量子ドットー有機分子複合系におけるアップコンバージョン機構に基づく太陽電池
| Project/Area Number |
19J14834
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| Research Category |
Grant-in-Aid for JSPS Fellows
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| Allocation Type | Single-year Grants |
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| Section | 国内 |
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| Review Section |
Basic Section 28030:Nanomaterials-related
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| Research Institution | Kyoto University |
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Principal Investigator |
張 傑 京都大学, 化学研究所, 特別研究員(PD)
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| Project Period (FY) |
2019-04-25 – 2021-03-31
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| Project Status |
Completed (Fiscal Year 2020)
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| Budget Amount *help |
¥1,900,000 (Direct Cost: ¥1,900,000)
Fiscal Year 2020: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2019: ¥1,000,000 (Direct Cost: ¥1,000,000)
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| Keywords | Photon upconversion / Near infrared light / Quantum dot / Triplet energy transfer / Triplet annihilation / Quantum dots / Perylene |
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| Outline of Research at the Start |
Low-energy photons have been abandoned in solar cells. Photon upconversion is a promising strategy to converting low-energy photons into useful high-energy photons. The efficiency of a solar cell can be improved to 43% using upconverted light.
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| Outline of Annual Research Achievements |
I established a triplet-triplet annihilation photon upconversion (TTA-UC) system based the composites of organic molecules and inorganic quantum dots (QDs). 5-(4-Carboxyphenyl)-10,15,20-triphenylporphyrin (TPP) molecules were assembled on the surface of PbS QDs for upconverting near infrared (NIR) into visible light. During UC process, PbS QDs are excited by a laser pulse and engages in interfacial triplet energy transfer to surface-attached TPP to generate TPP in the triplet excited state (TPP (T1)). Successive TTET then occurs from TPP (T1) to 2,5,8,11-tetra-tert-butylperylene (TTBP) molecules dissolved in the solution, which act as an annihilator. Then, two TTBP (T1) undergo TTA-UC to produce a singlet that emits a higher-energy photon.
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| Research Progress Status |
令和2年度が最終年度であるため、記入しない。
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| Strategy for Future Research Activity |
令和2年度が最終年度であるため、記入しない。
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Report
(2 results)
Research Products
(1 results)
