Operando quantum-state sensing for sodium-ion rechargeable battery

• Project/Area Number: 19K05519
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Review Section: Basic Section 34020:Analytical chemistry-related
• Research Institution: Gunma University
• Principal Investigator: Suzuki Kosuke 群馬大学, 大学院理工学府, 准教授 (90580506)
• Project Period (FY): 2019-04-01 – 2023-03-31
• Project Status: Completed (Fiscal Year 2022)
• Budget Amount: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000); Fiscal Year 2021: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000); Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2019: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
• Keywords: コンプトン散乱 / 高エネルギーX線 / 電極材料 / 電子状態 / ナトリウム二次電池 / リチウム二次電池 / イメージング / コンプトン散乱法 / 蓄電池 / 電極反応 / コンプトンプロファイル / ナトリウムイオン電池 / 金属間化合物

Outline of Research at the Start

ナトリウム二次電池は、資源の偏在がないナトリウムが電荷担体となること、電極にコバルトなどの希少金属を使用しないことから大型蓄電池としての応用が期待されている。しかし、未だ本格的な実用化には至っておらず、最適な電極材料の探査が続いている。このような背景の下、反応下にある電極の電子状態の変化、すなわち電極の量子状態を計測する分析法の開発は、電子論に基づいた新たな電極材料の設計指針を与えうる。本研究は、コンプトン散乱法をナトリウムイオン二次電池の負極材料Na3Biに初めて適用し、電極の量子状態をセンシングする新たな分析手法の確立を目指す。

Outline of Final Research Achievements

This study aims to develop electronic structure analysis for electrode materials using the high-energy Compton scattering technique and to apply it to Na3Bi of sodium-ion battery material. With the development of analysis techniques, we visualized the non-bonding O 2p orbital of lithium-rich cathode material. Moreover, by applying the Compton scattering technique to the practical 18650-type lithium-ion battery, we non-destructively observe inhomogeneous lithium reactions. Then the Compton scattering technique observes the change in the electronic structure of Na3Bi with increasing Na ions.

Academic Significance and Societal Importance of the Research Achievements

本研究成果の学術的意義や社会的意義は、高容量な電極材料の設計指針が得られることと、最適な実電池の設計指針が得られることである。本研究により明らかになったリチウム過剰系正極材料の電子状態から、遷移金属の3d軌道の変化、ならびに、酸化還元軌道の分布をディスクリプタとする電極材料設計指針になり得ると考えている。さらに本研究で得られたリチウム反応パターンの最適化により高性能なリチウムイオン実電池の開発が可能になると考えている。

