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Elucidation of mechanism and verification of multipole origin for novel physical properties in rare-earth sulfides aimed at exploring new materials for the next generation

Research Project

Project/Area Number 19K05238
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 29010:Applied physical properties-related
Research InstitutionMuroran Institute of Technology

Principal Investigator

Ebisu Shuji  室蘭工業大学, 大学院工学研究科, 教授 (10250523)

Co-Investigator(Kenkyū-buntansha) 宮崎 正範  室蘭工業大学, 大学院工学研究科, 助教 (30634357)
Project Period (FY) 2019-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2022: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2021: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2020: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2019: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords希土類硫化物 / 単結晶育成 / 異常磁気伝導 / 電気抵抗率異常増減 / 巨大物性応答 / 磁化容易軸交換 / 磁場中試料回転 / 一軸圧 / 逐次磁気相転移 / 磁化容易方向 / 準安定状態 / 一軸圧下磁化率 / 静水圧下電気抵抗率 / 結晶場 / 圧力下電気抵抗率 / 弱強磁性磁化過程 / 残留エントロピー / 四極子秩序 / 弾性率測定 / 磁気構造 / 一軸応力
Outline of Research at the Start

希土類三二硫化物α-R2S3 (R:希土類元素)の単結晶が、極低温の狭い温度域で電気抵抗率が100倍以上の急増急減を示すなどの特異な物性を示すことが筆者らによって発見された。これらが、希土類元素の4f電子がある特殊な状態(電気四極子)で揺らいでいたり、磁場の印加により秩序化したりということに起因しているのではないかという仮説について実験的に検証し、次世代の社会に有益な希土類化合物の探索に対して指針を与える。

Outline of Final Research Achievements

In order to elucidate the mechanism of the novel physical properties, especially the anomalous enhancement/restoration of electrical resistivity in the narrow temperature range near the magnetic transition temperature, for single crystals of rare earth sesquisulfides α-R2S3, μSR experiments using microprobe and macroscopic physical property measurements were carried out. We conclude that the phenomenon is caused by a large magnetic fluctuation due to the short-range ordering of magnetic moments in the temperature range of T > TC1 for α-Sm2S3 and T > TN2 for α-Dy2S3. In addition, we consider that there are multiple metastable ground states of rare-earth ions in the crystalline field of this compound, and the coexistence of these states leads to a strange crossing of the easy magnetization axes, and the transitions between these states cause gigantic physical property responses.

Academic Significance and Societal Importance of the Research Achievements

狭い温度範囲で6桁にも及ぶ電気抵抗率の急増・急減というのは希有な現象であり、その機構を解明することはそれ自体が学術的に意義深く、また新しいタイプの巨大物性応答を示す化合物群を探索する手掛かりにもなり得る。外場に対して巨大な物性応答が得られれば、その物質は高効率・省エネルギー・低環境負荷で、ある機能を発揮する新材料となり、高機能電子デバイスへの展開が期待される。

Report

(5 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • 2019 Research-status Report
  • Research Products

    (35 results)

All 2023 2022 2021 2020 2019 Other

All Int'l Joint Research (1 results) Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results) Presentation (32 results) (of which Int'l Joint Research: 7 results)

  • [Int'l Joint Research] TRIUMF(カナダ)

    • Related Report
      2021 Research-status Report
  • [Journal Article] Successive weak-ferromagnetic transitions in α-Sm2S3.2022

    • Author(s)
      Zhao L.J., Ebisu S.
    • Journal Title

      Journal of Magnetism and Magnetic Materials

      Volume: 557 Pages: 169502-169502

    • DOI

      10.1016/j.jmmm.2022.169502

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel magnetic behavior of antiferromagnetic GdTe3 induced by magnetic field2021

    • Author(s)
      Guo Q.、Bao D.、Zhao L.J.、Ebisu S.
    • Journal Title

      Physica B: Condensed Matter

      Volume: 617 Pages: 413153-413153

    • DOI

      10.1016/j.physb.2021.413153

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] α-Dy2S3単結晶の磁化容易軸の交錯と導電性2023

    • Author(s)
      照井陵大, Muhamad Anif Bin Mat Nasir, 久保純喜, 堀井隆太, 宮崎正範, 戎修二
    • Organizer
      第58回応用物理学会北海道支部学術講演会
    • Related Report
      2022 Annual Research Report
  • [Presentation] α-Dy2S3の単結晶のac面内磁化容易軸2023

