Key factors that predominantly affact electrical and mechanical properties of ultrananpcrystalline diamond films
Project/Area Number |
19H02436
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Review Section |
Basic Section 26020:Inorganic materials and properties-related
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Research Institution | Kyushu University |
Principal Investigator |
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Project Period (FY) |
2019-04-01 – 2023-03-31
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Project Status |
Completed (Fiscal Year 2022)
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Budget Amount *help |
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2022: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2021: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2020: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2019: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
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Keywords | ナノダイヤモンド / ダイヤモンド / 同軸型アークプラズマ堆積法 / 物理気相成長法 / 硬質被膜 / オーミック電極 / 硬度 / 耐酸腐食性 / ヤング弾性率 / オーミック特性 / 半導体物性 / 機械特性 / 薄膜創製 / 薄膜 / 半導体 / コーティング / レーザーアブレーション法 |
Outline of Research at the Start |
粒径10 nm以下のダイヤモンド微結晶がa-C:Hマトリックス中に無数に存在する構造を持つUNCD膜は,膜中における粒界界面の占める割合が無視できないレベルで大きくなり,その結果単結晶ダイヤモンドともa-C:Hとも異なる新奇な物性を発現する.BおよびNドープによりpおよびn型化がキャリア濃度の制御を含めて可能であり,光電変換材料として有望であることを実証してきた.またDLCの最高硬度に匹敵する60 GPaの高硬度膜を,DLC膜より一桁以上厚い数ミクロンの厚膜を堆積可能であることを実証してきた.特異な物性の発現するキーとなる粒界を含むナノ構造を,化学結合構造の視点から明らかにする.
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Outline of Final Research Achievements |
Physical properties specific to nanodiamond (ND) films were investigated and the following results were obtained. (1) Hardness of 85 GPa was achieved by applying a negative voltage. (2) We applied near-field Raman spectroscopy to ND films for the first time and demonstrated that Raman scattering light from ND crystal grains can be detected. (3) The conductive ND film was applied to n-type single crystal diamond, and it was demonstrated that the contact resistance was about one order of magnitude smaller than that of conventional Ti-based electrodes and that the interfacial potential was clearly lowered. (4) The acid corrosion resistance was examined by immersing the ND film in boiling mixed acid; while the Ti-based electrode peeled off immediately after the first session, the ND film remained below the initial contact resistance of the Ti-based electrode for 300 hours, demonstrating that the ND film has extremely high acid corrosion resistance.
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Academic Significance and Societal Importance of the Research Achievements |
同軸型アークプラズマ堆積法でナノダイヤモンド(NCD)膜の成長に唯一成功している。CVD法では結晶サイズを小さくするのが難しいのに対して我々の方法では容易である。数ナノサイズのNCD結晶がアモルファスカーボン(a-C)マトリックス中の存在していることは,化学結合構造の視点からすれば,四面体構造で規則的に配列した部分(NCD結晶)と結合角度がそろっていない部分(a-C)とが混在した状態,すなわち化学結合がナノスケールで変調された状態となっており,バルクとバルクの粒界のように異質なものの境界ではない。無数に内在する粒界の効果を解明することは学術的に極めて意義深い。
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Report
(5 results)
Research Products
(99 results)
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[Presentation] Nanocarbon Electrodes Fabricated by Coaxial Arc Plasma Deposition for Phosphorus-doped Diamond Electronics Application2022
Author(s)
Sreenath Mylo Valappil, Shinya Ohmagari, Abdelrahman Zkria, Phongasaphak Sittimart, Eslam Abubakar, Hiromatsu Kato, Tsuyoshi Yoshitake
Organizer
15th International Conference on New Diamond and Nano Carbons (NDNC) 2022, Kanazawa Bunka Hall, Japan, June 5-9, 2022
Related Report
Int'l Joint Research
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[Presentation] Mechanical and structural properties of Si doped nanodiamond composite coatings deposited on cemented carbide2021
Author(s)
H. Naragino, M. Egiza, H. Ohue, A. M. Ali, K. Murasawa, H. Sugita, Y. Fukui, H. Gonda, M. Sakurai, and T. Yoshitake
Organizer
International Conference on New Diamond and Nano Carbons 2020/2021 (NDNC2020/2021), June 7-9, 2021, (online). 8A-13
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[Presentation] Structural properties and adhesion enhanced of Nanodiamond Composite Films Deposited on Si Substrates at Room Temperature by Employing Buffer Layer2021
Author(s)
A. Mohamed Ali, M. Egiza, K. Murasawa, H. Sugita, Y. Fukui, H. Gonda, M. Sakurai, and T. Yoshitake
Organizer
International Conference on New Diamond and Nano Carbons 2020/2021 (NDNC2020/2021), June 7-9, 2021, (online). II-06-1