Research Products

• [Int'l Joint Research] LUT University(フィンランド)
• [Int'l Joint Research] Northeastern University/Carnegie Mellon University(米国)
• [Int'l Joint Research] LUT University/University of Helsinki/Akkurate Oy(フィンランド)
• [Int'l Joint Research] Northeastern University/Carnegie Mellon University(米国)
• [Int'l Joint Research] LUT University/Akkurate Oy/University of Helsinki(フィンランド)
• [Int'l Joint Research] Northeastern University/Carnegie Mellon University(米国)
• [Int'l Joint Research] Northeastern University/Carnegie Mellon University(米国)
• [Int'l Joint Research] LUT University/Akkurate Oy/University of Helsinki(フィンランド)
• [Int'l Joint Research] AGH University of Science and Technology(ポーランド)
• [Journal Article] Non-Destructive Analysis of a High-Power Capacitor Using High-Energy X-ray Compton Scattering (2022)
  • Author(s): Suzuki Kosuke、Takano Kodai、Suzuki Shunta、Hanawa Hirotaka、Tsuji Naruki、Ando Tomoya、Hoshi Kazushi、Minato Yoshihiro、Ishimoto Shuichi、Sakurai Yoshiharu、Sakurai Hiroshi
  • Journal Title: Crystals Volume: 12 Issue: 6 Pages: 824-824
  • DOI: 10.3390/cryst12060824
  • Peer Reviewed / Open Access
• [Journal Article] Identifying Redox Orbitals and Defects in Lithium-Ion Cathodes with Compton Scattering and Positron Annihilation Spectroscopies: A Review (2022)
  • Author(s): Nokelainen Johannes、Barbiellini Bernardo、Kuriplach Jan、Eijt Stephan、Ferragut Rafael、Li Xin、Kothalawala Veenavee、Suzuki Kosuke、Sakurai Hiroshi、Hafiz Hasnain、Pussi Katariina、Keshavarz Fatemeh、Bansil Arun
  • Journal Title: Condensed Matter Volume: 7 Issue: 3 Pages: 47-47
  • DOI: 10.3390/condmat7030047
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Magnetic Compton scattering study of Li-rich battery materials (2022)
  • Author(s): Kosuke Suzuki, Yuji Otsuka, Kazushi Hoshi, Hiroshi Sakurai, Naruki Tsuji, Kentaro Yamamoto, Naoaki Yabuuchi, Hasnain Hafiz, Yuki Orikasa, Yoshiharu Uchimoto, Yoshiharu Sakurai, Venkatasubramanian Viswanathan, Arun Bansil, and Bernardo Barbiellini
  • Journal Title: Condensed Matter Volume: 7 Issue: 1 Pages: 4-11
  • DOI: 10.3390/condmat7010004
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Redox oscillations in 18650-type lithium-ion cell revealed by <i>in operando</i> Compton scattering imaging (2021)
  • Author(s): Suzuki Kosuke、Suzuki Shunta、Otsuka Yuji、Tsuji Naruki、Jalkanen Kirsi、Koskinen Jari、Hoshi Kazushi、Honkanen Ari-Pekka、Hafiz Hasnain、Sakurai Yoshiharu、Kanninen Mika、Huotari Simo、Bansil Arun、Sakurai Hiroshi、Barbiellini Bernardo
  • Journal Title: Applied Physics Letters Volume: 118 Issue: 16 Pages: 161902-161902
  • DOI: 10.1063/5.0048310
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Tomographic reconstruction of oxygen orbitals in lithium-rich battery materials (2021)
  • Author(s): Hasnain Hafiz, Kosuke Suzuki, Bernardo Barbiellini, Naruki Tsuji, Naoaki Yabuuchi, Kentaro Yamamoto, Yuki Orikasa, Yoshiharu Uchimoto, Yoshiharu Sakurai, Hiroshi Sakurai, Arun Bansil & Venkatasubramanian Viswanathan
  • Journal Title: Nature Volume: 594 Issue: 7862 Pages: 213-216
  • DOI: 10.1038/s41586-021-03509-z
