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Development of ultra-high resolution X-ray diffraction method in the range from micro eV to nano eV and its application to dynamics studies

Research Project

Project/Area Number 19H04404
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 80040:Quantum beam science-related
Research InstitutionNational Institutes for Quantum Science and Technology

Principal Investigator

Takaya Mitsui  国立研究開発法人量子科学技術研究開発機構, 関西光科学研究所 放射光科学研究センター, 上席研究員 (20354988)

Co-Investigator(Kenkyū-buntansha) 大和田 謙二  国立研究開発法人量子科学技術研究開発機構, 関西光科学研究所 放射光科学研究センター, グループリーダー (60343935)
Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Fiscal Year 2021: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2020: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2019: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
Keywords放射光 / 核共鳴散乱 / メスバウアー分光 / X線非弾性散乱 / X線回折 / 量子ビーム / 非弾性散乱 / メスバウアー効果 / 超高分解能測定 / 誘電体 / 量子ダイナミクス / スバウアー分光法 / 超高分解能 / 動力学効果 / X線光学 / フォノン
Outline of Research at the Start

本研究は、バンド幅可変の核分光器で放射光から生成したμeV~neV領域の超単色X線を用
いて、物質のダイナミクス研究に資する超高エネルギー分解能X線回折法を創出させるもの
である。その応用研究として、ミクロン程度まで集光した超単色X線による強誘電体ドメイ
ンダイナミクスの局所解析や平面波の超単色X線による完全単結晶(Si, Ge等)のブラッグ反射付近に生じる熱散漫散乱の動力学的回折現象や非調和熱振動効果の検証実験を行う。

Outline of Final Research Achievements

A synchrotron radiation based ultrahigh resolution spectrometer was developed by an variable bandwidth iron-57 synchrotron Mossbauer radiation and a nuclear resonant absorber. It is possible to separate elastic and inelastic scattering components from the scattered radiation, and also to measure the ultrahigh energy resolution inelastic X-ray scattering spectrum in the wide dynamic range. As a notable application, dynamical diffraction effects of thermal diffuse scattering on Si (111) Bragg reflection were observed for the first time using plane wave Mossbauer γ-rays, whose angular divergence was better than 1.0 arcsecond. The measurements are impossible with non-directed γ-rays from conventional radioactive isotopes. A variable bandwidth iron-57 synchrotron Mossbauer radiation will open up new possibilities of advanced dynamics studies with an ultra-high resolution in the range from μeV to neV.

Academic Significance and Societal Importance of the Research Achievements

バンド幅可変核モノクロメーターによる放射光超単色X線の生成とその応用研究は、世界的に例がなく、本研究で開発したμeV~neV領域の超高エネルギー分解能X線回折分光法は、液体、固体のスローダイナミクス研究の格段の進展につながる革新的量子ビーム利用技術である。今後、開発した計測法が、半導体、誘電体などの単結晶材料から高分子、生体物質のソフトマター物質の機能発現メカニズムの解明を目指した研究に利用展開されることが期待される。

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (35 results)

All 2022 2021 2020 2019 Other

All Journal Article (20 results) (of which Peer Reviewed: 19 results,  Open Access: 1 results) Presentation (13 results) (of which Int'l Joint Research: 3 results,  Invited: 6 results) Remarks (2 results)

  • [Journal Article] Direct Observation of Magnetic Friedel Oscillation at the Fe (001) Surface2022

    • Author(s)
      三井 隆也、境 誠司、瀬戸 誠、赤井 久純
    • Journal Title

      Butsuri

      Volume: 77 Issue: 1 Pages: 23-28

    • DOI

      10.11316/butsuri.77.1_23

    • NAID

      130008139657

    • ISSN
      0029-0181, 2423-8872
    • Year and Date
      2022-01-05
    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamical Effects on Thermal Diffuse Scattering in Si 111 Bragg Reflection2022

    • Author(s)
      Mitsui Takaya、Fujiwara Kosuke、Imai Yasuhiko、Yoda Yoshitaka
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 91 Issue: 3

    • DOI

      10.7566/jpsj.91.035002

    • NAID

      210000188950

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rayleigh Scattering of Synchrotron Mossbauer Radiation Using a Variable Bandwidth Nuclear Bragg Monochromator2022

