• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of ultrathin separation membranes utilizing 2D nanosheet materials for water treatment

Research Project

Project/Area Number 19K05121
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 27010:Transport phenomena and unit operations-related
Research InstitutionKobe University

Principal Investigator

Nakagawa Keizo  神戸大学, 科学技術イノベーション研究科, 准教授 (60423555)

Co-Investigator(Kenkyū-buntansha) 松山 秀人  神戸大学, 先端膜工学研究センター, 教授 (50181798)
吉岡 朋久  神戸大学, 先端膜工学研究センター, 教授 (50284162)
Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2021: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2020: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2019: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsナノシート / 膜分離 / 水処理 / ナノろ過膜 / 酸化グラフェン / ニオブ酸ナノシート / 分離膜 / 異種ナノシート界面 / 二硫化モリブデン
Outline of Research at the Start

本研究では種々の2次元ナノシート材料を積層した高い分離機能を有する超薄膜型水処理膜の開発を行う.異なる機能性を有するナノシートを組み合わせたナノシート複合積層膜を作製し,各ナノシート種の表面構造を活かした協奏的2次元チャネルを形成させ,高い構造安定性と共に,優れた透過性と分離性を両立しうる革新的ナノシート分離膜の設計手法を構築する.

Outline of Final Research Achievements

Inorganic membranes have excellent chemical resistance and mechanical strength. Therefore, the inorganic membranes have a wide range of applications, a long membrane life, and relatively high separation property. However, there are problems in terms of permeance, membrane-forming, and manufacturing cost.
In this study, we have developed ultrathin laminar membranes using graphene oxide and niobate nanosheets for water treatment. The composite membranes showed higher separation properties of salts than each single laminar membrane. From the results of structural analysis such as the positron annihilation method and molecular dynamics simulation, it was clarified that high separation performance is exhibited by the formation of an interfacial dense heterolayer between different nanosheet layers.

Academic Significance and Societal Importance of the Research Achievements

本研究で開発された新規ナノシート複合膜は,過去に報告例のない異なる種類のナノシートで形成される超薄膜が形成されており,高い塩阻止性が得られている.このような結果は,水処理のみならずガス分離,有機溶剤ろ過への応用に展開でき,水や大気環境の改善,石油化学や医薬品産業等における溶剤濃縮の省エネルギー化に寄与することが期待される.本研究成果は,化学工学分野において重要な学術的知見であり,カーボンニュートラルの実現に貢献しうる.

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Research-status Report
  • Research Products

    (49 results)

All 2022 2021 2020 2019 Other

All Int'l Joint Research (7 results) Journal Article (6 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 6 results,  Open Access: 1 results) Presentation (31 results) (of which Int'l Joint Research: 9 results,  Invited: 5 results) Book (1 results) Remarks (3 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] University of Oxford(英国)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] Chung Yuan Christian University/National Taiwan Univ/National Taiwan Univ of Sci and Tech(中国)

    • Related Report
      2021 Annual Research Report
  • [Int'l Joint Research] University of Oxford(英国)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] Chung Yuan Christian University/National Taiwan Univ of Sci and Tech(台湾)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] City University of Hong Kong(香港)

    • Related Report
      2020 Research-status Report
  • [Int'l Joint Research] University of Oxford(英国)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] Chung Yuan Christian University/National Taiwan Univ of Sci and Tech(台湾)

    • Related Report
      2019 Research-status Report
  • [Journal Article] Controlling interlayer spacing and organic solvent permeation in laminar graphene oxide membranes modified with crosslinker2021

    • Author(s)
      K. Nakagawa, S. Araya, K. Ushio, M. Kunimatsu, T. Yoshioka, T. Shintani, E. Kamio, K-L. Tung, H. Matsuyama
    • Journal Title

      Separation and Purification Technology

      Volume: 276 Pages: 119279-119279

    • DOI

      10.1016/j.seppur.2021.119279

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Laminar HNb3O8-based membranes supported on anodic aluminum oxide with enhanced anti-swelling property for organic solvent nanofiltration2021

    • Author(s)
      K. Nakagawa, M. Kunimatsu, K. Yasui, T. Yoshioka, T. Shintani, E. Kamio, K-L. Tung, S. C. E. Tsang, H. Matsuyama
    • Journal Title

      Journal of Membrane Science

      Volume: 640 Pages: 119799-119799

    • DOI

      10.1016/j.memsci.2021.119799

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] HNb3O8 Nanosheet-Graphene Oxide Composite Membranes for Molecular Separation2021

