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Nanoscale Element Replacement Science: Structural Transformation of Nanocrystalline Phases and Development of Novel Functions

Research Project

Project/Area Number 19H05634
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Review Section Broad Section E
Research InstitutionKyoto University

Principal Investigator

Teranishi Toshiharu  京都大学, 化学研究所, 教授 (50262598)

Project Period (FY) 2019-06-26 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥201,630,000 (Direct Cost: ¥155,100,000、Indirect Cost: ¥46,530,000)
Fiscal Year 2023: ¥25,090,000 (Direct Cost: ¥19,300,000、Indirect Cost: ¥5,790,000)
Fiscal Year 2022: ¥31,850,000 (Direct Cost: ¥24,500,000、Indirect Cost: ¥7,350,000)
Fiscal Year 2021: ¥31,850,000 (Direct Cost: ¥24,500,000、Indirect Cost: ¥7,350,000)
Fiscal Year 2020: ¥32,370,000 (Direct Cost: ¥24,900,000、Indirect Cost: ¥7,470,000)
Fiscal Year 2019: ¥80,470,000 (Direct Cost: ¥61,900,000、Indirect Cost: ¥18,570,000)
Keywordsナノ材料 / 元素置換 / 金属化合物 / 合金 / イオン結晶 / 電子構造 / 触媒 / ナノ結晶相
Outline of Research at the Start

本研究では、電子構造で決定される希少貴金属の優れた物性や触媒能を凌駕する新奇無機ナノ粒子群の合成法と新奇機能を開拓する。具体的には、①低周期dブロック金属元素とpブロック元素との化合物形成ならびにpブロック元素との元素置換により、電子構造を変調した新奇な金属化合物・合金ナノ粒子群を創製する。さらに、②ヘビードープ半導体ナノ粒子の元素置換により、結晶構造・電子構造を部分的に変調し、全近赤外領域を網羅する光エネルギー変換材料を創製する。これら新奇無機ナノ粒子群の新たな物性・固体触媒特性探索を徹底的に行い、「基底電子構造変調」という新しい概念に根ざした物質科学『ナノ元素置換科学』を開拓する。

Outline of Final Research Achievements

A variety of unprecedented alloy nanoparticles have been successfully synthesized by galvanic replacement reactions of nanoparticles in which p-block elements have been introduced into d-block metal nanoparticles, and in manifesting novel plasmonic properties. By utilizing the interelement miscibility, unprecedented Z3-type nanoparticles have been synthesized for the first time. On the other hand, considering the characteristic that the anion sublattice is maintained in the cation exchange reaction of ionic nanoparticles, thermodynamically metastable spinel-type Ni3Se4 nanoparticles and Cu2-xSe/Ni3Se4 heterostructure nanoparticles have been successfully obtained by cation exchange between Cu2-xSe nanoparticles and Ni(II). Furthermore, in the cation exchange reaction of hexagonal Cu1.8S nanoparticles, we have clarified the factors that determine the crystal structure of the nanoparticles after cation exchange.

Academic Significance and Societal Importance of the Research Achievements

11族元素を含まない合金ナノ粒子において、可視プラズモン特性を示すことを実証し、その原理を解明した。また、特定の元素間相溶性を考慮することで、前例のない合金構造を安定化することを実証し、未踏合金結晶構造群の合成指針を示すことができた。一方、イオン結晶ナノ粒子のカチオン交換反応において、熱力学的準安定相を安定化することができることを実証したのみならず、カチオン交換後のナノ粒子の結晶構造決定因子を明らかにした。これらの材料は、新たな可視プラズモン材料や各種触媒(水分解触媒、酸素還元触媒など)として高いポテンシャルを有していることを示した。

Assessment Rating
Ex-post Assessment Comments (Rating)

A: In light of the aim of introducing the research area into the research categories, expected outcomes of research have been produced.

Assessment Rating
Interim Assessment Comments (Rating)

A: In light of the aim of introducing the research area into the research categories, the expected progress has been made in research.

