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Reconsideration of a role of RO2 uptake by aerosols in the atmospheric HOx cycle based on the kinetics study

Research Project

Project/Area Number 19H04255
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 63010:Environmental dynamic analysis-related
Research InstitutionKyoto University

Principal Investigator

Sakamoto Yosuke  京都大学, 地球環境学堂, 助教 (50747342)

Project Period (FY) 2019-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2022: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2021: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2020: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2019: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Keywords光化学オキシダント / エアロゾル / ラジカル取り込み速度 / HOxサイクル / オゾン生成速度 / PM / 不均一反応 / RO2ラジカル / 取り込み反応速度 / 取り込み係数 / オゾン / オキシダント / ペルオキシラジカル / HOxサイクル
Outline of Research at the Start

レーザーポンプ・レーザー誘起蛍光検出(LP-LIF)法を用い,RO2のエアロゾルへの取り込み係数を世界に先駆け測定する.そして得られる取り込み係数を基にボックスモデル計算を行いエアロゾル取り込み過程がHOXサイクルの回転効率に与える影響を計算し,そのオキシダント・二次エアロゾル生成における潜在的インパクトを評価することを目的とする.

Outline of Final Research Achievements

A method for determining the uptake coefficients of RO2 radicals onto aerosols by combining laser-pump radical generation and laser-induced fluorescence radical detection was established. The uptake coefficients of various RO2 radicals into inorganic and organic aerosols were examined in laboratory experiments. We also developed a method for direct determination of the uptake coefficients of RO2 onto atmospheric aerosols, and applied for determination of the uptake coefficients of isoprene-derived RO2 by atmospheric observation. Assuming that the obtained uptake coefficient of isoprene-derived RO2 onto atmospheric aerosol is representative, the ozone formation suppression effect up to 8.5% was estimated after sunrise under the observed conditions.

Academic Significance and Societal Importance of the Research Achievements

本研究によりRO2の取り込み係数の決定手法が確立され,また一部RO2について大気エアロゾルの取り込み係数を報告したため,今後はこれまで実験値が無く考慮されてこなかったRO2ラジカルのエアロゾルへの取り込み過程を大気モデルシミュレーションに実装する根拠が示された.本研究結果を基に,今後大気プロセスの中でRO2のエアロゾル取り込みがオキシダント・二次エアロゾル動態とどのように関わるか定量的に明らかにされると期待される.特に,我が国において前駆体削減に関わらず高止まりを続けているオゾン濃度について,ひとつの説明となることが期待される.

Report

(5 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (37 results)

All 2023 2022 2021 2020 2019

All Journal Article (12 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 12 results,  Open Access: 6 results) Presentation (25 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results)

  • [Journal Article] Determination of Uptake Coefficient of Isoprene-Derived Organic Peroxy Radical onto Ambient Particles Using Laser Spectroscopic Techniques2023

    • Author(s)
      坂本 陽介、Li Jiaru、河野 七瀬、中山 智喜、佐藤 圭、梶井 克純
    • Journal Title

      Journal of Japan Society for Atmospheric Environment / Taiki Kankyo Gakkaishi

      Volume: 58 Issue: 1 Pages: 1-9

    • DOI

      10.11298/taiki.58.1

    • ISSN
      1341-4178, 2185-4335
    • Year and Date
      2023-01-10
    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Study of Verification of Suppression Effect on Tropospheric Ozone Formation by Aerosol Particles and Source Identification of Unidentified and Difficult to Measure OH-reactive Substances2023

    • Author(s)
      坂本 陽介
    • Journal Title

      Journal of Japan Society for Atmospheric Environment / Taiki Kankyo Gakkaishi

      Volume: 58 Issue: 1 Pages: 35-45

    • DOI

      10.11298/taiki.58.35

    • ISSN
      1341-4178, 2185-4335
    • Year and Date
      2023-01-06
    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Determination of Uptake Coefficient of Peroxy Radical Loss by Aerosols Using HO<sub>x</sub> Reactivity Measurement Technique2022

    • Author(s)
      坂本 陽介
    • Journal Title

      Earozoru Kenkyu

      Volume: 37 Issue: 1 Pages: 5-11

    • DOI

      10.11203/jar.37.5

    • ISSN
      0912-2834, 1881-543X
    • Year and Date
      2022-03-20
    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Chemical Characterization and Health Risk Assessment of Particulate Matter from Household Activities in Bamako, Mali, Western Sub-Saharan Africa2022