    • Author(s)
      Nakagawa Keizo、Kunimatsu Misato、Yasui Kengo、Yoshioka Tomohisa、Shintani Takuji、Yasui Tomoki、Kamio Eiji、Hung Wei-Song、Lee Kueir-Rarn、Edman Tsang Shik Chi、Matsuyama Hideto
    • Journal Title

      ACS Applied Nano Materials

      Volume: 4 Issue: 4 Pages: 3455-3466

    • DOI

      10.1021/acsanm.0c03348

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 2D Nanocomposite Membranes: Water Purification and Fouling Mitigation2020

    • Author(s)
      Loske Lara、Nakagawa Keizo、Yoshioka Tomohisa、Matsuyama Hideto
    • Journal Title

      Membranes

      Volume: 10 Issue: 10 Pages: 295-295

    • DOI

      10.3390/membranes10100295

    • NAID

      120006897854

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Design of Niobate Nanosheet-Graphene Oxide Composite Nanofiltration Membrane with Improved Permeability2020

    • Author(s)
      M. Kunimatsu, K. Nakagawa, T. Yoshioka, T. Shintani, T. Yasui, E. Kamio, S. C. E. Tsang, J. Li, H. Matsuyama
    • Journal Title

      Journal of Membrane Science

      Volume: 595 Pages: 117598-117598

    • DOI

      10.1016/j.memsci.2019.117598

    • NAID

      120007006667

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Two–dimensional Nanosheet Membranes for Liquid Separation2019

    • Author(s)
      中川敬三
    • Journal Title

      MEMBRANE

      Volume: 44 Issue: 3 Pages: 115-120

    • DOI

      10.5360/membrane.44.115

    • NAID

      130007661117

    • ISSN
      0385-1036, 1884-6440
    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Presentation] 加圧ろ過法を用いたMoS2ナノシート積層膜の作製と芳香族化合物還元反応への応用2021

    • Author(s)
      上野拓洋, 中川敬三, 新谷卓司, 松岡 淳, 神尾英治, 松山秀人, 吉岡朋久
    • Organizer
      日本膜学会第43年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 2次元ナノチャネルを有するナノシート積層膜の開発2021

    • Author(s)
      中川敬三, Kecheng Guan, 松山秀人
    • Organizer
      第15回酸化グラフェンシンポジウム
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Two-dimensional nanomaterial-based membranes for water treatment and organic solvent filtration2021

    • Author(s)
      Keizo Nakagawa
    • Organizer
      Online Lecture Series on "Nanoscience and Nanotechnology" in The Hong Kong Polytechnic University
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 酸化グラフェン積層膜の有機溶剤ナノろ過性能に及ぼす支持膜構造の影響2021

    • Author(s)
      牛尾 海, 中川敬三, Kecheng Guan, 吉岡朋久, 新谷卓司, 松岡淳, 神尾英治, 松山秀人
    • Organizer
      化学工学会第52回秋季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] カーボンナイトライド/ニオブ酸ナノシート複合膜の光触媒特性と耐ファウリング性の評価2021

    • Author(s)
      井元誠志, 中川敬三, Chechia Hu, 新谷卓司, 松岡淳, 神尾英治, 松山秀人, 吉岡朋久
    • Organizer
      化学工学会第52回秋季大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Advancing Metal Oxide-based Laminar Membranes:Water treatment and Organic Solvent Filtration (Plenary Lecture)2021

    • Author(s)
      Keizo Nakagawa
    • Organizer
      International Membrane Conference in Taiwan 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 酸化グラフェンを利用した有機溶剤ナノろ過膜:支持膜構造制御による阻止性能の向上2021

    • Author(s)
      牛尾 海, 中川敬三, Kecheng Guan, 吉岡朋久, 新谷卓司, 松岡淳, 神尾英治, 松山秀人
    • Organizer
      膜シンポジウム2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] 二硫化モリブデンナノシート積層型膜反応器の作製と芳香族ニトロ化合物還元反応への応用2021

    • Author(s)
      上野拓洋, 中川敬三, 新谷卓司, 松岡 淳, 神尾英治, 松山秀人, 吉岡朋久
    • Organizer
      分離技術会年会2021
    • Related Report
      2021 Annual Research Report
  • [Presentation] 二硫化モリブデンナノシート積層型膜反応器における芳香族化合物還元反応の検討2021

    • Author(s)
      上野拓洋, 中川敬三, 吉岡朋久, 新谷卓司, 神尾英治, 松山秀人,
    • Organizer
      第23回化学工学会学生発表会
    • Related Report
      2020 Research-status Report
  • [Presentation] カーボンナイトライド/ニオブ酸ナノシート複合膜の作製とナノろ過特性の評価2021