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Identifying the Degradation Mechanism in Commercial Lithium Rechargeable Batteries via High-Energy X-ray Compton Scattering Imaging (2020)
  • Author(s): Suzuki Kosuke、Otsuka Yuji、Tsuji Naruki、Hoshi Kazushi、Sakurai Yoshiharu、Sakurai Hiroshi
  • Journal Title: Applied Sciences Volume: 10 Issue: 17 Pages: 5855-5855
  • DOI: 10.3390/app10175855
  • Peer Reviewed / Open Access
• [Journal Article] High-Energy X-Ray Compton Scattering Imaging of 18650-Type Lithium-Ion Battery Cell (2019)
  • Author(s): Suzuki Kosuke、Honkanen Ari-Pekka、Tsuji Naruki、Jalkanen Kirsi、Koskinen Jari、Morimoto Hideyuki、Hiramoto Daisuke、Terasaka Ayumu、Hafiz Hasnain、Sakurai Yoshiharu、Kanninen Mika、Huotari Simo、Bansil Arun、Sakurai Hiroshi、Barbiellini Bernardo
  • Journal Title: Condensed Matter Volume: 4 Issue: 3 Pages: 66-66
  • DOI: 10.3390/condmat4030066
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Identification of ferrimagnetic orbitals preventing spinel degradation by charge ordering in LixMn2O4 (2019)
  • Author(s): Hafiz Hasnain、Suzuki Kosuke、Barbiellini Bernardo、Orikasa Yuki、Kaprzyk Stanislaw、Tsuji Naruki、Yamamoto Kentaro、Terasaka Ayumu、Hoshi Kazushi、Uchimoto Yoshiharu、Sakurai Yoshiharu、Sakurai Hiroshi、Bansil Arun
  • Journal Title: Physical Review B Volume: 100 Issue: 20 Pages: 205104-205104
  • DOI: 10.1103/physrevb.100.205104
  • Peer Reviewed / Int'l Joint Research
• [Presentation] Spatiotemporal pattern of lithiation state in 18650-type cell observed by Compton scattering spectroscopy (2022)
  • Author(s): K. Suzuki, N. Tsuji, K. Jaikanen, J. Koskinen, K. Hoshi, A.-P. Honkanen, H. Hafiz, Y. Sakurai, M. Kanninen, S. Huotari, A. Bansil, H. Sakurai, and B. Barbiellini
  • Organizer: Material Research Meeting Fall Meeting & Exhibits
  • Int'l Joint Research
• [Presentation] Non-destructive imaging of the light elements in the functional materials using high-energy X-ray Compton scattering (2021)
  • Author(s): K. Suzuki, H. Sakurai, N. Tsuji, Y. Sakurai, Y. Orikasa, Y. Uchimoto, A.-P. Honkanen, K. Jalkanen, J. Koskinen, H. Hafiz, M. Kanninen, S. Huotari, A. Bansil and B. Barbiellini
  • Organizer: nternational Conference on Processing & Manufacturing of Advanced Materials 2021
  • Int'l Joint Research / Invited
• [Presentation] Redox oscillations in 18650-type lithium-ion cell revealed by in-operando Compton scattering imaging (2021)
  • Author(s): K. Suzuki, S. Suzuki, Y. Otsuka, N. Tsuji, K. Jalkanen, J. Koskinen, K. Hoshi, A.-P. Honkanen, H. Hafiz, Y. Sakurai, M. Kanninen, S. Huotari, A. Bansil. H. Sakurai, and B. Barbiellini
  • Organizer: 25th Congress and General Assembly of the International Union of Crystallography
  • Int'l Joint Research
• [Presentation] 高エネルギーX線コンプトン散乱によるリチウム電池研究 (2021)
  • Author(s): 鈴木宏輔
  • Organizer: SPring-8シンポジウム2021
  • Invited
• [Presentation] Visualization of spatio-temporal oscillation of electrode reaction in a large electrochemical cell using operando Compton scattering imaging (2021)
  • Author(s): K. Suzuki, S. Suzuki, Y. Otsuka, N. Tsuji, K. Jalkanen, J. Koskinen, K. Hoshi, A.-P. Honkanen, H. Hafiz, Y. Sakurai, M. Kanninen, S. Huotari, A. Bansil. H. Sakurai, and B. Barbiellini