    • Author(s)
      Sidibe Alimata、Sakamoto Yosuke、Murano Kentaro、Sato Keiichi、Yuba Akie、Futami Mari、Koita Ousmane A.、Traore Ibrahim、Kajii Yoshizumi
    • Journal Title

      Atmosphere

      Volume: 13 Issue: 8 Pages: 1290-1290

    • DOI

      10.3390/atmos13081290

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Impacts of missing OH reactivity and aerosol uptake of HO2 radicals on tropospheric O3 production during the AQUAS-Kyoto summer campaign in 20182022

    • Author(s)
      N. Kohno, J. Zhou, J. Li, M. Takemura, N. Ono, Y. Sadanaga, Y. Nakashima, K. Sato, S. Kato, Y. Sakamoto, Y. Kajii
    • Journal Title

      Atmospheric Environment

      Volume: 281 Pages: 119130-119130

    • DOI

      10.1016/j.atmosenv.2022.119130

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Potential Factors Contributing to Ozone Production in AQUAS?Kyoto Campaign in Summer 2020: Natural Source-Related Missing OH Reactivity and Heterogeneous HO<sub>2</sub>/RO<sub>2</sub> Loss2022

    • Author(s)
      Li Jiaru、Kohno Nanase、Sakamoto Yosuke、Pham Huy Gia、Murano Kentaro、Sato Kei、Nakayama Tomoki、Kajii Yoshizumi
    • Journal Title

      Environmental Science &amp; Technology

      Volume: 56 Issue: 18 Pages: 12926-12936

    • DOI

      10.1021/acs.est.2c03628

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of OH-reactivity budget in the isoprene, α-pinene and m-xylene oxidation with OH under high NOx conditions2022

    • Author(s)
      Sakamoto Yosuke、Kohno Nanase、Ramasamy Sathiyamurthi、Sato Kei、Morino Yu、Kajii Yoshizumi
    • Journal Title

      Atmospheric Environment

      Volume: 271 Pages: 118916-118916

    • DOI

      10.1016/j.atmosenv.2021.118916

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics and impacting factors of HO&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt; uptake onto submicron atmospheric aerosols during the 2019 Air QUAlity Study (AQUAS) in Yokohama, Japan2021

    • Author(s)
      Zhou Jun、Sato Kei、Bai Yu、Fukusaki Yukiko、Kousa Yuka、Ramasamy Sathiyamurthi、Takami Akinori、Yoshino Ayako、Nakayama Tomoki、Sadanaga Yasuhiro、Nakashima Yoshihiro、Li Jiaru、Murano Kentaro、Kohno Nanase、Sakamoto Yosuke、Kajii Yoshizumi
    • Journal Title

      Atmospheric Chemistry and Physics

      Volume: 21 Issue: 16 Pages: 12243-12260

    • DOI

      10.5194/acp-21-12243-2021

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] A quantitative understanding of total OH reactivity and ozone production in a coastal industrial area during the Yokohama air quality study (AQUAS) campaign of summer 20192021

    • Author(s)
      Li Jiaru、Kohno Nanase、Sakamoto Yosuke、Fukusaki Yukiko、Kousa Yuka、Sadanaga Yasuhiro、Nakashima Yoshihiro、Sato Kei、Ramasamy Sathiyamurthi、Takami Akinori、Yoshino Ayako、Nakayama Tomoki、Kato Shungo、Ono Natsuki、Zhou Jun、Bai Yu、Kajii Yoshizumi
    • Journal Title

      Atmospheric Environment

      Volume: 267 Pages: 118754-118754

    • DOI

      10.1016/j.atmosenv.2021.118754

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rate constants of CH3O2 + NO2 CH3O2NO2 and C2H5O2 + NO2 C2H5O2NO2 reactions under atmospheric conditions2020

    • Author(s)
      Kohno Nanase、Li Jiaru、Sakamoto Yosuke、Kajii Yoshizumi
    • Journal Title

      International Journal of Chemical Kinetics

      Volume: 53 Issue: 5 Pages: 571-582

    • DOI

      10.1002/kin.21466

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Real-time quantification of the total HO2 reactivity of ambient air and HO2 uptake kinetics onto ambient aerosols in Kyoto (Japan)2020

    • Author(s)
      Jun Zhou, Kentaro Murano, Nanase Kohno, Yosuke Sakamoto and Yoshizumi Kajii
    • Journal Title

