| Budget Amount *help |
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2022: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2021: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2020: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2019: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
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| Outline of Final Research Achievements |
The aim of this work is development of circular lanthanide-based open cages with high flexibility in response to guest up take events. The resulting open cage systems are capable of recognizing a wide range of nanoscale molecular guests. The lnathanide complexes have a unique coordination property, that is, their coodrnation vector is highly flexible and therefore capable of changing the coordination angle depending on the changes in coordination environments. As a typical result of this work, this study revealed a long-range chirality recognition mechanism using the diketonate ligands with long spacer unit as a mediator of the chiral recognition (Chem. Sci. 2021).
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