    • Author(s)
      井元誠志, 中川敬三, Hu Chechia, 新谷卓司, 神尾英治, 松山秀人, 吉岡朋久
    • Organizer
      化学工学会第86回年会
    • Related Report
      2020 Research-status Report
  • [Presentation] 加圧ろ過法で作製した酸化グラフェン積層膜の積層構造制御と有機溶剤ナノろ過性能2021

    • Author(s)
      牛尾 海, 中川敬三, 吉岡朋久, 新谷卓司, 神尾英治, 松山秀人
    • Organizer
      化学工学会第86回年会
    • Related Report
      2020 Research-status Report
  • [Presentation] ジアミン化合物で架橋されたGO積層膜の有機溶剤ナノろ過特性2020

    • Author(s)
      牛尾 海, 中川敬三, 吉岡朋久, 新谷卓司, 神尾英治, 松山秀人
    • Organizer
      日本膜学会第42年会
    • Related Report
      2020 Research-status Report
  • [Presentation] 二硫化モリブデンナノシート積層膜の加圧処理によるナノろ過特性の向上2020

    • Author(s)
      釆尾崇哉, 中川敬三, Jiri Kulhavy, Shik Chi Edman Tsang, 新谷卓司, 神尾英治, 松山秀人, 吉岡朋久
    • Organizer
      化学工学会第51回秋季大会
    • Related Report
      2020 Research-status Report
  • [Presentation] 界面緻密層を有するレイヤー型複合ナノシート積層膜の作製とナノろ過特性2020

    • Author(s)
      中川敬三, 國松美里, 吉岡朋久, 新谷卓司, 神尾英治, 松山秀人
    • Organizer
      膜シンポジウム2020
    • Related Report
      2020 Research-status Report
  • [Presentation] Fabrication of niobate nanosheet-graphene oxide composite membranes and their organic solvent nanofiltration performance2020

    • Author(s)
      K. Nakagawa, M. Kunimatsu, T. Yoshioka, T. Shintani, E. Kamio, H. Matsuyama
    • Organizer
      International Congress on Membranes & Membrane Processes 2020 (ICOM2020)
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research
  • [Presentation] アミン系架橋剤を利用した積層型酸化グラフェン膜の作製と有機溶剤ナノろ過特性の評価2020

    • Author(s)
      牛尾 海, 中川 敬三, 吉岡 朋久, 新谷 卓司, 神尾 英治, 松山 秀人
    • Organizer
      第22回化学工学会学生発表会(岡山大会)
    • Related Report
      2019 Research-status Report
  • [Presentation] 圧力支援法によるMoS2ナノシート積層膜の作製とナノろ過特性の評価2020

    • Author(s)
      釆尾 崇哉, 中川 敬三, Shik Chi Edman Tsang, 新谷 卓司, 神尾 英治, 松山 秀人, 吉岡 朋久
    • Organizer
      化学工学会第85年会
    • Related Report
      2019 Research-status Report
  • [Presentation] 架橋型酸化グラフェン積層膜および酸化グラフェン/ニオブ酸化物ナノシート複合積層膜の作製とナノろ過性能の比較検討2019

    • Author(s)
      中川 敬三, 國松 美里, 荒屋伸太朗, 吉岡 朋久, 新谷 卓司, 神尾 英治, 松山 秀人
    • Organizer
      日本膜学会第41年会
    • Related Report
      2019 Research-status Report
  • [Presentation] ニオブ酸化物ナノシート/酸化グラフェン複合膜の作製とナノろ過特性の評価2019

    • Author(s)
      國松 美里, 中川 敬三, 吉岡 朋久, 新谷 卓司, 神尾 英治, 松山 秀人
    • Organizer
      分離技術会年会2019
    • Related Report
      2019 Research-status Report
  • [Presentation] Development of Stacked Metal Oxide Nanosheet Membranes for Water Treatment2019

    • Author(s)
      K. Nakagawa
    • Organizer
      Advanced Hybrid Materials and Membrane Separation Symposium
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] The nanofiltration property of stacked nanosheet composite membrane incorporating graphene oxide into metal oxide membrane2019

    • Author(s)
      M. Kunimatsu, K. Nakagawa, T. Yoshioka, T. Shintani, E. Kamio, H. Matsuyama
    • Organizer
      12th Conference of the Aseanian Membrane Society (AMS12)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 二次元無機ナノシートを利用した積層型分離膜の開発2019

    • Author(s)
      中川敬三
    • Organizer
      第10回無機膜懇話会
    • Related Report
      2019 Research-status Report
  • [Presentation] Fabrication of niobium oxide based nanosheet membranes and their nanofiltration performance in water and alcohol2019

