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Syntheses and layer distance control of novel anode materials and improvement for performance of Na ion battery

Research Project

Project/Area Number 19H02818
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionKyushu Institute of Technology

Principal Investigator

MA TINGLI  九州工業大学, 大学院生命体工学研究科, 教授 (20380545)

Co-Investigator(Kenkyū-buntansha) 飯久保 智  九州大学, 総合理工学研究院, 教授 (40414594)
Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥17,420,000 (Direct Cost: ¥13,400,000、Indirect Cost: ¥4,020,000)
Fiscal Year 2021: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2020: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2019: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywordsナトリウムイオン電池 / 2D電極材料 / 層間制御 / 脱離機構 / 高性能化 / 低コスト化 / 新規材料の合成 / 電池の性能評価 / 2D材料 / 低温合成 / 電極評価 / 性能向上 / メカニズム解析 / 最適化 / 低コスト / 高性能 / 安定性 / 2D原子層材料 / ナノ空間制御 / ナトリウムイオン二次電池 / Na+の吸蔵・放出過程 / ナノ空間の制御 / 高性能負極材料の開発
Outline of Research at the Start

近年、ナトリウムイオン二次電池(SIBs)は、Naの資源的問題が無く、低コストであるため、大型蓄電デバイスの有力候補となっている。しかし、現在まで報告されたSIBsはNa+の吸蔵・放出が電極材料により制限され、その性能が低くて、実用化は難しい。本研究は優れた導電性、高い耐熱性及び構造の安定性をもつ新規な2D原子層材料のナノ空間を制御し、高性能のSIBsを創生することが目的である。本提案では、新規な複合炭化物を合成し、独自な方法でエッチングを行う。更に、ナノ空間を制御し、Na+の挿入、脱離機構を解明する。従来のSIBsより高いエネルギー容量及び優れた耐久性をもつナトリウムイオン電池を創生する。

Outline of Final Research Achievements

Recently, ambient-temperature sodium ion batteries (SIBs) have attracted extensive attention again and confirmed to be a promising alternative to LIBs due to the low cost, natural abundance and high energy densities, meeting the demands of large-scale electrical energy storage systems. This work developed 2D materials to applicate SIBs. The 2D composition and distinctive structure facilitate the rapid diffusion of Na+ and improve the charge transfer at the heterogeneous interface, providing sufficient space for volume expansion and improving anode materials’ structural stability. The results showed that our 2D material makes it a promising candidate for sodium storage.

Academic Significance and Societal Importance of the Research Achievements

本研究を実施することにより、今まで報告された負極材料より高性能な負極材料が開発できた。またNa+の挿入及び脱離の改善にも成功した。更に電池の充電、充放電サイクル寿命と安定性などについての有用性も確認できた。ナトリウムイオン電池の実用化ができれば、埋蔵量の制約がリチウムイオン二次電池より約3桁に緩和され、環境負荷とコストを大幅に低減できると期待される。またナトリウムイオン二次電池は低コストであるため、大型蓄電デバイスにも使用可能である。

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (20 results)

All 2022 2021 2020 2019 Other

All Int'l Joint Research (3 results) Journal Article (11 results) (of which Int'l Joint Research: 11 results,  Peer Reviewed: 11 results,  Open Access: 11 results) Presentation (3 results) Remarks (3 results)

  • [Int'l Joint Research] 中国計量大学(中国)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] 中国大連理工大学/中国計量大学(中国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] 中国大連理工大学(中国)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] A cross-linked tin oxide/polymer composite gel electrolyte with adjustable porosity for enhanced sodium ion batteries2022

    • Author(s)
      Zhao Yue、Liu Hongbin、Meng Xianhe、Liu Anmin、Chen Yun、Ma Tingli
    • Journal Title

      Chemical Engineering Journal

      Volume: 431 Pages: 133922-133922

    • DOI

      10.1016/j.cej.2021.133922

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] MOFs and their derivatives as Sn-based anode materials for lithium/sodium ion batteries2021

    • Author(s)
      Liu Kaiyuan、Li Chao、Yan Lijing、Fan Meiqiang、Wu Yechao、Meng Xianhe、Ma Tingli
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 9 Issue: 48 Pages: 27234-27251

    • DOI

      10.1039/d1ta06996a

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Bimetallic Sulfide SnS<sub>2</sub>/FeS<sub>2</sub> Nanosheets as High-Performance Anode Materials for Sodium-Ion Batteries2021

    • Author(s)
      Chen Yun、Liu Hongbin、Guo Xiaolin、Zhu Shangping、Zhao Yue、Iikubo Satoshi、Ma Tingli
    • Journal Title

      ACS Applied Materials &amp; Interfaces

      Volume: 13 Issue: 33 Pages: 39248-39256

    • DOI

      10.1021/acsami.1c08801

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Two-Dimensional Cu<sub>2</sub>MoS<sub>4</sub>-Loaded Silicon Nanospheres as an Anode for High-Performance Lithium-Ion Batteries2021