      Atmospheric Environment

      Volume: 223 Pages: 117189-117189

    • DOI

      10.1016/j.atmosenv.2019.117189

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relative and Absolute Sensitivity Analysis on Ozone Production in Tsukuba, a City in Japan2019

    • Author(s)
      Yosuke Sakamoto, Yasuhiro Sadanaga, Jiaru Li, Kohei Matsuoka, Marina Takemura, Tomihide Fujii, Maho Nakagawa, Nanase Kohno, Yoshihiro Nakashima, Kei Sato, Tomoki Nakayama, Shungo Kato, Akinori Takami, Ayako Yoshino, Kentaro Murano and Yoshizumi Kajii
    • Journal Title

      Environmental Science & Technology

      Volume: 53 Issue: 23 Pages: 13629-13635

    • DOI

      10.1021/acs.est.9b03542

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] OH/HO2 uptake coefficient onto various polydisperse aerosols determined by combining laser-pump and laser-induced fluorescence2022

    • Author(s)
      Jiaru Li; Yosuke Sakamoto; Kei Sato; Yoshizumi Kajii
    • Organizer
      The iCACGP-IGAC 2022 Conference
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] エアロゾルへの有機過酸化ラジカル取り込みによる対流圏オゾン生成抑制効果のHOx反応性測定に基づく定量的評価2022

    • Author(s)
      坂本陽介、黎珈汝、河野七瀬、中山智喜、佐藤圭、梶井克純
    • Organizer
      第63回 大気環境学会年会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 都市域における有機硝酸の観測および有機硝酸生成がオゾン生成に与える影響2022

    • Author(s)
      定永靖宗、河野七瀬、黎珈汝、坂本陽介、中嶋吉弘、加藤俊吾、佐藤圭、中山智喜、梶井克純
    • Organizer
      第63回 大気環境学会年会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 数値モデルによるオゾン生成速度・生成レジームの再現性検証2022

    • Author(s)
      森野悠、佐藤圭、坂本陽介、定永靖宗、梶井克純
    • Organizer
      第63回 大気環境学会年会
    • Related Report
      2022 Annual Research Report
  • [Presentation] オゾン生成に対する自然エミッションとエアロ ゾルによるHO2/RO2取り込みの影響ーー2020年 京都における夏季観測を例として2022

    • Author(s)
      黎珈汝、河野七瀬、坂本陽介、村野健太郎、佐藤圭、中山智喜、梶井克純
    • Organizer
      第63回 大気環境学会年会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 2020 年夏季京都市内におけるオゾン生成レジー ムの実測による評価2022

    • Author(s)
      村岡 達也, 定永 靖宗 , 野尻 亮太, 大原 和, 河野 七瀬 , 黎 珈汝 , 坂本 陽介 , 中嶋 吉弘, 佐 藤 圭, 加藤 俊吾 , 中山 智喜, 松岡 雅也, 椎木 弘, 梶井 克純
    • Organizer
      第63回 大気環境学会年会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 湿潤条件における無機エアロゾルへのイソプレン由来 過酸化ラジカルの取り込み係数決定因子の考察2022

    • Author(s)
      坂本陽介, Jiaru Li, 河野七瀬, 佐藤圭,梶井克純
    • Organizer
      第27回大気化学討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Uptake coefficients of OH and HO2 radicals onto polydisperse aerosols determined by combining laser-pump and laser-induced fluorescence2022

    • Author(s)
      Li Jiaru, Sakamoto Yosuke, Kei Sato, Murano Kentaro, Kajii Yoshizumi
    • Organizer
      第27回大気化学討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Investigation of gaseous and heterogeneous reactions of RO2 radicals using FAGE-LIF method2021

    • Author(s)
      河野 七瀬、Li Jiaru、坂本 陽介、梶井 克純
    • Organizer
      Japan Geoscience Union Meeting 2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] Real-time measurement of HO2 and RO2 uptake loss rate onto ambient particles during AQUAS-Kyoto summer campaign in 20202021

    • Author(s)
      坂本 陽介、Bai Yu、Jiaru Li、河野 七瀬、梶井 克純
    • Organizer
      Japan Geoscience Union Meeting 2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] 大気中過酸化ラジカル(HO2及びRO2)の化学ダイナミクス研究 -オゾン生成機構の完全理解とエアロゾル変質過程の解明に向けて2021

    • Author(s)
      梶井 克純、坂本 陽介、河野 七瀬、佐藤 圭、森野 悠、吉野 彩子、高見 昭憲、定永 靖宗
    • Organizer
      第62回 大気環境学会年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] PERCA-CAPS 法による過酸化ラジカルの測定およびオゾン生成速度測定への応用2021

    • Author(s)
      江上 孝一、 坂本 陽介、 定永 靖宗、 梶井 克純
    • Organizer
      第62回 大気環境学会年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] つくば、横浜および京都における総 OH 反応性とオゾン生成に関する大気質研究2021

    • Author(s)
      黎 珈汝,、河野 七瀬、坂本 陽介、村野 健太郎、梶井 克純
    • Organizer
      第62回 大気環境学会年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 未知OH反応性とエアロゾルへのラジカル取り込みを考慮した 2020 年 9 月の京都市におけるオゾン生成レジーム判定2021

    • Author(s)
      Pham Gia Huy、河野 七瀬、坂本 陽介、梶井 克純
    • Organizer
      第62回 大気環境学会年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 大気化学モデルを用いた大気酸化反応系でのOH反応性予測における準揮発性有機化合物の不均一消失の影響2021

    • Author(s)
      坂本 陽介、佐藤 圭、森野 悠、河野 七 瀬、梶井 克純
    • Organizer
      第26回大気化学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] How do missing OH reactivity and heterogeneous HO2/RO2 radicals loss affect ozone production during the 2020 AQUAS (Air QUAlity Study) Kyoto campaign?2021

    • Author(s)
      Li Jiaru、Kohno Nanase、Sakamoto Yosuke、Murano Kentaro、Kajii Yoshizumi
    • Organizer
      第26回大気化学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Determination of the rate constants of CH3O2 + NO2 and C2H5O2 + NO2 reaction2021

    • Author(s)
      Nanase KOHNO、Jiaru LI、Yosuke SAKAMOTO、Yoshizumi KAJII
    • Organizer
      Pacifichem 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Determination of reaction rate constants of CH3O2 + NO2 + M ? CH3O2NO2 + M and C2H5O2 + NO2 + M ? C2H5O2NO2 + M under atmospheric conditions2021

    • Author(s)
      Nanase Kohno、Jiaru Li、Yosuke Sakamoto、Yoshizumi Kajii
    • Organizer
      36th Symposium on Chemical Kinetics and Dynamics
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of heterogeneous radical loss on ozone production in Kyoto, a case study in Japan2021

    • Author(s)
      Jiaru Li、Nanase Kohno、Yosuke Sakamoto、Kentaro Murano、Yoshizumi Kajii
    • Organizer
      6th International Workshop on Heterogeneous Kinetics Related to Atmospheric Aerosols
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] FAGE-LIF法を用いたRO2ラジカルの検出およびNO2との反応速度定数の決定2020

    • Author(s)
      河野七瀬, LI Jiaru, 坂本陽介, 坂本陽介, 梶井克純, 梶井克純
    • Organizer
      第61回大気環境学会年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] HOx反応性観測を基にしたエアロゾル-オゾン生成間相互作用に関する研究2020

    • Author(s)
      坂本陽介, ZHOU Jun, 河野七瀬, 梶井克純
    • Organizer
      第61回大気環境学会年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] The investigation of HO2 uptake kinetics onto ambient aerosols in East Asia2019

    • Author(s)
      Jun Zhou, Yukiko Fukusaki, Yu Bai , Alimata Sidibe, Nanase Kohno , Kentaro Murano, Yosuke Sakamoto, Yoshizumi Kajii
    • Organizer
      European Aerosol Conference 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] HO2ラジカルの大気エアロゾルへの取り込み速度の測定2019

    • Author(s)
      坂本 陽介, Jun Zhou, 小野 夏樹, 河野 七瀬, 梶井 克純
    • Organizer
      第24回大気化学討論会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Development of a new method for selective detection of ROx radicals and determination of radical yields2019

    • Author(s)
      Kohno, Nanase; Li, Jiaru; Zhou, Jun; Murano, Kentaro; Sakamoto, Yosuke; Kajii, Yoshizumi
    • Organizer
      35th Symposium on Chemical Kinetics and Dynamics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] エアロゾルとHOxサイクルの相互作用2019

    • Author(s)
      梶井 克純,小野 夏樹,Jun Zhou,河野 七瀬,坂本 陽介
    • Organizer
      第60回大気環境学会年会
    • Related Report
      2019 Annual Research Report

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Published: 2019-04-18   Modified: 2024-01-30  

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