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Mechanism study of nanoparticle assembly based on femtosecond laser multi-photon reduction

Research Project

Project/Area Number 19H02474
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 26050:Material processing and microstructure control-related
Research InstitutionYamagata University

Principal Investigator

Nishiyama Hiroaki  山形大学, 大学院理工学研究科, 准教授 (80403153)

Project Period (FY) 2019-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000)
Fiscal Year 2022: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2021: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2020: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2019: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords超短パルスレーザー / ナノ材料 / 光熱変換 / レーザー描画 / ナノ粒子 / 集積 / アセンブリ― / フェムト秒レーザー / アセンブリー / 多光子反応 / マイクロバブル
Outline of Research at the Start

超短パルスレーザーを用いた溶液中での特異な微粒子集積固化現象についてその機構解明と制御指針の獲得に取り組む.同現象は,従来のレーザー加工では適用が困難な非感光性材料について,レーザー直接描画でマイクロパターンを形成することを可能とし,極めて広い被加工材料選択性と高い応用性を持つ.このレーザーによる微粒子集積固化機構に深く関わると推定されるマイクロバブルの役割を明確化し,新しいレーザー加工プロセスの原理を構築する.

Outline of Final Research Achievements

In conventional micropatterns have been fabricated by several processes such as lithography and etching, which generate a large amount of waste liquid, or by inkjet printing, which produces a small amount of waste liquid but is not so fine. On the other hand, we have developed a direct photofabrication process for functional materials only by light irradiation. This process is based on the findings of unique phenomenon that occurs in the laser focus. In this study, we investigated this phenomenon to understand the mechanism. Detailed observation with high-speed camera and heat transfer simulation indicated the validity of our proposed physical mechanism model. Two phenomena with large time difference proceeded during the laser writing. From this understanding the mechanism, we newly developed another laser writing process with high efficiency.

Academic Significance and Societal Importance of the Research Achievements

研究成果の学術的意義として,従来のレーザー直接描画手法の原理的課題ともされてきた適用材料の制限を克服し得る特異現象について,集光部で起こる光化学反応とそれを起点として誘起される流体現象の関係を明らかにした.いずれか一方だけの現象はこれまでも多く報告されており,ある意味で事前に現象を予測することも可能だが,この複合現象は当初,機構の推定が二転三転して解明には時間を要した.ただ,この機構解明を通して,廃液がほぼなく光照射だけで,多様な機能性材料についてマイクロ配線を高速で描く手法を開発することができ,これは脱炭素や効率的なエネルギー利用に役立つといった社会的意義に繋がったと考える.

Report

(5 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (21 results)

All 2022 2021 2020 2019

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Open Access: 3 results) Presentation (15 results) (of which Int'l Joint Research: 3 results,  Invited: 5 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] レーザー二光子還元反応を起点とした機能性微粒子 の集積体形成2022

    • Author(s)
      西山宏昭
    • Journal Title

      光学

      Volume: 51 Pages: 75-79

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Femtosecond laser writing of plasmonic nanoparticles inside PNIPAM microgels for light-driven 3D soft actuators2020

    • Author(s)
      H. Nishiyama, S. Odashima, S. Asoh
    • Journal Title

      Optics Express

      Volume: 28 Issue: 18 Pages: 26470-26480

    • DOI

      10.1364/oe.399440

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Multiphoton photoreduction for dual-wavelength-light-driven shrinkage and actuation in hydrogel2020

    • Author(s)
      Kosuke Mizuguchi, Yo Nagano, Hiroaki Nishiyama, Hiroaki Onoe, Mitsuhiro Terakawa
    • Journal Title

      Optical Materials Express

      Volume: 10 Issue: 8 Pages: 1931-1931

    • DOI

      10.1364/ome.399874

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Versatile direct laser writing of non-photosensitive materials using multi-photon reduction-based assembly of nanoparticles2019

    • Author(s)
      H. Nishiyama, K. Umetsu, K. Kaito
    • Journal Title

      Scientific Reports

      Volume: 9 Issue: 1 Pages: 14310-14310

    • DOI

      10.1038/s41598-019-50630-1

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] フェムト秒レーザー粒子集積プロセスにおける 集光部近傍の伝熱解析2022