Report

(11 results)
  • 2024 Ex-post Assessment (Comments) ( PDF )
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Abstract (Interim Assessment) ( PDF )   Annual Research Report   Interim Assessment (Comments) ( PDF )
  • 2020 Annual Research Report
  • 2019 Abstract ( PDF )   Comments on the Screening Results ( PDF )   Annual Research Report
  • Research Products

    (45 results)

All 2024 2023 2022 2021 2020 2019 Other

All Int'l Joint Research (5 results) Journal Article (13 results) (of which Peer Reviewed: 13 results,  Open Access: 7 results) Presentation (25 results) (of which Int'l Joint Research: 15 results,  Invited: 25 results) Remarks (2 results)

  • [Int'l Joint Research] RMIT University(オーストラリア)

    • Related Report
      2023 Annual Research Report
  • [Int'l Joint Research] Strasbourg University(フランス)

    • Related Report
      2023 Annual Research Report
  • [Int'l Joint Research] RMIT University(オーストラリア)

    • Related Report
      2022 Annual Research Report
  • [Int'l Joint Research] RMIT University(オーストラリア)

    • Related Report
      2019 Annual Research Report
  • [Int'l Joint Research] University of Castilla-La Mancha(スペイン)

    • Related Report
      2019 Annual Research Report
  • [Journal Article] Pseudomorphic amorphization of three-dimensional superlattices through morphological transformation of nanocrystal building blocks2024

    • Author(s)
      Saruyama Masaki、Takahata Ryo、Sato Ryota、Matsumoto Kenshi、Zhu Lingkai、Nakanishi Yohei、Shibata Motoki、Nakatani Tomotaka、Fujinami So、Miyazaki Tsukasa、Takenaka Mikihito、Teranishi Toshiharu
    • Journal Title

      Chemical Science

      Volume: 15 Issue: 7 Pages: 2425-2432

    • DOI

      10.1039/d3sc05085h

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Tuning the Direction of Photoinduced Electron Transfer in Porphyrin-Protected Gold Clusters2024

    • Author(s)
      Chiga Yuki、Suzuki Wataru、Takahata Ryo、Kobiyama Etsuki、Tahara Hirokazu、Kanemitsu Yoshihiko、Shibuta Masahiro、Sakamoto Masanori、Teranishi Toshiharu
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 128 Issue: 9 Pages: 3824-3831

    • DOI

      10.1021/acs.jpcc.3c06402

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Location-selective immobilisation of single-atom catalysts on the surface or within the interior of ionic nanocrystals using coordination chemistry2023

    • Author(s)
      Endo Kenichi、Saruyama Masaki、Teranishi Toshiharu
    • Journal Title

      Nature Communications

      Volume: 14 Issue: 1 Pages: 4241-4241

    • DOI

      10.1038/s41467-023-40003-8

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Isomer-Selective Conversion of Au Clusters by Au(I) Thiolate Insertion2023

    • Author(s)
      Chiga Yuki、Takahata Ryo、Suzuki Wataru、Mizuhata Yoshiyuki、Tokitoh Norihiro、Teranishi Toshiharu
    • Journal Title

      Inorganic Chemistry

      Volume: 62 Issue: 26 Pages: 10049-10053

    • DOI

      10.1021/acs.inorgchem.3c01442

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stabilization of unprecedented crystal phases of metal nanomaterials2023

    • Author(s)
      Matsumoto Kenshi、Sato Ryota、Teranishi Toshiharu
    • Journal Title

      Trends in Chemistry

      Volume: 5 Issue: 3 Pages: 201-213

    • DOI

      10.1016/j.trechm.2022.12.011

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Control over Ligand-Exchange Positions of Thiolate-Protected Gold Nanoclusters Using Steric Repulsion of Protecting Ligands2022

    • Author(s)
      Suzuki Wataru、Takahata Ryo、Chiga Yuki、Kikkawa Soichi、Yamazoe Seiji、Mizuhata Yoshiyuki、Tokitoh Norihiro、Teranishi Toshiharu
    • Journal Title

      Journal of the American Chemical Society

      Volume: 144 Issue: 27 Pages: 12310-12320

    • DOI

      10.1021/jacs.2c03670

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bridging electrocatalyst and cocatalyst studies for solar hydrogen production via water splitting2022