    • Author(s)
      Liu Hongbin、Chen Yun、Zhao Yue、Liu Kaiyuan、Guo Xiaolin、Meng Xianhe、Ma Tingli
    • Journal Title

      ACS Applied Energy Materials

      Volume: 4 Issue: 11 Pages: 13061-13069

    • DOI

      10.1021/acsaem.1c02697

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Two-dimensional CuAg/Ti3C2 catalyst for electrochemical synthesis of ammonia under ambient conditions: a combined experimental and theoretical study2020

    • Author(s)
      Liu Anmin、Yang Qiyue、Ren Xuefeng、Gao Mengfan、Yang Yanan、Gao Liguo、Li Yanqiang、Zhao Yingyuan、Liang Xingyou、Ma Tingli
    • Journal Title

      Sustainable Energy & Fuels

      Volume: 4 Issue: 10 Pages: 5061-5071

    • DOI

      10.1039/d0se00915f

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Significant effect of base assisted intercalates in synthesis of 2D semiconductor Ti3C2O22020

    • Author(s)
      Gao Liguo、Wang Ning、Cao Junmei、Li Yang、Ma Tingli
    • Journal Title

      Surfaces and Interfaces

      Volume: 20 Pages: 100604-100604

    • DOI

      10.1016/j.surfin.2020.100604

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Synthesis of 2D layered Nb2SnC at low sintering temperature and its application for high-performance supercapacitors2020

    • Author(s)
      Zhang Zhiguo、Huang Xiao、Lu Wenxin、Qiu Xinping、Ma Tingli、Xia Wu
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 288 Pages: 121425-121425

    • DOI

      10.1016/j.jssc.2020.121425

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hierarchical porous architectures derived from low-cost biomass equisetum arvense as a promising anode material for lithium-ion batteries2020

    • Author(s)
      Chen Yun、Liu Hongbin、Jiang Bo、Zhao Yue、Meng Xianhe、Ma Tingli
    • Journal Title

      Journal of Molecular Structure

      Volume: 1221 Pages: 128794-128794

    • DOI

      10.1016/j.molstruc.2020.128794

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hollow-structure engineering of a silicon-carbon anode for ultra-stable lithium-ion batteries2020

    • Author(s)
      Liu Hongbin、Chen Yun、Jiang Bo、Zhao Yue、Guo Xiaolin、Ma Tingli
    • Journal Title

      Dalton Transactions

      Volume: 49 Issue: 17 Pages: 5669-5676

    • DOI

      10.1039/d0dt00566e

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Electrostatic self-assembly of 2D delaminated MXene (Ti3C2) onto Ni foam with superior electrochemical performance for supercapacitor2019

    • Author(s)
      Guo Jing、Zhao Yingyuan、liu Anmin、Ma Tingli
    • Journal Title

      Electrochimica Acta

      Volume: 305 Pages: 164-174

    • DOI

      10.1016/j.electacta.2019.03.025

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] A black phosphorus/Ti3C2 MXene nanocomposite for sodium-ion batteries: a combined experimental and theoretical study2019

    • Author(s)
      Li Huan、Liu Anmin、Ren Xuefeng、Yang Yanan、Gao Liguo、Fan Meiqiang、Ma Tingli
    • Journal Title

      Nanoscale

      Volume: 11 Issue: 42 Pages: 19862-19869

    • DOI

      10.1039/c9nr04790e

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] A cross-linked tin oxide/polymer composite gel electrolyte with adjustable porosity for enhanced sodium-ion batteries2021

    • Author(s)
      趙 越, 劉 宏彬, 馬 廷麗
    • Organizer
      第62回電池討論会オンライン
    • Related Report
      2021 Annual Research Report
  • [Presentation] Equisetum arvense--Derived Hierarchical SiOx/C as Low Cost and Environmentally friendly Anodes for Lithium-Ion Batteries2021

    • Author(s)
      Yun Chen, Hongbin Liu, Bo Jiang, Tingli MA
    • Organizer
      電気化学会88大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Hollow-Structure Engineering of Silicon-Carbon Anode for Ultra-Stable Lithium-ion Batteries2021

    • Author(s)
      Hongbin Liu, Yun Chen, Zhao Yue, Bo Jiang, Tingli MA
    • Organizer
      電気化学会88大会
    • Related Report
      2020 Annual Research Report
  • [Remarks] 九州工業大学 大学院生命体工学研究科 本研究室のホームページ

    • URL

      http://www.life.kyutech.ac.jp/~tinglima/index.html

    • Related Report
      2021 Annual Research Report
  • [Remarks] 九州工業大学 大学院生命体工学研究科 本研究室のホームページ

    • URL

      http://www.life.kyutech.ac.jp/~tinglima/index.html

    • Related Report
      2020 Annual Research Report
  • [Remarks]

    • URL

      http://www.life.kyutech.ac.jp/~tinglima/

    • Related Report
      2019 Annual Research Report

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Published: 2019-04-18   Modified: 2023-01-30  

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