    • Author(s)
      Mitsui Takaya、Masuda Ryo、Kitao Shinji、Kobayashi Yasuhiro、Seto Makoto
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 91 Issue: 6

    • DOI

      10.7566/jpsj.91.064001

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature dependence of site-resolved Fe magnetic moments in ThMn12-type Sm(Fe1-xCox )12 compounds studied via synchrotron Mossbauer spectroscopy2022

    • Author(s)
      Ogawa D.、Fukazawa T.、Li S.、Ueno T.、Sakai S.、Mitsui T.、Miyake T.、Okamoto S.、Hirosawa S.、Takahashi Y.K.
    • Journal Title

      Journal of Magnetism and Magnetic Materials

      Volume: 552 Pages: 169188-169188

    • DOI

      10.1016/j.jmmm.2022.169188

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 161Dy synchrotron-radiation-based Mossbauer absorption spectroscopy2022

    • Author(s)
      Masuda Ryo、Kitao Shinji、Tajima Hiroyuki、Taniguchi Hiroki、Mitsui Takaya、Fujiwara Kosuke、Yoda Yoshitaka、Nagasawa Nobumoto、Ishikawa Daisuke、Baron Alfred. Q. R.、Yoshida Takefumi、Sato Tetsu、Katoh Keiichi、Kobayashi Hisao、Seto Makoto
    • Journal Title

      Hyperfine Interactions

      Volume: 243 Issue: 1 Pages: 1-8

    • DOI

      10.1007/s10751-022-01802-5

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 斜入射放射光メスバウアー分光法による鉄基薄膜の局所磁性探査 - 鉄表面の磁気フリーデル振動の観測に成功 -2022

    • Author(s)
      三井隆也
    • Journal Title

      放射光学会誌 「放射光」

      Volume: 77 Pages: 23-28

    • NAID

      40022827640

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mossbauer spectroscopy with polarized synchrotron beams at Fe/Au (111) interface2021

    • Author(s)
      Okabayashi Jun、Li Songtian、Sakai Seiji、Kobayashi Yasuhiro、Fujiwara Kosuke、Mitsui Takaya、Mitani Seiji
    • Journal Title

      Hyperfine Interactions

      Volume: 242 Issue: 1 Pages: 1-8

    • DOI

      10.1007/s10751-021-01788-6

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct observation of magnetic Friedel oscillation at Fe(001) surface2021

    • Author(s)
      Mitsui Takaya、Sakai Seiji、Li Songtian、Ueno Tetsuro、Watanuki Tetsu、Kobayashi Yasuhiro、Masuda Ryo、Seto Makoto、Akai Hisazumi
    • Journal Title

      Hyperfine Interactions

      Volume: 242 Issue: 1 Pages: 1-15

    • DOI

      10.1007/s10751-021-01772-0

    • NAID

      130008139657

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pure nuclear Bragg reflection due to combined magnetic and quadrupole interaction in Fe<sub>3</sub>O<sub>4</sub>2021

    • Author(s)
      Nakamura Shin、Mitsui Takaya、Kurokuzu Masayuki、Shimomura Susumu
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 90 Issue: 10 Pages: 104713-104713

    • DOI

      10.7566/jpsj.90.104713

    • NAID

      40022709417

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantum Interference of Totally Reflected Mossbauer γ-Rays from a 57Fe Monolayer Embedded in a Thin Film2021

    • Author(s)
      Fujiwara Kosuke、Mitsui Takaya、Aoyagi Yumito、Yoda Yoshitaka、Ikeda Naoshi
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 90 Issue: 8 Pages: 084705-084705

    • DOI

      10.7566/jpsj.90.084705

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Element-specific magnetic hysteresis loops observed in hexagonal ErFeO3 thin films2021

    • Author(s)
      Yokota Hiroko、Kobori Yu、Jitsukawa Shunsuke、Sakai Seiji、Takeda Yukiharu、Mitsui Takaya、Kobayashi Yasuhiro、Kitao Shinji
    • Journal Title

      Materials Research Express

      Volume: 8 Issue: 8 Pages: 086402-086402

    • DOI

      10.1088/2053-1591/ac1aa9

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synchrotron Mossbauer spectroscopic and x-ray diffraction study of ferropericlase in the high-pressure range of the lower mantle region2021

    • Author(s)
      Hamada Maki、Kamada Seiji、Ohtani Eiji、Sakamaki Tatsuya、Mitsui Takaya、Masuda Ryo、Hirao Naohisa、Ohishi Yasuo、Akasaka Masahide
    • Journal Title

      Physical Review B

      Volume: 103 Issue: 17 Pages: 1-9

    • DOI

      10.1103/physrevb.103.174108

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mixed-valence state and structure changes of EuH (x=2 and 2<x<3) under high-pressure H2 atmosphere2021

    • Author(s)
      Kuno Keiji、Matsuoka Takahiro、Masuda Ryo、Mitsui Takaya、Seto Makoto、Machida Akihiko、Fujihisa Hiroshi、Hirao Naohisa、Ohishi Yasuo、Shimizu Katsuya、Sasaki Shigeo
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 865 Pages: 158637-158637

    • DOI

      10.1016/j.jallcom.2021.158637

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Perpendicular magnetic anisotropy at Fe/Au(111) interface studied using Mossbauer, x-ray absorption, and photoemission spectroscopies2021

    • Author(s)
      J. Okabayashi, S. Li, S. Sakai, Y. Kobayashi, T. Mitsui, K. Tanaka and S. Mitani
    • Journal Title

      Phys. Rev. B

      Volume: 103 Issue: 10

    • DOI

      10.1103/physrevb.103.104435

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synchrotron mössbauer diffraction of natural iron Fe<sub>3</sub>BO<sub>6</sub>2020

    • Author(s)
      Nakamura Shin、Mitsui Takaya、Kobayashi Yasuhiro、Kurokuzu Masayuki、Shimomura Susumu
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 89 Issue: 12 Pages: 125001-125001

    • DOI

      10.7566/jpsj.89.125001

    • NAID

      210000158671

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Friedel Oscillation at the Fe(001) Surface: Direct Observation by Atomic-Layer-Resolved Synchrotron Radiation Fe57 Mossbauer Spectroscopy2020

    • Author(s)
      T. Mitsui 、S. Sakai、S. Li 、T. Ueno、T. Watanuk、Y. Kobayashi、R. Masuda、M. Seto M、H. Akai
    • Journal Title

      Physical Review Letters

      Volume: 125 Issue: 23

    • DOI

      10.1103/physrevlett.125.236806

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Simultaneous Measurement of γ-ray and Conversion Electron Mossbauer Spectra of Fe Films under Total Reflection Conditions Using Synchrotron Mossbauer Source2020

    • Author(s)
      Mitsui Takaya、Mibu Ko、Tanaka Masaaki、Kitao Shinji、Kobayashi Yasuhiro、Masuda Ryo、Seto Makoto
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 89 Issue: 5 Pages: 0547071-6

    • DOI

      10.7566/jpsj.89.054707

    • NAID

      40022226629

    • Related Report
      2020 Annual Research Report 2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synchrotron-radiation-based Mossbauer absorption spectroscopy with high resonant energy nuclides2019

    • Author(s)
      Ryo Masuda, Kohei Kusada, Takefumi Yoshida, Shinji Michimura, Yasuhiro Kobayashi, Shinji Kitao, Hiroyuki Tajima, Takaya Mitsui, Hirokazu Kobayashi, Hiroshi Kitagawa, Makoto Seto
    • Journal Title

      Hyperfine Interactions

      Volume: 240 Issue: 1 Pages: 120-120

    • DOI

      10.1007/s10751-019-1672-x

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mossbauer Spectroscopy Study of KxFe2-ySe2 under Pressure2019

    • Author(s)
      Yoshiya Yamamoto, Takaya Mitsui, Shinji Kitao, Makoto Seto, Naoyuki Mizobata, Toshinori Ozaki, Hitoshi Yamaoka, Jun’ichiro Mizuki
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 88 Issue: 12 Pages: 124703-124703