    • Author(s)
      K. Nakagawa, M. Kunimatsu,T. Yoshioka, T. Shintani, E.Kamio, H. Matsuyama
    • Organizer
      18th Asina Pacific Confederation of Chemical Engineering Congress (APCChE2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Effect of composite membrane structure on performance of graphene oxide/metal oxide nanosheets composite membranes2019

    • Author(s)
      M. Kunimatsu, K. Nakagawa, T. Yoshioka, T. Shintani, E.Kamio, H. Matsuyama
    • Organizer
      18th Asina Pacific Confederation of Chemical Engineering Congress (APCChE2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fabrication of graphene oxide membranes on porous α-alumina support by pressure assisted method2019

    • Author(s)
      H. Shiono, K. Nakagawa, T. Shintani, E.Kamio, H. Matsuyama, T. Yoshioka
    • Organizer
      18th Asina Pacific Confederation of Chemical Engineering Congress (APCChE2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fabrication and separation performances of stacked CuBDC MOF nanosheet membranes by vacuum filtration method2019

    • Author(s)
      M. Onoyama, K. Nakagawa, T. Shintani, E.Kamio, H. Matsuyama, T. Yoshioka
    • Organizer
      18th Asina Pacific Confederation of Chemical Engineering Congress (APCChE2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 液系分離への応用を目指した2次元ナノシート膜の開発2019

    • Author(s)
      中川敬三
    • Organizer
      先端膜工学研究拠点 第5回ワークショップ
    • Related Report
      2019 Research-status Report
  • [Presentation] Development of metal oxide nanosheet membranes: Separation performance in water and organic solvent2019

    • Author(s)
      K. Nakagawa
    • Organizer
      石油学会山形大会(第49回石油・石油化学討論会)[若手研究者・技術者によるインターナショナルセッション]
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Pt含有酸化グラフェン積層膜の作製とp-ニトロフェノール還元反応における触媒活性評価2019

    • Author(s)
      塩野 颯斗, 中川 敬三, 新谷 卓司, 神尾 英治, 松山 秀人,吉岡 朋久
    • Organizer
      膜シンポジウム2019
    • Related Report
      2019 Research-status Report
  • [Presentation] 二次成長法によるナノシート膜上へのCuBDC MOF膜の作製2019

    • Author(s)
      小野山 真之, 中川 敬三, 田中 俊輔, 新谷 卓司, 松山 秀人, 吉岡 朋久
    • Organizer
      膜シンポジウム2019
    • Related Report
      2019 Research-status Report
  • [Presentation] MoS2ナノシート積層膜の作製と加圧処理が及ぼす膜性能への影響2019

    • Author(s)
      釆尾 崇哉, 中川敬三, Shik Chi Edman Tsang, 新谷卓司, 松山秀人, 吉岡朋久
    • Organizer
      膜シンポジウム2019
    • Related Report
      2019 Research-status Report
  • [Book] ポストグラフェン材料の創製と用途開発最前線 ~二次元ナノシートの物性評価、構造解析、合成、成膜プロセス技術、応用展開~ 担当:分担執筆, 範囲:第III編 第3章 第3節 金属酸化物ナノシートを利用した積層型分離膜の開発2020

    • Author(s)
      中川敬三, その他49名
    • Total Pages
      448
    • Publisher
      株式会社エヌ・ティー・エス
    • ISBN
      9784860436575
    • Related Report
      2020 Research-status Report
  • [Remarks] 神戸大学大学院科学技術イノベーション研究科 中川敬三

    • URL

      https://kuid-rm-web.ofc.kobe-u.ac.jp/profile/ja.a1ea8968e41175ff520e17560c007669.html

    • Related Report
      2021 Annual Research Report 2020 Research-status Report
  • [Remarks] researchmap 中川敬三

    • URL

      https://researchmap.jp/7000017383

    • Related Report
      2021 Annual Research Report 2020 Research-status Report
  • [Remarks] 神戸大学大学院科学技術イノベーション研究科 中川敬三

    • URL

      http://www.stin.kobe-u.ac.jp/outline/member/Nakagawa.html

    • Related Report
      2019 Research-status Report
  • [Patent(Industrial Property Rights)] 可視光応答型ナノシート複合光触媒膜とその作製方法2022

    • Inventor(s)
      中川敬三,井元誠志,吉岡朋久,新谷卓司,胡哲嘉
    • Industrial Property Rights Holder
      中川敬三,井元誠志,吉岡朋久,新谷卓司,胡哲嘉
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2022-019998
    • Filing Date
      2022
    • Related Report
      2021 Annual Research Report

URL: 

Published: 2019-04-18   Modified: 2023-01-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi