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Investigation of correlation between process and phase separation structure of multicomponent alloys and establishment of guideline for new materials process design

Research Project

Project/Area Number 19H02493
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 27010:Transport phenomena and unit operations-related
Research InstitutionTohoku University

Principal Investigator

Tsukada Takao  東北大学, 工学研究科, 教授 (10171969)

Co-Investigator(Kenkyū-buntansha) 福山 博之  東北大学, 多元物質科学研究所, 教授 (40252259)
Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Fiscal Year 2021: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2020: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2019: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywords多元系合金 / 融液内対流 / 相分離構造 / 過冷却凝固 / プロセス-構造相関 / プロセスー構造相関 / 融体内対流 / プロセス-構造相関
Outline of Research at the Start

過冷却域に二液相分離域を有するCu基合金融体を過冷却凝固すると,二液相分離が誘起され,その相分離(凝固組織)構造に由来する新規な特性を有する材料の創製が可能である.本研究では,相分離構造に影響を及ぼす因子として融体内対流に着目し,対流制御が可能な静磁場重畳電磁浮遊技術,位相シフト干渉計や中性子CT等の計測技術,数値シミュレーションを融合し,多元系合金融体内対流と相分離構造との相関を解明する.さらに,多元系合金の相分離構造を俯瞰できるように,対流強度,温度・濃度場の変化速度,相分離駆動力等の影響因子を軸とするプロセス空間に相分離構造をマッピングし,プロセス-構造相関マップを作成する.

Outline of Final Research Achievements

The effect of static magnetic filed (i.e., melt convection) on the phase separation structures of undercooled Cu-Co and Cu-Fe alloys solidified under a static magnetic field was clarified using an electromagnetic levitation (EML) technique superimposed with a static magnetic field and neutron CT. By direct numerical simulations of three-dimensional, unsteady magnetohydrodynamic (MHD) convection in a spherical electromagnetically levitated molten Cu-Co droplet under different strengths of the static magnetic field, it was demonstrated that the marked change in phase separation structures in undercooled Cu-Co alloys with increasing the static magnetic filed was closely related to the laminar-turbulent transition of MHD convection in the levitated droplet. The compositional dependence of the thermal conductivity of a molten Cu-Fe alloy at low Fe contents was measured by combining the EML with a static magnetic field and a periodic laser heating method.

Academic Significance and Societal Importance of the Research Achievements

Cu基合金の多くは過冷却域に二液相分離域を有するため,過冷却凝固に伴い二液相分離特有のマクロ,ミクロ凝固組織構造が発現し,その構造に由来した新奇な電気的,磁気的あるいは機械的特性を有する新材料の創製が期待される.本研究は,Cu基合金の相分離構造の制御因子に関し,これまで研究がほとんど行われていなかった融体内対流を制御因子の一つとして捉え,対流構造や強度と相分離構造との関係を実験と理論の両側面から詳細に明らかにした点に学術的意義がある.

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (9 results)

All 2021 2020 2019

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (6 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Numerical simulation of laminar-turbulent transition in magnetohydrodynamic convection in an electromagnetically levitated molten droplet of Cu-Co alloys under a static magnetic field2021

    • Author(s)
      Eita Shoji, Koki Tanada, Ryuji Takahashi, Shosei Isogai, Rikuto Susuki, Masaki Kubo, Takao Tsukada, Atsuki Komiya, Hiroyuki Fukuyama
    • Journal Title

      Metallurgical and Materials Transactions B

      Volume: 52 Issue: 2 Pages: 896-902

    • DOI

      10.1007/s11663-021-02063-3

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Compositional Dependence of Thermal Conductivity of Molten Cu-Fe Alloy at Low Fe Contents2020

    • Author(s)
      Eita Shoji, Naoto Ito, Masaki Kubo, Takao Tsukada, Hiroyuki Fukuyama
    • Journal Title

      Metallurgical and Materials Transactions B

      Volume: 51 Issue: 6 Pages: 2504-2509

    • DOI

      10.1007/s11663-020-01965-y

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Neutron computed tomography of phase separation structures in solidified Cu-Co alloys and investigation of relationship between the structures and melt convection during solidification2020

    • Author(s)
      Eita Shoji, Shosei Isogai, Rikuto Suzuki, Masaki Kubo, Takao Tsukada, Tetsuya Kai, Takenao Shinohara, Yoshihiro Matsumoto, Hiroyuki Fukuyama
    • Journal Title

      Scripta Materialia

      Volume: 175 Pages: 29-32

    • DOI

      10.1016/j.scriptamat.2019.08.041

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] 静磁場下での過冷却凝固によるCu基合金の相分離構造 -Cu-CoとCu-Fe合金の比較-2021

    • Author(s)
      奥山大貴,鈴木陸人,庄司衛太,久保正樹,塚田隆夫,福山博之
    • Organizer
      化学工学会第52回秋季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 静磁場重畳電磁浮遊技術を用いたCu基合金の相分離挙動に及ぼす諸因子の影響2020

    • Author(s)
      久保正樹,鈴木陸人,奥山大貴,庄司衛太,塚田隆夫,福山博之
    • Organizer
      日本マイクログラビティ応用学会 第32回学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Study on the effect of melt convection on phase separation structures in molten Cu-based alloys using an electromagnetic levitator super imposed with a static magnetic field2020

    • Author(s)
      Taiki Okuyama, Rikuto Suzuki, Eita Shoji, Masaki Kubo, Takao Tsukada, Hiroyuki Fukuyama
    • Organizer
      2020年度化学系学協会東北大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 静磁場重畳電磁浮遊Cu-Co液滴内のMHD対流の数値解析と相分離構造への影響評価2019

    • Author(s)
      庄司衛太, 磯谷祥世, 高橋龍司, 多奈田紘希, 久保正樹, 塚田隆夫, 福山博之
    • Organizer
      第56回日本伝熱シンポジウム
    • Related Report
      2019 Annual Research Report
  • [Presentation] Investigation of correlation between phase separation structures and melt convection in Cu-Co molten alloys using neutron CT and DNS2019

    • Author(s)
      Shosei ISOGAI, Eita SHOJI, Masaki KUBO, Takao TSUKADA, Tetsuya KAI, Takenao SHINOHARA, Yoshihiro MATSUMOTO, Hiroyuki FUKUYAMA
    • Organizer
      18th Asian Pacific Confederation of Chemical Engineering Congress
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 静磁場重畳電磁浮遊技術を用いたCu-Fe合金の相分離構造に及ぼす融体内対流の影響評価2019

    • Author(s)
      鈴木陸人, 磯谷祥世, 庄司衛太, 久保正樹, 塚田隆夫, 福山博之
    • Organizer
      日本マイクログラビティ応用学会 第31回学術講演会
    • Related Report
      2019 Annual Research Report

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Published: 2019-04-18   Modified: 2023-01-30  

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