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Int'l Joint Research
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[Presentation] PVD nanodiamond composite hard coatings for cutting tools application: structural, mechanical, and tribological properties2021
Author(s)
Mohamed Egiza, Ali Mohamed Ali, Koki Murasawa, Lama Abdelbaset, Hiroshi Naragino, and Tsuyoshi Yoshitake
Organizer
2021年応用物理学会九州支部学術講演会/The 6th Asian Applied Physics Conference (Asian-APC), Dec. 4-5, 2021, Oral (online, invited). 4Ep-2
Related Report
Int'l Joint Research
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[Presentation] Si 上に成膜された接着層を有するナノダイヤモンド混相膜の機械的および構造的特性2020
Author(s)
S. Saito, H. Ohue, A. M. Ali, M. Egiza, K. Murasawa, H. Sugita, Tanja Deckert-Gaudig, Volker Deckert, T. Yoshitake
Organizer
2 0 2 0 年(令和2年度)応用物理学会九州支部学術講演会/The 5th Asian Applied Physics Conference (Asian-APC)、2020 年11 月28 日(土) ~ 29 日(日)、オンライン開催
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[Presentation] 同軸型アークプラズマ蒸着法による量子センターを含むナノダイヤモンドの作成2020
Author(s)
中原大哉, 森田修平, Sreenath M V, Ali M. Ali, Abdelrahman Zkria, Dong Wang, 坪内信輝, 大曲新矢, 吉武剛
Organizer
2 0 2 0 年(令和2年度)応用物理学会九州支部学術講演会/The 5th Asian Applied Physics Conference (Asian-APC)、2020 年11 月28 日(土) ~ 29 日(日)、オンライン開催
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[Presentation] 単結晶ダイヤモンドを用いた横型スピンバルブ素子の評価2020
Author(s)
荒巻枚希, 濵崎健, 坂井拓也, 吉武剛, 堺研一郎
Organizer
2 0 2 0 年(令和2年度)応用物理学会九州支部学術講演会/The 5th Asian Applied Physics Conference (Asian-APC)、2020 年11 月28 日(土) ~ 29 日(日)、オンライン開催
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[Presentation] Mechanical and Structural Properties of Nanodiamond Composite Films Deposited on Si Substrates with Intermediate Layers2020
Author(s)
H. Ohue, A. M. Ali, M. Egiza, K. Murasawa, H. Sugita, Tanja Deckert-Gaudig, Volker Deckert, T. Yoshitake
Organizer
The 5th Asian Applied Physics Conference (Asian-APC), Nov 28-29, 2020, online
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[Presentation] Quantum Centers in Nanocrystalline Diamond Prepared by Coaxial Arc Plasma Deposition2020
Author(s)
Shuhei Morita, Sreenath M V, Hiroya Nakahara, Ali M. Ali, Abdelrahman Zkria, Dong Wang, Tsuyoshi Yoshitake, Nobuteru Tsubouchi, Shinya Ohmagari
Organizer
The 5th Asian Applied Physics Conference (Asian-APC), Nov 28-29, 2020, online
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[Presentation] Formation of Nitrogen and Silicon Quantum Centers in Nanodiamonds using Coaxial Arc Plasma Deposition2020
Author(s)
Sreenath Mylo Valappil, Shuhei Morita, Hiroya Nakahara, Abdelrahman Zkria, Ali Mohamed Ali, Dong Wang, Nobuteru Tsubouchi, Shinya Ohmagari, Tsuyoshi Yoshitake
Organizer
The 5th Asian Applied Physics Conference (Asian-APC), Nov 28-29, 2020, online
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[Presentation] FORMATION OF COLOR CENTERS IN NANODIAMONDS USING COAXIAL ARC PLASMA DEPOSITION2020
Author(s)
Shuhei Morita, Sreenath M V, Hiroya Nakahara, Ali M. Ali, Abdelrahman Zkria, Dong Wang, Nobuteru Tsubouchi, Shinya Ohmagari and Tsuyoshi Yoshitake
Organizer
The 22nd Cross Straits Symposium on Energy and Environmental Science and Technology (CSS-EEST), Dec 2-3, 2020, online
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[Presentation] Atomic structures, mechanical, and tribological properties of B-doped ultrananocrystalline diamond/ nonhydrogenated amorphous carbon composite films deposited on cemented carbide2019
Author(s)
M. Egiza, A. M. Ali1, K. Murasawa, Y. Fukui, H. Gonda, M. Sakurai, and T. Yoshitake
Organizer
The 13th New Diamond and Nano Carbon Conference(NDNC 2019), Taiwan, May 12-17, 2019
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[Presentation] Si doping effects on mechanical properties of ultrananocrystalline diamond/ amorphous carbon composite films deposited on cemented carbide2019
Author(s)
M. Egiza, K. Murasawa, A.M. Ali, Y. Fukui, H. Gonda, M. Sakurai, T. Yoshitake
Organizer
30th International conference in Diamond and Carbon materials (ICDCM-2019) , Sep. 8-12, 2019, Melia Lebreros, Seville, Spain
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[Presentation] Mechanical and structural properties of Si doped nanodiamond composite films coatings deposited on cemented carbide2019
Author(s)
H.Ohue, M.Egiza, A.M.Ali, K.Murasawa, Y.Fukui, H.Gonda, M.Sakurai, T.Yoshitake
Organizer
JSAP Kyushu Chapter Annual Meeting 2019 /The 4th Asian Applied Physics Conference (Asian-APC), Nov 23-24, 2019, Kumamoto Univ
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