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Hierarchical Heterogeneity and Stress Distribution in Polymer Network Systems by Spatio-Temporal Mapping Analysis

Research Project

Project/Area Number 19H02780
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 35020:Polymer materials-related
Research InstitutionKyushu University

Principal Investigator

Shundo Atsuomi  九州大学, 工学研究院, 准教授 (40585915)

Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2021: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2020: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2019: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000)
Keywords高分子 / ナノレオロジー / 動的不均一性 / 応力集中 / ガラス / 協同運動再配置領域 / 破壊 / 温度時間換算則 / ソフトマテリアル / 濃度揺らぎ / 粒子追跡法 / デフォーカスイメージング / 不均一性 / ネットワーク / 力学物性 / ナノコンポジット
Outline of Research at the Start

本研究では、(1) 高分子ネットワークの形成・固化過程における不均一性と応力分布の関係、および(2) 応力分布とタフネス性・寿命との関係を正確に理解し、力学物性が精密に制御された材料の設計原理・指針を創出することを目的とした。そのアプローチとして、(1) 量子ドットをプローブとした時空間マッピング解析に基づく様々な時空間スケールにおける不均一性の可視化、および(2) メカノクロミズム分子を用いた応力分布の可視化を提案した。

Outline of Final Research Achievements

To visualize a density fluctuation and a spatial heterogeneity, thermal motion of the probe particles dispersed in polymer liquid and solution has been analyzed. As a result, they were spatially heterogeneous in terms of the physical properties when the observation time scale was shorter than relaxation time. Also, the network formation process was accompanied by the changes in the extent and the length scale of the heterogeneity. Such a change in the heterogeneity was related to the stress distribution. thereby toughness and fracture behavior of the resultant materials.

Academic Significance and Societal Importance of the Research Achievements

高分子ネットワークは樹脂やゴム、ゲル等の様々な材料にみられる構造であり、シーリング材、接着剤、構造材料等として広く用いられている。安全性や信頼性の確保・向上に向けて、材料の靭性や寿命の予測・制御が強く求められているが、それには至っていないのが現状である。本研究で得られた不均一性と応力分布、延性・破壊挙動に関する科学的知見は、力学特性や破壊挙動の制御、寿命予測に資するものと期待される。

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (46 results)

All 2021 2020 2019 Other

All Int'l Joint Research (1 results) Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results) Presentation (34 results) (of which Int'l Joint Research: 5 results,  Invited: 3 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] National Cheng Kung University(中国)

    • Related Report
      2020 Annual Research Report
  • [Journal Article] Effect of Cross-Linking Density on Horizontal and Vertical Shift Factors in Linear Viscoelastic Functions of Epoxy Resins2021

    • Author(s)
      Shundo Atsuomi、Aoki Mika、Yamamoto Satoru、Tanaka Keiji
    • Journal Title

      Macromolecules

      Volume: 54 Issue: 20 Pages: 9618-9624

    • DOI

      10.1021/acs.macromol.1c01293

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cross-Linking Effect on Segmental Dynamics of Well-Defined Epoxy Resins2021

    • Author(s)
      Shundo Atsuomi、Aoki Mika、Yamamoto Satoru、Tanaka Keiji
    • Journal Title

      Macromolecules

      Volume: 54 Issue: 13 Pages: 5950-5956

    • DOI

      10.1021/acs.macromol.1c00513

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spatial Heterogeneity Accompanying Gel Formation of Poly(N-isopropylacrylamide) Aqueous Solution at a Temperature below Cloud Point2020

    • Author(s)
      Takuro Kogo, Atsuomi Shundo, Chi Wang, and Keiji Tanaka
    • Journal Title

      Macromolecules

      Volume: 53 Issue: 24 Pages: 10964-10971

    • DOI

      10.1021/acs.macromol.0c02292

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of Heterogeneous Network on Glass Transition Dynamics and Solvent Crack Behavior of Epoxy Resins2020

    • Author(s)
      Mika Aoki, Atsuomi Shundo, Satoru Yamamoto, Keiji Tanaka
    • Journal Title

      Soft Matter

      Volume: 16 Issue: 32 Pages: 7470-7478

    • DOI

      10.1039/d0sm00625d

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Time-dependent Heterogeneity in Polyacrylic Pressure Sensitive Adhesive2020

    • Author(s)
      Yihao Wu, Atsuomi Shundo, Yuji Yasukochi and Keiji Tanaka
    • Journal Title

      European Polymer Journal

      Volume: 134 Pages: 109812-109812

    • DOI

      10.1016/j.eurpolymj.2020.109812

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mesoscopic heterogeneity in a nanocellulose-containing cell storage medium2020

    • Author(s)
      Shundo Atsuomi、Matsumoto Yuji、Hayashi Hisato、Tsuruzoe Nobutomo、Matsuno Hisao、Tanaka Keiji
    • Journal Title

      Journal of Materials Chemistry B

      Volume: 8 Issue: 21 Pages: 4570-4574

    • DOI

      10.1039/d0tb00219d

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of the Heterogeneous Structure on Mechanical Properties for a Nanocellulose-Reinforced Polymer Composite2019

