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Ionics at Solid-Solid Interfaces in All-Solid-State Batteries

Research Project

Project/Area Number 19H02603
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 29020:Thin film/surface and interfacial physical properties-related
Research InstitutionNippon Institute of Technology

Principal Investigator

SHIRAKI SUSUMU  日本工業大学, 基幹工学部, 教授 (80342799)

Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2021: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2020: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2019: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Keywords全固体電池 / 界面 / 薄膜 / リチウム2次電池 / エピタキシャル薄膜 / RFスパッタリング法 / 表面界面物性 / リチウム電池 / パルスレーザー堆積法 / スパッタリング法
Outline of Research at the Start

全固体電池と液系電池の大きな違いは、電解質が固体であること、そしてリチウムイオンが固体電解質と電極の「固体/固体界面」を移動することである。そして、全固体リチウム電池の実用化に向け、その固体電解質/電極界面の低抵抗化が急務となっている。本研究では、(1)電解質/電極界面の抵抗は小さくできるのか?そして、(2)その界面抵抗はどこまで小さくすることができるのか?(3)抵抗の小さい界面はどのような構造であるか?の3点に着目し研究を行う。正極、固体電解質、負極の各薄膜を積層して薄膜型全固体電池を作製し、その電気化学評価を行うことにより、上記課題を解決する。

Outline of Final Research Achievements

All-solid-state batteries are expected to be used as large lithium batteries for automotive applications and stationary storage batteries. In this study, we developed an all-in-vacuum fabrication and in-situ evaluation system for thin-film all-solid-state batteries, and fabricated epitaxial thin films of battery materials such as cathode, anode, and solid electrolyte. Thin-film all-solid-state batteries were also fabricated using 5V-class cathode material (lithium nickel manganate), solid electrolyte (lithium phosphate), and anode lithium, and the resistance of the electrode/electrolyte interface was evaluated.

Academic Significance and Societal Importance of the Research Achievements

今回の成果により、電池材料の薄膜とそれらを積層した薄膜型全固体電池の作製に関する知見、ノウハウを得ることができました。また、薄膜技術や真空技術などの、これまでに電池研究で利用されていなかった技術や手法、アプローチが、電池の基礎研究に極めて有効であることも分かりました。これらの取り組みが拡まり、大きな技術革新につながることが期待されます。

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (26 results)

All 2021 2020 2019 Other

All Journal Article (10 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 1 results) Presentation (11 results) (of which Int'l Joint Research: 3 results,  Invited: 7 results) Book (2 results) Remarks (3 results)

  • [Journal Article] Study of Solid-Solid Interface in All-Solid-State Batteries: Atomic Structures and Ion Conductivities at Interfaces2021

    • Author(s)
      白木将、白澤徹郎、一杉太郎
    • Journal Title

      Journal of Surface Analysis

      Volume: 27 Issue: 3 Pages: 156-160

    • DOI

      10.1384/jsa.27.156

    • NAID

      40022522119

    • ISSN
      1341-1756, 1347-8400
    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 全固体電池の界面不純物制御による容量倍増と電解質/正極界面におけるLi移動解析2021

    • Author(s)
      河底秀幸、白澤徹郎、西尾和記、清水亮太、白木將、一杉太郎
    • Journal Title

      マテリアルステージ

      Volume: 27 Pages: 42-47

    • Related Report
      2021 Annual Research Report
  • [Journal Article] Clean Solid-Electrolyte/Electrode Interfaces Double the Capacity of Solid-State Lithium Batteries2021

    • Author(s)
      Kawasoko Hideyuki、Shirasawa Tetsuroh、Nishio Kazunori、Shimizu Ryota、Shiraki Susumu、Hitosugi Taro
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 13 Issue: 4 Pages: 5861-5865

    • DOI

      10.1021/acsami.0c21586

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 全固体電池における電解質/電極界面の抵抗低減と高速充放電2020

    • Author(s)
      白木将、一杉太郎
    • Journal Title

      車載テクノロジー

      Volume: 7 Pages: 42-46

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Low Interface Resistance in Solid-State Lithium Batteries Using Spinel LiNi0.5Mn1.5O4(111) Epitaxial Thin Films2020

    • Author(s)
      Kawasoko Hideyuki、Shirasawa Tetsuroh、Shiraki Susumu、Suzuki Toru、Kobayashi Shigeru、Nishio Kazunori、Shimizu Ryota、Hitosugi Taro
    • Journal Title

      ACS Applied Energy Materials

      Volume: 3 Issue: 2 Pages: 1358-1363

    • DOI

      10.1021/acsaem.9b01766

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Origin of Optical Transparency in a Transparent Superconductor LiTi2O42020

    • Author(s)
      Ohsawa Takeo、Yamada Naoomi、Kumatani Akichika、Takagi Yoshitaka、Suzuki Tohru、Shimizu Ryota、Shiraki Susumu、Nojima Tsutomu、Hitosugi Taro
    • Journal Title

      ACS Applied Electronic Materials

      Volume: 2 Issue: 2 Pages: 517-522

    • DOI

      10.1021/acsaelm.9b00751

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metallic band structure of CaF2 thin films grown on silicon(1 1 1): Possible formation of CaSi22020