    • Author(s)
      Masaki Saruyama, Christian Mark Pelicano, Toshiharu Teranishi
    • Journal Title

      Chemical Science

      Volume: 13 Issue: 10 Pages: 2824-2840

    • DOI

      10.1039/d1sc06015e

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Inter-element miscibility driven stabilization of ordered pseudo-binary alloy2022

    • Author(s)
      Matsumoto Kenshi, Sato Ryota, Tatetsu Yasutomi, Takahata Ryo, Yamazoe Seiji, Yamauchi Miho, Inagaki Yuji, Horibe Yoichi, Kudo Masaki, Toriyama Takaaki, Auchi Mitsunari, Haruta Mitsutaka, Kurata Hiroki, Teranishi Toshiharu
    • Journal Title

      Nature Communications

      Volume: 13 Issue: 1 Pages: 1047-1047

    • DOI

      10.1038/s41467-022-28710-0

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Bimetallic Synergy in Ultrafine Cocatalyst Alloy Nanoparticles for Efficient Photocatalytic Water Splitting2022

    • Author(s)
      Christian Mark Pelicano, Masaki Saruyama, Ryo Takahata, Ryota Sato, Yasutaka Kitahama, Hiroyuki Matsuzaki, Taro Yamada, Takashi Hisatomi, Kazunari Domen, Toshiharu Teranishi
    • Journal Title

      Advanced Functional Materials

      Volume: 32 Issue: 31 Pages: 2202987-2202987

    • DOI

      10.1002/adfm.202202987

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transformations of Ionic Nanocrystals via Full and Partial Ion Exchange Reactions2021

    • Author(s)
      M. Saruyama, R. Sato, T. Teranishi
    • Journal Title

      Accounts of Chemical Research

      Volume: 54 Issue: 4 Pages: 765-775

    • DOI

      10.1021/acs.accounts.0c00701

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determinants of Crystal Structure Transformation in Cation Exchange Reaction2021

    • Author(s)
      Z. Li, M. Saruyama, T. Asaka, Y. Tatetsu, and T. Teranishi
    • Journal Title

      Science

      Volume: 373 Issue: 6552 Pages: 332-337

    • DOI

      10.1126/science.abh2741

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-activated Rh-Zr Mixed Oxide as a Nonhazardous Cocatalyst for Photocatalytic Hydrogen Evolution2020

    • Author(s)
      T. Nishino, M. Saruyama, Z. Li, Y. Nagatsuma, M. Nakabayashi, N. Shibata, T. Yamada, R. Takahata, S. Yamazoe, T. Hisatomi, K. Domen, and T. Teranishi
    • Journal Title

      Chemical Science

      Volume: 11 Issue: 26 Pages: 6862-6867

    • DOI

      10.1039/d0sc01363c

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Phase Segregated Cu2-xS-Ni3Se4 Bimetallic Selenide Nanocrystals Formed through Cation Exchange Reaction for Active Water Oxidation Precatalyst2020

    • Author(s)
      1.S. Kim, H. Mizuno, M. Saruyama, M. Sakamoto, M. Haruta, H. Kurata, T. Yamada, K. Domen, and T. Teranishi
    • Journal Title

      Chem. Sci.

      Volume: 11 Issue: 6 Pages: 1523-1530

    • DOI

      10.1039/c9sc04371c

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] 元素置換反応が拓くナノ物質科学2024

    • Author(s)
      寺西利治
    • Organizer
      電気化学会第91回大会
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] 原子層・結晶相配列制御による未踏ナノ物質の創製と機能発現2024

    • Author(s)
      寺西利治
    • Organizer
      日本化学会第91春季年会
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] New Class of Plasmonic Alloy Nanoparticles2023

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      243rd ECS Meeting
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Transformation of Inorganic Nanocrystals by Element Substitution Reactions2023

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      Nanomaterials Chemistry Workshop
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of visible-to-near infrared plasmonic nanomaterials by element substitution reactions2023

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      The 31st International Conference on Photochemistry
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] International Symposium on Small Particles and Inorganic Clusters XXI2023