    • Author(s)
      Yuji Matsumoto, Atsuomi Shundo, Hisato Hayashi, Nobutomo Tsuruzoe, Keiji Tanaka
    • Journal Title

      Macromolecules

      Volume: 52 Pages: 8266-8274

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Segregation of an Amine Component in a Model Epoxy Resin at a Copper Interface2019

    • Author(s)
      Mika Aoki, Atsuomi Shundo, Kenji Okamoto, Tatsuya Ganbe, Keiji Tanaka
    • Journal Title

      Polymer Journal

      Volume: 51 Pages: 359-363

    • NAID

      40021935799

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mesoscopic Heterogeneity in the Curing Process of an Epoxy-Amine System2019

    • Author(s)
      Mika Aoki, Atsuomi Shundo, Ruichi Kuwahara, Ssatoru Yamamoto, Keiji Tanaka
    • Journal Title

      Macromolecules

      Volume: 52 Pages: 2075-2082

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] 超分子ファイバー含有高分子コンポジットの凝集状態と力学特性2021

    • Author(s)
      春藤淳臣、吉田萌華、田中敬二
    • Organizer
      2021年繊維学会年次大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] エポキシ硬化物の力学特性に及ぼすアミン系硬化剤の級数の影響2021

    • Author(s)
      武谷亮佑、春藤淳臣、山本智、田中敬二
    • Organizer
      第58回化学関連支部合同九州大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] エポキシガラスの不均一性とソルベントクラック挙動の関係2021

    • Author(s)
      春藤淳臣、青木美佳、山本智 、田中敬二
    • Organizer
      東京大学物性研究所短期研究会「ガラスおよび関連する複雑系の最先端研究」
    • Related Report
      2021 Annual Research Report
  • [Presentation] エポキシ硬化物における化学量論比がネットワークおよび力学特性に及ぼす影響2021

    • Author(s)
      光木紘介、春藤淳臣、山本智、田中敬二
    • Organizer
      令和3年度九州地区高分子若手研究会・夏の講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Evolution of heterogeneity and gelation of poly(N-sopropylacrylamide) aqueous solution at a temperature below cloud point2021

    • Author(s)
      Takuro Kogo, Atsuomi Shundo, Chi Wang, Keiji Tanaka
    • Organizer
      25th Congress of the International Union of Crystallography
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 異なる硬化過程を経由したエポキシ樹脂の不均一構造が引張特性に与える影響2021

    • Author(s)
      青木美佳、春藤淳臣、山本智、星野大樹、田中敬二
    • Organizer
      第70回高分子討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] エポキシ樹脂の不均一硬化過程と力学特性2021

    • Author(s)
      伊田怜也、春藤淳臣、山本智、田中敬二
    • Organizer
      第70回高分子討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] エポキシ硬化物中の架橋点がセグメント運動に及ぼす影響2021

    • Author(s)
      春藤淳臣、青木美佳、山本智、田中敬二
    • Organizer
      第69回レオロジー討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Off-stoichiometry Effect on Network Structure and Tensile Properties of an Epoxy Resin2021

    • Author(s)
      Kosuke Mitsuki, Atsuomi Shundo, Satoru Yamamoto, Keiji Tanaka
    • Organizer
      Fall Annual Meeting of The Polymer Society of Korea (PSK)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] エポキシ硬化物における化学量論比がネットワーク構造に及ぼす影響2021

    • Author(s)
      光木紘介、春藤淳臣、山本智、田中敬二
    • Organizer
      第11回 CSJ化学フェスタ2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] エポキシ硬化物における鎖延長剤が力学特性に及ぼす影響2021

    • Author(s)
      武谷亮佑、春藤淳臣、山本智、田中敬二
    • Organizer
      第11回 CSJ化学フェスタ2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] エポキシ硬化物におけるダングリング鎖が力学特性に及ぼす影響2021

    • Author(s)
      武谷亮佑、春藤淳臣、山本智、田中敬二
    • Organizer
      接着界面科学研究会PartⅦ第8回例会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 超分子ファイバー分散系の不均一性制御とフィラーとしての応用2021

    • Author(s)
      春藤淳臣、松本裕治、水流添暢智、田中敬二
    • Organizer
      2021年 繊維学会秋季研究発表会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Effect of Chemical Structure on Reaction Kinetics and Mechanical Properties of Epoxy-Amine Systems2021

    • Author(s)
      Nguyen Thao Phan, Mika Aoki, Atsuomi Shundo, Satoru Yamamoto, Keiji Tanaka
    • Organizer
      令和3年度高分子学会九州地区高分子若手研究会・冬の講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 水と接した高分子ヒドロゲル界面における分子鎖ダイナミクス2020

    • Author(s)
      春藤 淳臣、板垣 望、川口 大輔、田中 敬二
    • Organizer
      日本レオロジー学会第47年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Dynamics of Chains in a Hydrogel Film at Water Interface2020

    • Author(s)
      Atsuomi Shundo, Nozomi Itagaki, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Nanoscopic Heterogeneity in an Acrylic Adhesive2020

    • Author(s)
      Yihao Wu, Atsuomi Shundo, Keiji Tanaka
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Deformation-induced Change in Heterogeneity of a Polymer Network2020

    • Author(s)
      Atsuomi Shundo, Aoki Kawaguchi, Keiji Tanaka
    • Organizer
      第69回高分子討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Nanoscopic Density Fluctuation in a Polyacrylic Adhesive2020

    • Author(s)
      Yihao Wu, Atsuomi Shundo, Yuji Yasukochi, Keiji Tanaka
    • Organizer
      第68回レオロジー討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ジェランガムファイバー分散培地のメゾスコピックな不均一性と細胞浮遊性2020

    • Author(s)
      春藤淳臣、古後拓朗、畑中大輔、水流添暢智、田中敬二
    • Organizer
      2020年繊維学会秋季研究発表会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ソフトマテリアルの局所領域におけるレオロジー解析2020

    • Author(s)
      春藤淳臣
    • Organizer
      Materials Research Meeting Forum 2020
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 異なる硬化過程を経由したエポキシ樹脂の不均一性2019

    • Author(s)
      青木美佳、春藤淳臣、山本智、田中敬二
    • Organizer
      第68回高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 超分子ファイバー含有高分子複合膜の力学特性2019

    • Author(s)
      吉田萌華、春藤淳臣、田中敬二
    • Organizer
      第68回高分子学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ジェランガム含有培地の不均一性が細胞浮遊性に与える影響2019

    • Author(s)
      古後拓朗、春藤淳臣、畑中大輔、水流添暢智、田中敬二
    • Organizer
      レオロジー学会第46年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ジェランガム含有培地のメゾスコピックな不均一性とその制御2019

    • Author(s)
      春藤淳臣、松本裕治、水流添暢智、田中敬二
    • Organizer
      レオロジー学会第46年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 硬化過程の異なるエポキシ樹脂の膨潤破壊挙動2019

    • Author(s)
      青木美佳、春藤淳臣、山本智、田中敬二
    • Organizer
      第57回日本接着学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 超分子ファイバーで強化した高分子の力学物性2019

    • Author(s)
      吉田萌華、春藤淳臣、田中敬二
    • Organizer
      第57回日本接着学会年次大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] ナノファイバー分散系における空間不均一性とそれに基づく材料設計2019

    • Author(s)
      春藤淳臣
    • Organizer
      第56回化学関連支部合同九州大会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] 超分子ナノファイバー含有高分子複合材料の凝集状態と力学特性2019

    • Author(s)
      吉田萌華、春藤淳臣、田中敬二
    • Organizer
      第56回化学関連支部合同九州大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Heterogeneous Structure and Mechanical Properties of Nanocellulose Composites2019

    • Author(s)
      Atsuomi Shundo
    • Organizer
      Japan Taiwan Bilateral Polymer Symposium 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Nano-Rheological Properties in a Polymer Network under Deformation2019

    • Author(s)
      Aoki Kawaguchi, Atsuomi Shundo, Yuji Yasukochi, Keiji Tanaka
    • Organizer
      Korea-Japan Joint Symposium on Polymer Science 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 超分子ファイバーで強靭化した高分子複合膜の凝集状態と力学特性2019

    • Author(s)
      吉田萌華、戸谷匡康、春藤淳臣、田中敬二
    • Organizer
      第9回CSJ化学フェスタ2019
    • Related Report
      2019 Annual Research Report
  • [Presentation] Mesoscopic Heterogeneity in Cell Culture Medium Containing Nanocelluloses2019

    • Author(s)
      Atsuomi Shundo, Yuji Matsumoto, Hisato Hayashi, Nobutomo Tsuruzoe, Hisao Matsuno, Keiji Tana
    • Organizer
      2019 Pusan-Gyeongnam/Kyushu-Seibu Joint Symposium on High Polymer (19th) and Fiber (17th) Conference
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子ネットワークのナノスケールにおける空間不均一性2019

    • Author(s)
      川口碧生、春藤淳臣、安河内裕司、田中敬二
    • Organizer
      2019年 繊維学会秋季研究発表会
    • Related Report
      2019 Annual Research Report
  • [Book] 接着の技術誌2021

    • Author(s)
      春藤淳臣、田中敬二
    • Total Pages
      4
    • Publisher
      (一社) 日本接着学会
    • Related Report
      2021 Annual Research Report
  • [Patent(Industrial Property Rights)] 脂質ペプチド型ゲル化剤とポリアルキレンオキシドとを含有する高分子複合材料2019

    • Inventor(s)
      田中敬二、春藤淳臣、吉田萌華
    • Industrial Property Rights Holder
      田中敬二、春藤淳臣、吉田萌華
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2019-090206
    • Filing Date
      2019
    • Acquisition Date
      2019
    • Related Report
      2019 Annual Research Report

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Published: 2019-04-18   Modified: 2023-01-30  

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