  • Organizer: Materials Research Meeting 2021
  • Int'l Joint Research
• [Presentation] 高分解能コンプトン散乱法によるリチウム過剰系正極材料の“孤立した”酸素2p軌道の可視化 (2021)
  • Author(s): 鈴木 宏輔, H. Hafiz, B. Barbiellini, 辻 成希, 藪内 直明, 山本 健太郎, 折笠 有基, 内本 喜晴, 櫻井 吉晴, 櫻井 浩, A. Bansil, V. Viswanathan
  • Organizer: 第35回日本放射光学会年会 放射光科学合同シンポジウム
• [Presentation] コンプトン散乱イメージングによる18650型 リチウムイオン電池の電極反応パターンのオペランド観測 (2021)
  • Author(s): 鈴木 宏輔, 鈴木 駿太, 大塚 祐司, 辻 成希, K. Jalkanen, J. Koskinen, 星 和志, A-.P. Honkanen, H. Hafiz, 櫻井 吉晴, M. Kanninen, S. Huotari, A. Bansil, 櫻井 浩, B. Barbiellini
  • Organizer: 第35回日本放射光学会年会 放射光科学合同シンポジウム
• [Presentation] Compton Scattering Imaging for Operando Observation of Lithiation State on Commercial Lithium Battery Cells (2020)
  • Author(s): K. Suzuki, N. Tsuji, Y. Orikasa, Y. Uchimoto, Y. Sakurai and H. Sakurai
  • Organizer: Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME) 2020
  • Int'l Joint Research
• [Presentation] High-Energy X-ray Compton Scattering Imaging for In-Situ Observation of Large-Size Lithium Cells (2020)
  • Author(s): K. Suzuki, D. Hiramoto, N. Tsuji, K. Jalkanen, J. Koskinen, A.-P. Honkanen, H. Hafiz, Y. Sakurai, M. Kanninen, S. Huotari, A. Bansil, H. Sakurai and B. Barbiellini
  • Organizer: International Conference on Technology and Social Science 2020 (ICTSS 2020)
  • Int'l Joint Research / Invited
• [Presentation] コンプトン散乱X線強度及びS-parameterを用いたLiイオン2次電池の評価手法の開発 (2020)
  • Author(s): 大塚祐司, 鈴木宏輔, 辻成希, 星和志, 櫻井吉晴, 櫻井浩
  • Organizer: 第34回日本放射光学会年会・放射光科学合同シンポジウム
• [Presentation] Non-destructive Visualizing of Lithium State in the Real Batteries using Compton Scattering Imaging (2019)
  • Author(s): K. suzuki
  • Organizer: Materials Research Meeting 2019
  • Int'l Joint Research
• [Presentation] Quantum Characterization for Functional Materials using High-Energy X-ray Compton Scattering (2019)
  • Author(s): K. Suzuki
  • Organizer: The 10th Pacific Rim International Conference on Advanced Materials and Processing
  • Int'l Joint Research / Invited
• [Presentation] High-Energy X-ray Compton Scattering for Non-destructive and Quantum Characterization in Batteries (2019)
  • Author(s): K. Suzuki, H. Sakurai, N. Tsuji, Y. Sakurai, Y. Orikasa, Y. Uchimoto, H. Hafiz, B. Barbiellini and A. Bansil
  • Organizer: The 11th International Conference on Inelastic X-ray Scattering
  • Int'l Joint Research / Invited
• [Presentation] 磁気コンプトンプロファイルによるLixMn2O4の磁気構造 (2019)
  • Author(s): 鈴木宏輔, H. Hafiz, B. Barbiellini, 折笠有基, K. Stanislas, 辻成希, 山本健太郎, 星和志, 内本喜晴, 櫻井吉晴, A. Bansil, 櫻井浩
  • Organizer: 日本物理学会2019年秋季大会
• [Book] リチウムイオン電池の長期安定利用に向けたマネジメント技術 (2023)
  • Author(s): 執筆者：84名、技術情報協会
  • Total Pages: 567
  • Publisher: 技術情報協会
  • ISBN: 9784861049385
• [Book] リチウムイオン電池の分析 解析と評価技術（高エネルギーX線コンプトン散乱法を用いたリチウム二次電池電極内部の非破壊分析） (2019)
  • Author(s): （分担執筆）鈴木宏輔, 櫻井浩
  • Total Pages: 400
  • Publisher: 株式会社科学技術協会
  • ISBN: 9784861047701
• [Remarks] 充電中の円筒型リチウムイオン実電池内で電極反応の自己組織化パターンを観測
  • URL: https://www.st.gunma-u.ac.jp/20210420-eisuzuki/
• [Remarks] 高エネルギーX線散乱によりリチウム過剰系正極材料に特徴的なアニオンの酸化還元軌道を可視化
  • URL: https://www.st.gunma-u.ac.jp/20210610-eisuzuki/