    • Author(s)
      戎修二, 照井陵大, 堀井隆太, Muhamad Anif Bin Mat Nasir, 宮崎正範
    • Organizer
      日本物理学会2023年春季大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Exchange between easy-magnetization axes in α-Dy2S3 single crystal induced by uni-axial pressure.2022

    • Author(s)
      Shuji Ebisu, Ryoma Nakatsuka, Lijuan Zhao, Masanori Miyazaki
    • Organizer
      29th International Conference on Low Temperature Physics
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnetic susceptibility of α-SmRS3 (R = Tb, Dy) single crystal: Effect of the multiplexing of rare earth in α-Sm2S3.2022

    • Author(s)
      Lijuan Zhao, Rie Asano, Masanori Miyazaki, Shuji Ebisu
    • Organizer
      29th International Conference on Low Temperature Physics
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] μSR study of successive magnetic transitions in α-R2S3 (R = Sm, Dy).2022

    • Author(s)
      Masanori Miyazaki, Lijuan Zhao, Ryoma Nakatsuka, Yipeng Cai, Kenji M Kojima, Shuji Ebisu
    • Organizer
      29th International Conference on Low Temperature Physics
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] α-Dy2S3の交流磁化率2022

    • Author(s)
      戎修二, 山川大智, 照井陵大, 堀井隆太, Zhao Lijuan, 宮崎正範
    • Organizer
      日本物理学会2022年秋季大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Relationship between easy-magnetization axis and anomalous enhancement of electrical resistivity in α-Sm2S3.2022

    • Author(s)
      L. Zhao, M. Miyazaki and S. Ebisu
    • Organizer
      日本物理学会2022年秋季大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Tb8Se14.8単結晶の圧力下電気抵抗率Ⅱ2022

    • Author(s)
      佐々木祐馬, 長谷川綾音, 松本裕大, 宮崎正範, 戎修二
    • Organizer
      第57回応用物理学会北海道支部学術講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] (K, Cs)xGdSe3-yの単結晶育成と磁気的性質2022

    • Author(s)
      照井陵大, 佐々木卓摩, 宮崎正範, 戎修二
    • Organizer
      第57回応用物理学会北海道支部学術講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] α-Dy2S3単結晶の物性に及ぼす圧力効果2022

    • Author(s)
      中塚亮磨, Zhao Lijuan, 山川大智, 宮崎正範, 戎修二
    • Organizer
      第57回応用物理学会北海道支部学術講演会
    • Related Report
      2021 Research-status Report
  • [Presentation] α-Dy2S3の磁性と伝導に及ぼす圧力効果2022

    • Author(s)
      戎修二, 中塚亮磨, Zhao Lijuan, 佐々木祐馬, 照井陵大, 宮崎正範
    • Organizer
      日本物理学会第77回年次大会
    • Related Report
      2021 Research-status Report
  • [Presentation] μSRからみたα-R2S3 (R = Dy, Sm)の磁気的逐次相転移2022

    • Author(s)
      宮崎正範, Zhao Lijuan, 中塚亮磨, Cai Yipeng, 小嶋健児, 戎修二
    • Organizer
      日本物理学会第77回年次大会
    • Related Report
      2021 Research-status Report
  • [Presentation] 層状化合物GdTe3の比熱と磁化率に及ぼす磁場の効果2021

    • Author(s)
      戎修二, Guo Qing, Bao Di, Zhao Lijuan, 宮崎正範
    • Organizer
      日本物理学会2021年秋季大会
    • Related Report
      2021 Research-status Report
  • [Presentation] Comparison of magnetization of weak-ferromagnetic compound α-Sm2S3 between single crystal and polycrystalline samples.2021

    • Author(s)
      Lijuan Zhao and Shuji Ebisu
    • Organizer
      ICSTR; International Conference on Science & Technology Research, 2021
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Weak-Ferromagnetic Properties of α-Sm2S3 single crystal.2021

    • Author(s)
      Lijuan Zhao and Shuji Ebisu
    • Organizer
      Muroran-IT Rare Earth Workshop 2021
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] α-Dy2S3単結晶におけるDyサイトの物性に及ぼす効果2021

    • Author(s)
      中塚亮磨, 山口将生, 宮崎正範, 戎修二
    • Organizer
      第56回応用物理学会北海道支部学術講演会
    • Related Report
      2020 Research-status Report
  • [Presentation] Magnetization curves for various single crystals of weak-ferromagnetic α-Sm2S3.2021

    • Author(s)
      Lijuan Zhao, Qing Guo, Ryota Terui, Masanori Miyazaki and Shuji Ebisu
    • Organizer
      第56回応用物理学会北海道支部学術講演会
    • Related Report
      2020 Research-status Report
  • [Presentation] Dy8Se14.8単結晶の低温物性2021

    • Author(s)
      井上正樹, 片山知哉, 宮崎正範, 戎修二
    • Organizer
      第56回応用物理学会北海道支部学術講演会
    • Related Report
      2020 Research-status Report
  • [Presentation] Tb8Se14.8単結晶の圧力下電気抵抗率2021

    • Author(s)
      佐々木祐馬, 鈴木一生, 宮崎正範, 戎修二
    • Organizer
      第56回応用物理学会北海道支部学術講演会
    • Related Report
      2020 Research-status Report
  • [Presentation] Preparation of antiferromagnetic Gd7Ni19As13 with a hexagonal crystal structure.2021

    • Author(s)
      Di Bao, Qing Guo, Masanori Miyazaki and Shuji Ebisu
    • Organizer
      第56回応用物理学会北海道支部学術講演会
    • Related Report
      2020 Research-status Report
  • [Presentation] 層状希土類化合物Dy8Se14.8の低温物性2021

    • Author(s)
      戎修二, 井上正樹, 佐々木祐馬, 中塚亮磨, 宮崎正範
    • Organizer
      日本物理学会第76回年次大会
    • Related Report
      2020 Research-status Report
  • [Presentation] Single Crystal Growth and Magnetic Properties of Newly found GdNi0.1Te0.9 Compound.2020

    • Author(s)
      Q. Guo, M. Miyazaki and S. Ebisu
    • Organizer
      日本物理学会2020年秋季大会
    • Related Report
      2020 Research-status Report
  • [Presentation] 層状希土類化合物CeSe2の伝導に及ぼす圧力効果2020

    • Author(s)
      戎 修二, 上田 隆介, 鮑 迪, 井上 正樹, 宮崎 正範
    • Organizer
      日本物理学会2020年秋季大会
    • Related Report
      2020 Research-status Report
  • [Presentation] Preparation of New Antiferromagetic Compound Gd7Ni19As13.2020

    • Author(s)
      Di Bao, Qing Guo and Shuji Ebisu
    • Organizer
      Muroran-IT Rare Earth Workshop 2020
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research
  • [Presentation] Magnetization Curves of Weak-Ferromagnetic Compound α-Sm2S3.2020

    • Author(s)
      Lijuan Zhao, Qing Guo and Shuji Ebisu
    • Organizer
      Muroran-IT Rare Earth Workshop 2020
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research
  • [Presentation] CeSe2単結晶の磁性と伝導2020

    • Author(s)
      上田隆介, 鮑迪, 中塚亮磨, 金澤竜太, 宮崎正範, 戎修二
    • Organizer
      第55回応用物理学会北海道支部学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] Dy8Se14.8単結晶の育成と電気的・磁気的性質2020

    • Author(s)
      井上正樹, 佐々木祐馬, 久末将人, 宮崎正範, 戎修二
    • Organizer
      第55回応用物理学会北海道支部学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] α-Sm2S3単結晶における磁気構造制御の試み2020

    • Author(s)
      浅野理恵, Zhao Lijuan, 国慶, 宮崎正範, 戎修二
    • Organizer
      第55回応用物理学会北海道支部学術講演会
    • Related Report
      2019 Research-status Report
  • [Presentation] α-Sm2S3単結晶の弱強磁性磁化曲線2020

    • Author(s)
      戎修二, 浅野理恵, Zhao Lijuan, 国慶, 宮崎正範
    • Organizer
      日本物理学会第75回年次大会
    • Related Report
      2019 Research-status Report
  • [Presentation] α-Sm2S3単結晶の低温物性と希土類複合化の効果2019

    • Author(s)
      浅野理恵, 井上正樹, 国慶, 宮崎正範, 戎修二
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] CeSe2単結晶の電気抵抗率に及ぼす圧力効果2019

    • Author(s)
      上田隆介, 鮑迪, 宮崎正範, 戎修二
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Research-status Report
  • [Presentation] 希土類硫化物α-Dy2S3 の弾性率測定2019

    • Author(s)
      工藤慎也, 村上陸, 中村光輝, 吉澤正人, 中西良樹, 戎修二
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2019 Research-status Report

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Published: 2019-04-18   Modified: 2024-01-30  

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