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Study of electroluminescence and photophysical properties of single halide perovskite nanocrystals

Research Project

Project/Area Number 19H02684
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 32020:Functional solid state chemistry-related
Research InstitutionTokyo Institute of Technology

Principal Investigator

Vacha Martin  東京工業大学, 物質理工学院, 教授 (50361746)

Project Period (FY) 2019-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2023: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2022: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2021: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2020: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2019: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Keywords単一分子分光 / ハロゲン化ペロブスカイト / 量子ドット / Single-molecule studies / Perovskite nanocrystals / ハライドペロブスカイト / ハライド ペロブスカイト
Outline of Research at the Start

有機無機ハライドペロブスカイトが優れた光物理的特性を持ち、発光デバイス、ディスプレーなど次世代の光・電子デバイスの材料として注目されている。しかし、ハライドペロブスカイトナノ結晶を発光体として用いた電界発光デバイスの効率が低いことが課題として残っている。本研究では、単一粒子分光法を用い、ペロブスカイトナノ結晶の基礎的な光物理特性を解明することを目的にする。ペロブスカイトの構造および表面特性と発光特性の関係に注目し、発光ブリンキング、スペクトル拡散などの現象を明確にする。電界発光デバイス効率の向上を目指し、本研究の成果がナノスケール光・電子デバイスの開発のフィードバックになることを期待する。

Outline of Final Research Achievements

Organic-inorganic halide perovskites show excellent photophysical properties and are attracting attention as materials for next-generation optical and electronic devices such as light-emitting diodes and displays. In this study, we aimed at elucidating the fundamental photophysical properties of perovskite nanocrystals using single particle spectroscopy. The main results include clarification of the electroluminescence blinking phenomenon and electroluminescence efficiency by simultaneous measurement of electroluminescence and photoluminescence in CsPbBr3 perovskite nanocrystals, suppression of the blinking of perovskite nanocrystals by ligand exchange, and elucidation of the nanocrystal formation process and ion diffusion in halide perovskite-metal organic framework composite materials.

Academic Significance and Societal Importance of the Research Achievements

有機無機ハロゲン化ペロブスカイトが次世代の光・電子デバイスの材料として期待されているが、ハロゲン化ペロブスカイトナノ結晶(量子ドット)を発光体として用いた電界発光デバイスの効率が低いことが課題として残っていた。本研究では、低効率の原因となる発光点滅(ブリンキング)に注目し、電界発光での点滅現象の解明へ大きく進捗した。また、リガンド交換による点滅の抑制方法も提案し、電子デバイスの開発のフィードバックを提供した。本研究の成果がナノスケール光・電子デバイスの研究開発の他、材料科学および物理化学の分野にも大きなインパクトを与えることが期待される。

Report

(6 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (21 results)

All 2023 2022 2021 2020 2019 Other

All Journal Article (13 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 13 results,  Open Access: 3 results) Presentation (6 results) (of which Int'l Joint Research: 5 results,  Invited: 4 results) Remarks (2 results)

  • [Journal Article] Suppression of blinking in single CsPbBr3 perovskite nanocrystals through surface ligand exchange2023

    • Author(s)
      Takagi Toranosuke、Omagari Shun、Vacha Martin
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 25 Issue: 28 Pages: 19004-19012

    • DOI

      10.1039/d3cp01844j

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Air-stable mixed cation lead halide perovskite films and microscopic study of their degradation process2023

    • Author(s)
      Agarwal Anubha、Omagari Shun、Vacha Martin
    • Journal Title

      Nanoscale

      Volume: 15 Issue: 25 Pages: 10642-10650

    • DOI

      10.1039/d3nr02003g

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In Situ Monitoring of Nanocrystal Formation and Ion Migration in Lead Halide Perovskite Metal?Organic Framework Composites2023

    • Author(s)
      Wu Xiayan、Omagari Shun、Gao Jinwei、Vacha Martin
    • Journal Title

      Advanced Optical Materials

      Volume: 12 Issue: 3 Pages: 2301479-2301479

    • DOI

      10.1002/adom.202301479

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Simultaneous Force and Fluorescence Spectroscopy on Single Chains of Polyfluorene: Effect of Intra-Chain Aggregate Coupling2023

    • Author(s)
      Nakamura Tomonori、Omagari Shun、Liang Xiaobin、Tan Qiwen、Nakajima Ken、Vacha Martin
    • Journal Title

      ACS Nano

      Volume: 17 Issue: 9 Pages: 8074-8082

    • DOI

      10.1021/acsnano.2c09773

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanoscale Structural Heterogeneity and Efficient Intergrain Charge Diffusion in a Series of Mixed MA/FA Halide Perovskite Films2022

    • Author(s)
      Agarwal Anubha、Omagari Shun、Vacha Martin
    • Journal Title

      ACS Energy Letters

      Volume: 7 Issue: 8 Pages: 2443-2449

    • DOI

      10.1021/acsenergylett.2c01271

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dynamic molecular conformational change leading to energy transfer in F8-5% BSP copolymer revealed by single-molecule spectroscopy2022

    • Author(s)
      Yan Hao、Tseng Tzu-Wei、Omagari Shun、Hamilton Iain、Nakamura Tomonori、Vacha Martin、Kim Ji-Seon
    • Journal Title

      The Journal of Chemical Physics

      Volume: 156 Issue: 7 Pages: 074704-074704

    • DOI

      10.1063/5.0080406

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Real-time molecular-level visualization of mass flow during patterned photopolymerization of liquid-crystalline monomers2021

    • Author(s)
      K. Ueda, M. Aizawa, A. Shishido, M. Vacha
    • Journal Title

      NPG Asia Mater.

      Volume: 13 Issue: 1 Pages: 25-25

    • DOI

      10.1038/s41427-021-00292-1

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Enhancement of the Photocurrent of a Single Photosystem I Complex by the Localized Plasmon of a Gold Nanorod2021

    • Author(s)
      Furuya Ryotaro、Omagari Shun、Tan Qiwen、Lokstein Heiko、Vacha Martin
    • Journal Title

      Journal of the American Chemical Society

      Volume: 143 Issue: 33 Pages: 13167-13174

    • DOI

      10.1021/jacs.1c04691

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dynamic Polymer Free Volume Monitored by Single-Molecule Spectroscopy of a Dual Fluorescent Flapping Dopant2021

    • Author(s)
      Goto Yuma、Omagari Shun、Sato Ryuma、Yamakado Takuya、Achiwa Ryo、Dey Nilanjan、Suga Kensuke、Vacha Martin、Saito Shohei
    • Journal Title

      Journal of the American Chemical Society

      Volume: 143 Issue: 35 Pages: 14306-14313

    • DOI

      10.1021/jacs.1c06428

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Energy localization vs. charge funneling in aggregates of CsPbBr3 perovskite nanocrystals2020

    • Author(s)
      Dharmendar Kumar Sharma*, Shuzo Hirata, Martin Vacha*
    • Journal Title

      Journal of Luminescence

      Volume: 222 Pages: 117119-117119

    • DOI

      10.1016/j.jlumin.2020.117119

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Mechanically Induced Conformation Change, Fluorescence Modulation, and Mechanically Assisted Photodegradation in Single Nanoparticles of the Conjugated Polymer Poly(9,9-dioctylfluorene)2020

    • Author(s)
      Nakamura Tomonori、Vacha Martin
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 11 Issue: 8 Pages: 3103-3110

    • DOI

      10.1021/acs.jpclett.0c00939

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Real-Time Monitoring of Formation and Dynamics of Intra- and Interchain Phases in Single Molecules of Polyfluorene2020

    • Author(s)
      Tseng Tzu-Wei、Yan Hao、Nakamura Tomonori、Omagari Shun、Kim Ji-Seon、Vacha Martin
    • Journal Title

      ACS Nano

      Volume: 14 Issue: 11 Pages: 16096-16104

    • DOI

      10.1021/acsnano.0c08038

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Single-particle electroluminescence of CsPbBr3 perovskite nanocrystals reveals particle-selective recombination and blinking as key efficiency factors2019

    • Author(s)
      Dharmendar Kumar Sharma*, Shuzo Hirata, Martin Vacha*
    • Journal Title

      Nature Communications

      Volume: 10 Issue: 1 Pages: 4499-4499

    • DOI

      10.1038/s41467-019-12512-y

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Nanoscale photophysical properties and real-time in situ dynamics of halide perovskite films and nanocrystals2023

    • Author(s)
      Martin Vacha
    • Organizer
      31st International Conference on Photochemistry
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nanoscale spectroscopy of halide perovskite films, nanocrystals and related systems2023

    • Author(s)
      Martin Vacha
    • Organizer
      12th Asian Photochemistry Conference
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electroluminescence at the nanoscale: Single-molecule and single-particle spectroscopy of conjugated polymers and perovskite nanocrystals2022

    • Author(s)
      Martin Vacha
    • Organizer
      13th International Conference of Electroluminescence and Optoelectronic Devices, London, UK
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Single-particle electroluminescence and photoluminescence spectroscopy of organic semiconductors and perovskite nanocrystals2021

    • Author(s)
      Vacha Martin
    • Organizer
      2021 International Chemical Congress of Pacific Basin Societies
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Single-Molecule Spectroscopy in Physics and Chemistry of Materials: From Conjugated Polymers and Perovskite Nanocrystals to Photosynthetic Systems2021

    • Author(s)
      Vacha Martin
    • Organizer
      RIES-Hokudai International Symposium
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Excitonic coupling phenomenon directly revealed on single chains of polyfluorene by combined force spectroscopy and fluorescence microscopy2021

    • Author(s)
      Vacha Martin
    • Organizer
      30th International Conference on Photochemistry
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Remarks] Vacha研究室

    • URL

      http://vacha.mat.mac.titech.ac.jp/

    • Related Report
      2023 Annual Research Report
  • [Remarks] Vacha研究室

    • URL

      http://www.op.titech.ac.jp/lab/vacha/index.html

    • Related Report
      2022 Annual Research Report

URL: 

Published: 2019-04-18   Modified: 2025-01-30  

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