FCC High-entropy Alloys2020

    • Author(s)
      Haruyuki Inui, Koudai Niitsu, Kyosuke Kishida, Easo George
    • Organizer
      TMS 2020 Annual Meeting & Exhibition
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Magnetic transition in ordered BCC phases of Fe-Al alloys2019

    • Author(s)
      K. Abe, Y. Kimura, X. Xu, K. Niitsu, T. Omori, R. Kainuma
    • Organizer
      CALPHAD 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of Heat-Treatment on Mechanical Properties of Equiatomic CrMnFeCoNi High-Entropy Alloy and Its Derivative Equiatomic Quaternary and Ternary Medium-Entropy Alloys2019

    • Author(s)
      Haruyuki Inui, Kodai Niitsu, Kyosuke Kishida
    • Organizer
      2019 MRS FALL MEETING & EXHIBIT
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Single-crystal Mechanical Properties of Equiatomic CrMnFeCoNi High-entropy Alloy and Its Derivative Equiatomic Quaternary and Ternary Medium-entropy Alloys2019

    • Author(s)
      Haruyuki Inui,Kyosuke Kishida, Koudai Niitsu, Easo George
    • Organizer
      World Congress on High Entropy Alloys (HEA 2019)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] FCCハイエントロピー合金の塑性変形と微視組織2019

    • Author(s)
      新津甲大,江原和輝,Ashif Equbal,浅倉誠仁,岸田恭輔,乾 晴行
    • Organizer
      日本金属学会2019年秋期(第165回)講演大会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] η-Fe2Al5の高次規則相と相平衡2019

    • Author(s)
      濱田鉄也,境龍太郎,新津甲大,乾 晴行
    • Organizer
      日本金属学会2019年秋期(第165回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] NiCoMnIn合金における磁場誘起マルテンサイト変態ダイナミクス2019

    • Author(s)
      矢野凱己,新津甲大,貝沼亮介,乾 晴行
    • Organizer
      日本金属学会2019年秋期(第165回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Cr-Co-Ni等原子量合金単結晶の塑性変形における熱活性化過程2019

    • Author(s)
      江原和輝,新津甲大,岸田恭輔,乾 晴行
    • Organizer
      日本金属学会2019年秋期(第165回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Ti-Zr-Nb-Hf-Ta等原子量合金のすべり面解析2019

    • Author(s)
      松浦周太郎,岸田恭輔,新津甲大,乾 晴行
    • Organizer
      日本金属学会2019年秋期(第165回)講演大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Isothermal nature of magnetc-feld-induced martensitc transformaton in NiCoMnIn metamagnetc shape memory alloy2019

    • Author(s)
      Yoshiki Yano, Kodai Niitsu, Ryosuke Kainuma, Haruyuki Inui
    • Organizer
      Intermetallics 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Single-crystal Mechanical Properties of Equiatomic CrMnFeCoNi High-entropy Alloy and its Derivative Equiatomic Quaternary and Ternary Medium-entropy Alloys2019

    • Author(s)
      Haruyuki Inui, Kyosuke Kishida, Kodai Niitsu
    • Organizer
      Materials Structure & Micromechanics of Fracture(MSMF9)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mechanical Properties of Single Crystals of Cr-Co-Ni Equiatomic Medium Entropy Alloy2019

    • Author(s)
      Ehara Kazuki, Makoto Asakura, Kodai Niitsu, Kyosuke Kishida, Haruyuki Inui
    • Organizer
      Beyond Nickel-Based Superalloys III
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Remarks] 個人ホームページ

    • URL

      https://kodai-niitsu.jimdofree.com/

    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] Holography reconstruction method and program2020

    • Inventor(s)
      原田研、新津甲大、嶌田惠子
    • Industrial Property Rights Holder
      原田研、新津甲大、嶌田惠子
    • Industrial Property Rights Type
      特許
    • Filing Date
      2020
    • Related Report
      2020 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] Particle beam device, observation method, and diffraction grating2019

    • Inventor(s)
      原田研、嶌田惠子、新津甲大
    • Industrial Property Rights Holder
      原田研、嶌田惠子、新津甲大
    • Industrial Property Rights Type
      特許
    • Filing Date
      2019
    • Acquisition Date
      2021
    • Related Report
      2020 Annual Research Report
    • Overseas

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Published: 2019-04-18   Modified: 2023-01-30  

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