    • DOI

      10.7566/jpsj.88.124703

    • Related Report
      2019 Annual Research Report
  • [Journal Article] The first observation of pure nuclear Bragg reflection from natural iron α-Fe<sub>2</sub>O<sub>3</sub> by synchrotron Mössbauer diffraction2019

    • Author(s)
      Nakamura Shin、Mitsui Takaya、Kobayashi Yasuhiro、Shimomura Susumu
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 88 Issue: 10 Pages: 103702-103702

    • DOI

      10.7566/jpsj.88.103702

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Presentation] 「鉄の磁石の「表面の謎」を解明! ― 表面を一原子層単位の深さ精度で磁性探査できる新技術を開発 ―2022

    • Author(s)
      三井隆也
    • Organizer
      第235回研究会/第82回スピントロニクス専門研究会「磁性材料の分 析評価技術の進展」, 日本磁気学会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 表面を一原子層単位の深さ精度で磁性探査できる新技術を開発 ―鉄の磁石の「表面の謎」を解明!―2021

    • Author(s)
      三井隆也
    • Organizer
      第82 回ONSA 先端科学研究会. 第73 回 放射線科学研究会. [ONSA 賞受賞講演会]
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] DIRECT OBSERVATION OF MAGNETIC FRIEDEL OSCILLATION AT THE IRON (001) SURFACE2021

    • Author(s)
      Takaya Mitsui
    • Organizer
      International conference on the application of the Mossbauer effect
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Atomic-Layer Resolved Magnetic Structure Analysis of Fe (001) Surface by In situ Synchrotron Mossbauer Spectroscopy2021

    • Author(s)
      Takaya Mitsui
    • Organizer
      Material Research Meeting 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 量子科学技術研究開発機構専用ビームライン2021

    • Author(s)
      片山芳則、綿貫徹、佐々木拓生、齋藤寛之、三井隆也
    • Organizer
      第34回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] BL11 SMS Setup and Applications2021

    • Author(s)
      Takaya Mitsui
    • Organizer
      Expert workshop on Nuclear Resonant Scattering of Synchrotron Radiation
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] 先端量子機能材料研究に向けた放射光核共鳴分光法の高度化と展開2020

    • Author(s)
      三井 隆也
    • Organizer
      第 14 回 SPRUC 核共鳴散乱研究会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 自然鉄Fe3O4の放射光メスバウアー回折2020

    • Author(s)
      中村真一, 三井隆也, 黒葛真行, 下村晋
    • Organizer
      日本物理学会 2020年秋季大会プログラム
    • Related Report
      2020 Annual Research Report
  • [Presentation] 全反射メスバウアー分光法における核共鳴散乱と電子散乱の干渉効果I2020

    • Author(s)
      藤原孝将, 三井隆也, 依田芳卓
    • Organizer
      日本物理学会 2020年秋季大会プログラム
    • Related Report
      2020 Annual Research Report
  • [Presentation] Investigations on local magnetic properties of magnetic thin films using synchrotron-radiation Mossbauer spectroscopy2020

    • Author(s)
      Takaya Mitsui
    • Organizer
      4th QST International Symposium -Innovation from Quantum Materials Science-
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 放射光メスバウアー分光による材料の局所構造解析2020

    • Author(s)
      三井 隆也
    • Organizer
      放射光設備利用講習会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 放射光メスバウアー線源を用いた鉄顕微鏡の開発研究2019

    • Author(s)
      三井隆也, 長谷川登, 錦野将元, 篠田圭司, 小林康浩, 増田亮, 瀬戸誠
    • Organizer
      日本物理学会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 高輝度メスバウアー分光法による機能材料の局所構造解析2019

    • Author(s)
      三井隆也
    • Organizer
      水素機能解析技術第190委員会 第2回総会
    • Related Report
      2019 Annual Research Report
  • [Remarks] BL11XU 放射光メスバウアー分光装置

    • URL

      http://www.spring8.or.jp/wkg/BL11XU/instrument/lang/INS-0000001401/instrument_view

    • Related Report
      2020 Annual Research Report
  • [Remarks] 放射光科学研究 | 磁性科学研究G

    • URL

      https://www.qst.go.jp/site/kansai-sr/20507.html

    • Related Report
      2020 Annual Research Report

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Published: 2019-04-18   Modified: 2023-01-30  

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