    • Author(s)
      Takahashi Yuzuru、Ichinokura Satoru、Shimizu Ryota、Shiraki Susumu、Hitosugi Taro、Hirahara Toru
    • Journal Title

      Applied Surface Science

      Volume: 509 Pages: 144687-144687

    • DOI

      10.1016/j.apsusc.2019.144687

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Extraordinary quasi-two-dimensional magnetotransport properties of a LaAlO3/SrTiO3 heterostructure tailored with a surface TiO2 atomic sheet2019

    • Author(s)
      Ohsawa Takeo、Shimizu Ryota、Iwaya Katsuya、Shiraki Susumu、Nojima Tsutomu、Hitosugi Taro
    • Journal Title

      Applied Physics Letters

      Volume: 115 Issue: 20 Pages: 201601-201601

    • DOI

      10.1063/1.5120045

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 真空プロセスによる電極/固体電解質接合界面の作製と界面抵抗の低減2019

    • Author(s)
      白木将、一杉太郎
    • Journal Title

      マテリアルステージ

      Volume: 19 Pages: 26-31

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Li(Ni0.5Mn1.5)O4全固体薄膜電池における超高速充放電特性2019

    • Author(s)
      河底秀幸、白木将、一杉太郎
    • Journal Title

      車載テクノロジー

      Volume: 6 Pages: 39-42

    • Related Report
      2019 Annual Research Report
  • [Presentation] Fabrication of All-Solid-State Thin-Film Lithium Batteries and their Electrochemical Properties2021

    • Author(s)
      Susumu Shiraki
    • Organizer
      The 5th International Symposium "Elucidation of Next Generation Functional Materials Surface/Interface Properties"
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] LiNi0.5Mn1.5O4エピタキシャル薄膜の低温合成2021

    • Author(s)
      副田海周、尾張眞則、白木将
    • Organizer
      日本表面真空学会 学術講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 真空・薄膜技術を活用した全固体電池研究2021

    • Author(s)
      白木将
    • Organizer
      R026先端計測技術の将来設計委員会 第3回研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 全固体電池の固固界面研究:界面の構造とイオン伝導性2020

    • Author(s)
      白木将、白澤徹郎、一杉太郎
    • Organizer
      実用表面分析講演会、Symposium on Practical Surface Analysis 2020 (PSA-20)
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 理想的なモデル薄膜電極を活用した全固体電池の界面研究2020

    • Author(s)
      白木将、一杉太郎
    • Organizer
      第81回応用物理学会秋季学術講演会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 薄膜を利用した全固体電池の電極/電解質界面研究2020

    • Author(s)
      白木将、一杉太郎
    • Organizer
      第67回応用物理学会春季学術講演会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Anisotropy and low interface resistance in all-solid-state lithium batteries using spinel LiNi0.5Mn1.5O4 epitaxial thin films2019

    • Author(s)
      Susumu Shiraki
    • Organizer
      The 4th International Symposium "Elucidation of Property of Next Generation Functional Materials of Surface/Interface
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication and in-situ characterization of well-defined solid electrolyte/electrode interfaces in thin-film lithium batteries2019

    • Author(s)
      Susumu Shiraki
    • Organizer
      12th International Symposium on Atomic Level Characterizations for New Materials and Devices ’19 (ALC'19)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 5V級正極材料薄膜の作製とその電気化学評価2019

    • Author(s)
      白木将
    • Organizer
      第80回応用物理学会秋季学術講演会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 全固体電池技術の現状と展望2019

    • Author(s)
      白木将
    • Organizer
      埼玉産業人クラブ・NITEC埼玉産学交流会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 表面界面制御・分析技術を活用した全固体電池研究2019

    • Author(s)
      白木将
    • Organizer
      日本学術振興会マイクロビームアナリシス第141委員会第176回研究会
    • Related Report
      2019 Annual Research Report
  • [Book] 全固体電池の界面抵抗低減と作製プロセス、評価技術2020

    • Author(s)
      白木将、西尾和記、一杉太郎
    • Total Pages
      490
    • Publisher
      情報技術協会
    • ISBN
      9784861047800
    • Related Report
      2019 Annual Research Report
  • [Book] リチウムイオン電池および部材の分析、解析と評価技術 事例集2019

    • Author(s)
      白澤徹郎、白木将、一杉太郎
    • Total Pages
      522
    • Publisher
      情報技術協会
    • ISBN
      9784861047701
    • Related Report
      2019 Annual Research Report
  • [Remarks] 日本工業大学応用化学科固体電気化学研究室

    • URL

      http://enjoy1.bb-east.ne.jp/~shiraki/

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
  • [Remarks] 全固体電池の界面不純物制御により電池容量を 2 倍に

    • URL

      https://www.nit.ac.jp/research-headlines/2

    • Related Report
      2020 Annual Research Report
  • [Remarks] 電気自動車向けのハイスペックな「全固体電池」を開発!

    • URL

      https://www.nit.ac.jp/jukensei/trainlabo/trainlabo3#no15

    • Related Report
      2019 Annual Research Report

URL: 

Published: 2019-04-18   Modified: 2024-12-25  

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