    • Author(s)
      西山宏昭,沼田洸,青山昌央
    • Organizer
      第70回春季応用物理学会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 二段階フェムト秒レーザー照射による 非感光性粒子集積体のライン描画2022

    • Author(s)
      西山 宏昭,松本 春加,大森 隆史
    • Organizer
      第70回春季応用物理学会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 二光子還元反応を起点としたレーザー集積固化プロセスにおける周辺対流の直接観察2022

    • Author(s)
      西山宏昭,奈良尚悟
    • Organizer
      第83回秋季応用物理学会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Nonlinear light-based controls of bottom-up assembly toward direct laser writing beyond material limitation2021

    • Author(s)
      H. Nishiyama
    • Organizer
      理研光量子工学研究センター71st RAP seminar
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] フェムト秒レーザー照射によるマイクロゲル内への位置選択的Agナノ粒子導入と 光駆動変形特性2021

    • Author(s)
      西山宏昭,阿相克
    • Organizer
      バイオオプティクス研究会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Femtosecond laser direct writing of layered pure hydroxyapatite based on nanoparticle assembly2021

    • Author(s)
      H. Nishiyama, S. Nara
    • Organizer
      MNC2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] Direct laser writing of non-photosensitive materials using femtosecond laser microbubble-based assembly2021

    • Author(s)
      H. Nishiyama, K. Kimura, K. Umetsu
    • Organizer
      LPM2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] 材料感光性に制限されないバブル駆動レーザー微細描画プロセス2021

    • Author(s)
      西山宏昭
    • Organizer
      第41回レーザー学会年次大会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Versatile direct laser writing of non-photosensitive materials using multi-photon reduction-based assembly2020

    • Author(s)
      T. Omori, K. Umetsu, K. Kimura, H. Nishiyama
    • Organizer
      The 8 th International Conference on Smart Systems Engineering
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Optical property controls of DUV plasmon using microactuated diaphragms2020

    • Author(s)
      K. Takahashi, N. Chizawa, K. Ikeda, H. Nishiyama
    • Organizer
      The 8 th International Conference on Smart Systems Engineering
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] NIR-driven deformation of PNIPAM microgels using plasmonic focusing effects2020

    • Author(s)
      M. Nakajima, W. Tabata, S. Odasima, A. Abe, H. Nishiyama
    • Organizer
      The 8 th International Conference on Smart Systems Engineering
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] レーザー多光子還元を起点とした光機能性微粒子の集積固化と素子応用2020

    • Author(s)
      西山宏昭
    • Organizer
      第40回レーザー学会年次大会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] レーザー多光子還元を起点とした機能性微粒子の集積体形成2019

    • Author(s)
      西山宏昭
    • Organizer
      第16回バイオオプティクス研究会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 液中フェムト秒レーザ照射されたAgマイクロドットのナノ粒子集積特性の評価2019

    • Author(s)
      松本春加,西山宏昭
    • Organizer
      応用物理学会東北支部講演会2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] 液中フェムト秒レーザ照射によるハイドロキシアパタイト微粒子の集積固化2019

    • Author(s)
      奈良尚悟,馮忠剛,西山宏昭
    • Organizer
      応用物理学会東北支部講演会2019
    • Related Report
      2019 Annual Research Report
  • [Patent(Industrial Property Rights)] レーザー照射による複合体の製造方法及び複合体2022

    • Inventor(s)
      西山宏昭,松本春加
    • Industrial Property Rights Holder
      西山宏昭,松本春加
    • Industrial Property Rights Type
      特許
    • Filing Date
      2022
    • Related Report
      2021 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] レーザー照射による複合配線の製造方法及び複合配線2021

    • Inventor(s)
      西山宏昭,松本春加
    • Industrial Property Rights Holder
      山形大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2021-019324
    • Filing Date
      2021
    • Related Report
      2020 Annual Research Report

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Published: 2019-04-18   Modified: 2025-01-30  

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