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Multi-element spreading sensor array for electrical discrimination of complex VOCs

Research Project

Project/Area Number 19J12232
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Review Section Basic Section 21060:Electron device and electronic equipment-related
Research InstitutionThe University of Tokyo (2020)
Kyushu University (2019)

Principal Investigator

ZENG Hao  東京大学, 大学院工学研究科, 特別研究員(PD)

Project Period (FY) 2019-04-25 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2020: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2019: ¥900,000 (Direct Cost: ¥900,000)
Keywordsthousand-bit sensors / crossbar array / exhaled breath / sensing
Outline of Research at the Start

(1) Fabrication of Multi-Element Metal Oxide Sensor Array: This sensor array based on multi-element composition spreading oxide sensing layer would greatly enhance the accuracy of complex molecular detection.
(2) Optimization of Material/Device Parameters:A distribution of chemical reactivity in the sensing layer is evaluated through measurements of sensor response to single species at each crossbar point.
(3) Electrical Discrimination of Complex VOCs: The evaluation system including optimized sensor array chip is built up to classify analyte gases.

Outline of Annual Research Achievements

With the support from JSPS during two years, the Thousand-bit sensor array has been successfully fabricated, and great progress in exhaled breath performance has been observed with high accuracy with reliability.
In the fabrication process of the sensor array, we have noticed the structure design and the materials selection of the unit in a thousand-bit sensor array can gigantically alter the performance of the device. To avoid the drawback of conventional laser-lithography, we have proposed a two-layer photoresist-assisted method to improve the reproducibility of our device performance. To avoid the contact problem between the sensing element and electrode, we used metallic metal oxide instead of conventional Ti contact. We successfully avoid the thermal oxidization on contact via using metallic Antimony doped Tin Oxide as electrode, meanwhile, we also observed that the anomalous behavior of the interface between ITO electrode and SnO2 single crystalline structure, which indicated that not all metallic oxide is suitable as electrode to avoid thermal degradation.
In the sensing unit design, we comprehensively did literature survey based on metal oxide nanomaterials based gas sensors to maximize the merit of our device. With the guidance from our literature review, we observed the disparity in individual based on the resistance variation from our original system by measuring the exhaled breath. Moreover, we successfully distinguished people who has drunk or not.

Research Progress Status

令和2年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和2年度が最終年度であるため、記入しない。

Report

(2 results)
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (6 results)

All 2021 2020 2019

All Journal Article (4 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 4 results,  Open Access: 2 results) Presentation (2 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Metal-Oxide Nanowires Molecular Sensors and Their Promises2021

    • Author(s)
      H. Zeng, G. Zhang, K. Nagashima, T. Takahashi, T. Hosomi and T. Yanagida
    • Journal Title

      Chemosensors

      Volume: 9 Issue: 2 Pages: 41-41

    • DOI

      10.3390/chemosensors9020041

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Oxygen-Induced Reversible Sn-Dopant Deactivation between Indium Tin Oxide and Single-Crystalline Oxide Nanowire Leading to Interfacial Switching2020

    • Author(s)
      Zeng Hao、Takahashi Tsunaki、Seki Takehito、Kanai Masaki、Zhang Guozhu、Hosomi Takuro、Nagashima Kazuki、Shibata Naoya、Yanagida Takeshi
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 12 Issue: 47 Pages: 52929-52936

    • DOI

      10.1021/acsami.0c16108

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enhancement of pH Tolerance in Conductive Al-Doped ZnO Nanofilms via Sequential Annealing2020

    • Author(s)
      R. Yan, T. Takahashi, H. Zeng, T. Hosomi, M. Kanai, G. Zhang, K. Nagashima and T. Yanagida
    • Journal Title

      ACS Applied Electronic Materials

      Volume: 3 Issue: 2 Pages: 955-962

    • DOI

      10.1021/acsaelm.0c01052

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Improvements of Electrical Characteristics of Single-Crystalline ZnO Nanowire Field-Effect Transistors via Self-Assembled Monolayer Modification2020

    • Author(s)
      Hao ZENG, Tsunaki TAKAHASHI, Takuro HOSOMI, Kazuki NAGASHIMA, Masaki KANAI, Guozhu ZHANG, and Takeshi YANAGIDA.
    • Journal Title

      Engineering Sciences Reports

      Volume: 41 Pages: 12-16

    • NAID

      120007053167

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Anomalous Reversible Sn-Dopant Deactivation between Indium Tin Oxide and Single-Crystalline Oxide Nanowire2021

    • Author(s)
      Hao Zeng,Tsunaki Takahashi,Takehito Seki,Masaki Kanai,Guozhu Zhang,Takuro Hosomi,Kazuki Nagashima,Naoya Shibata,Takeshi Yanagida
    • Organizer
      第68回応用物理学会春季学術講演会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Electrical Degradation of ITO Contact Electrodes on Metal Oxide Nanowires2019

    • Author(s)
      H. Zeng, T. Takahashi, M. Kanai, G. Zhang, T. Hosomi, K. Nagashima, and T. Yanagida
    • Organizer
      International School and Symposium on Nanoscale Transport and phoTomics
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research

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Published: 2019-05-29   Modified: 2024-03-26  

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