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      Transformations of Inorganic Nanocrystals by Element Substitution Reactions
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 元素置換反応が拓くナノ物質科学2023

    • Author(s)
      寺西利治
    • Organizer
      大阪大学ナノ理工学人材育成コンソーシアム2023ナノ理工学セミナー
    • Related Report
      2023 Annual Research Report
    • Invited
  • [Presentation] 元素置換反応が拓くナノ物質科学2023

    • Author(s)
      寺西利治
    • Organizer
      GTR-IRCCS-RCMSセミナー
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] Transformations of Ionic Nanocrystals via Ion Exchange Reactions2022

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      241st ECS Meeting
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of Near Infrared Plasmonic Nanoparticles for Hydrogen Evolution2022

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      The 13th Asia-Pacific Conference on Near-Field Optics
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 元素置換による可視-近赤外プラズモンナノ材料の開拓2022

    • Author(s)
      寺西利治
    • Organizer
      2022光化学討論会
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] Synthesis of Near Infrared Plasmonic Nanoparticles for Hydrogen Evolution2022

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      Conference on Advanced in Catalysis for Energy and Environment
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 元素置換反応が拓くナノ物質科学2022

    • Author(s)
      寺西利治
    • Organizer
      第23回プラズモニック化学シンポジウム
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] Transformations of Ionic Nanocrystals via Ion Exchange Reactions2021

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      241st ECS Meeting
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 近赤外プラズモニクスの開拓と水素生成触媒への展開2021

    • Author(s)
      寺西利治
    • Organizer
      日本化学会第101春季年会中長期企画(人工光合成)
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] ナノ元素置換科学:未踏構造ナノ粒子の合成と構造特異機能2021

    • Author(s)
      寺西利治
    • Organizer
      光・量子デバイス研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Nanoscale Element Replacement Science: Structural Transformation of Nanocrystalline Phases and Development of Novel Functions2021

    • Author(s)
      Toshiharu Teranishi
    • Organizer
      Seminar on Low-dimensional Physics and Devices
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 元素置換による新奇プラズモニック合金ナノ粒子の合成2020

    • Author(s)
      寺西利治
    • Organizer
      第18回プラズモニック化学シンポジウム
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Novel Plasmonic Nanomaterials for Near Infrared Light Energy Conversion2020

    • Author(s)
      T. Teranishi
    • Organizer
      8th International Conference on Nanoscience and Nanotechnology (ICONN 2020)
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Novel Plasmonic Nanomaterials for Near Infrared Light Energy Conversion2019

    • Author(s)
      T. Teranishi
    • Organizer
      ChinaNano
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Plasmon-induced Hot Carrier Chemistry2019

    • Author(s)
      T. Teranishi
    • Organizer
      ASNANO-2 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 新しい可視・近赤外プラズモン合金ナノ粒子2019

    • Author(s)
      寺西利治
    • Organizer
      第68回高分子討論会
    • Related Report
      2019 Annual Research Report
    • Invited
  • [Presentation] Plasmon-induced Hot Carrier Chemistry2019

    • Author(s)
      T. Teranishi
    • Organizer
      KU-UNIST Joint Symposium
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Plasmon-induced Hot Carrier Chemistry in Inorganic Nanoparticles2019

    • Author(s)
      T. Teranishi
    • Organizer
      12th China‐Japan Joint Symposium on Metal Cluster Compounds
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Novel Plasmonic Nanomaterials for Near Infrared Light Energy Conversion2019

    • Author(s)
      T. Teranishi
    • Organizer
      Okinawa Colloids 2019
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Remarks] Teranishi Laboratory

    • URL

      https://www.scl.kyoto-u.ac.jp/~teranisi/

    • Related Report
      2023 Annual Research Report 2022 Annual Research Report 2021 Annual Research Report 2020 Annual Research Report
  • [Remarks] 寺西研

    • URL

      https://www.scl.kyoto-u.ac.jp/~teranisi/

    • Related Report
      2019 Annual Research Report

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Published: 2019-06-27   Modified: 2025-02-04  

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