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光触媒的二酸化炭素還元のための共有結合性有機構造体を利用した単一原子触媒の創製

Research Project

Project/Area Number 19J23268
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section国内
Review Section Basic Section 28030:Nanomaterials-related
Research InstitutionKyoto University

Principal Investigator

李 展召  京都大学, 理学研究科, 特別研究員(DC1)

Project Period (FY) 2019-04-25 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 2021: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2020: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 2019: ¥900,000 (Direct Cost: ¥900,000)
Keywordsnanoplates / cation exchange / morphological evolution / heterostructures / nanocrystals / heterostructure / shape memory / phase transformation
Outline of Research at the Start

The photocatalytic reduction of CO2 into value-added hydrocarbons (ex. CH3OH and CH4) by sunlight is an environmentally-friendly and sustainable route to relieve environmental and energy issues.

Outline of Annual Research Achievements

In this year, we continuously focused on the synthesis of various ionic metal sulfide nanocrystal (NC) heterostructures as the potential photocatalysts for CO2 reduction. The NC heterostructures integrated with tunable compositions were synthesized by a special waning and waxing morphological evolution process in cation exchange (CE) reaction. This fine-tuning of the composition and structure in plate-shaped NCs enables a wide-range adjustment of the band positions and band alignments of different phases in the hybrid heterostructures and thus allows us to an accurately control the formation of intermediates and products in the photocatalytic CO2 reduction.

Research Progress Status

令和3年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和3年度が最終年度であるため、記入しない。

Report

(3 results)
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • 2019 Annual Research Report
  • Research Products

    (6 results)

All 2021 2020

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (4 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Determinants of Crystal Structure Transformation in Cation Exchange Reaction2021

    • Author(s)
      Z. Li, M. Saruyama, T. Asaka, Y. Tatetsu, and T. Teranishi
    • Journal Title

      Science

      Volume: 373 Issue: 6552 Pages: 332-337

    • DOI

      10.1126/science.abh2741

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-activated Rh-Zr Mixed Oxide as a Nonhazardous Cocatalyst for Photocatalytic Hydrogen Evolution2020

    • Author(s)
      T. Nishino, M. Saruyama, Z. Li, Y. Nagatsuma, M. Nakabayashi, N. Shibata, T. Yamada, R. Takahata, S. Yamazoe, T. Hisatomi, K. Domen, and T. Teranishi
    • Journal Title

      Chemical Science

      Volume: 11 Issue: 26 Pages: 6862-6867

    • DOI

      10.1039/d0sc01363c

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] “Scrap and rebuild” of Cu1.8S nanoparticles during cation exchange reaction2021

    • Author(s)
      Zhanzhao Li
    • Organizer
      環太平洋国際化学会議2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Shape Memory Behaviour of Cu1.8S Nanoparticles during Cation Exchange Reaction2021

    • Author(s)
      Zhanzhao Li
    • Organizer
      日本化学会第101春季年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Crystal Structural Transformation of Ionic Nanocrystals during Cation Exchange Reaction Governed by the Shape of Host Nanocrystals and the Kind of Guest Cation2020

    • Author(s)
      Zhanzhao Li
    • Organizer
      ナノ学会第18回大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Shape and Element Dependent Crystal Structural Transformation of Ionic Nanocrystals in Cation Exchange Reaction2020

    • Author(s)
      Zhanzhao Li
    • Organizer
      日本化学会第100春季年会
    • Related Report
      2019 Annual Research Report

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Published: 2019-05-29   Modified: 2024-03-26  

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