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Material development to realize a comprehensive process for carbon dioxide recovery, effective utilization, and reduction

Research Project

Project/Area Number 19K05559
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 34030:Green sustainable chemistry and environmental chemistry-related
Research InstitutionChiba University

Principal Investigator

KANOH Hirofumi  千葉大学, 大学院理学研究院, 教授 (60334166)

Project Period (FY) 2019-04-01 – 2022-03-31
Project Status Completed (Fiscal Year 2021)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2021: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2020: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2019: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords環境負荷低減物質 / アルカリ金属炭酸塩 / 二酸化炭素回収 / 異種原子置換 / ナノ構造化 / コンポジット / カーボン電極 / 酸素濃縮 / 構造活性化 / ナノコンポジット / 二酸化炭素回収・有効利用・削減 / 炭酸アルカリ金属塩 / 二酸化炭素還元反応
Outline of Research at the Start

本研究では、(1) Na2CO3‐炭素ナノコンポジットによるCO2回収技術の実用化に向けた取り組み、(2) 回収したCO2の有効利用 および (3) 高酸素濃度気体中での燃焼によるCO2の排出量削減について、包括的なシステムを構築するための材料開発を進める。(1) Na2CO3‐炭素コンポジットのより安価な調製法の開発と、工場排ガス共存成分のCO2吸蔵反応に及ぼす影響を明らかにする。(2)銅ナノ粒子炭素電極を用いて、CO2還元によるエタノール生成の検討を行う。(3) については、構造柔軟性MOF (ELM) を用いた空気からの酸素濃縮について検討する。

Outline of Final Research Achievements

1) In order to overcome problems in CO2 capture by K2CO3 and Na2CO3, which are promising materials under a moist condition, we prepared their composites with carbon, and also proceeded with the compositing of Mg-doped Na2CO3. It was found that these materials showed a significant effect on improving the reaction rate and lowering the regeneration temperature. It was suggested that Na2CO3 becomes nanocrystals as a factor of this effect and that it has structural strain in the constrained space. In addition, the effects of SO2 and NOx contained in the target gas were examined in advance.
2) A plasma CVD device was prepared, and a thin film in which nitrogen-doped carbon was formed on an iron substrate using C2H2 and NH3 as raw materials. The film was examined as an electrode for electrochemical reduction of CO2. 3) Using structurally flexible MOF, the possibility of highly selective O2 sorption was shown.

Academic Significance and Societal Importance of the Research Achievements

地球温暖化ガスであるCO2の削減を実現するには、CO2の回収・貯留、有効利用および排出量の低減が必要である。これまで進めてきた有望なCO2回収材であるNa2CO3‐炭素コンポジットのより安価な調製法の開発と、課題となっていた反応促進や再生コスト高低減の指針を得た。さらにNa2CO3‐炭素コンポジットの大気からの直接CO2回収技術への適用可能性も広がった。また、柔軟構造をもつMOFの酸素濃縮について、比較的温和な条件で行える可能性を示した。

Report

(4 results)
  • 2021 Annual Research Report   Final Research Report ( PDF )
  • 2020 Research-status Report
  • 2019 Research-status Report
  • Research Products

    (28 results)

All 2022 2021 2020 2019

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (21 results) (of which Int'l Joint Research: 6 results,  Invited: 2 results)

  • [Journal Article] Colorless Magnetic Colloidal Particles Based on an Amorphous Metal-Organic Framework Using Holmium as the Metal Species2022

    • Author(s)
      Y. Fujita, K. Kohaku, N. Komiyama, K. Ujiie, H. Masu, T. Kojima, H. Wadati, H. Kanoh, K. Kishikawa, M. Kohri
    • Journal Title

      ChemNanoMat

      Volume: 掲載決定

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Full-Color Magnetic Nanoparticles Based on Holmium-Doped Polymers2020

    • Author(s)
      Kohaku Kotona、Inoue Mizuki、Kanoh Hirofumi、Taniguchi Tatsuo、Kishikawa Keiki、Kohri Michinari
    • Journal Title

      ACS Applied Polymer Materials

      Volume: 2 Issue: 5 Pages: 1800-1806

    • DOI

      10.1021/acsapm.0c00038

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural Dynamics of An ELM-11 Framework Transformation Accompanied with Double-Step CO2 Gate sorption: An NMR Spin Relaxation Study2020

    • Author(s)
      Ohazama Kazuki、Ueda Takahiro、Ukai Kazuki、Ichikawa Manami、Masu Hyuma、Kajiro Hiroshi、Kanoh Hirofumi
    • Journal Title

      Crystals

      Volume: 10 Issue: 4 Pages: 328-328

    • DOI

      10.3390/cryst10040328

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] Poly-β-Ketoester Particles as a Versatile Scaffold for Lanthanide-Doped Colorless Magnetic Materials2020

    • Author(s)
      Yamamoto Mikiya、Ando Koki、Inoue Mizuki、Kanoh Hirofumi、Yamagami Mai、Wakiya Takeshi、Iida Eiji、Taniguchi Tatsuo、Kishikawa Keiki、Kohri Michinari
    • Journal Title

      ACS Applied Polymer Materials

      Volume: 2 Issue: 6 Pages: 2170-2178

    • DOI

      10.1021/acsapm.0c00149

    • Related Report
      2020 Research-status Report
    • Peer Reviewed
  • [Journal Article] CO2 Capture by a K2CO3-Carbon Composite under Moist Conditions2020

    • Author(s)
      Nasiman Tuerxun、Kanoh Hirofumi
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 59 Issue: 8 Pages: 3405-3412

    • DOI

      10.1021/acs.iecr.9b05498

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] A flexible two-dimensional layered metal-organic framework functionalized with (trifluoromethyl)trifluoroborate: synthesis, crystal structure, and adsorption/separation properties2020

    • Author(s)
      Kondo Atsushi、Kajiro Hiroshi、Nakagawa Tomohiro、Tanaka Hideki、Kanoh Hirofumi
    • Journal Title

      Dalton Transactions

      Volume: 49 Issue: 12 Pages: 3692-3699

    • DOI

      10.1039/c9dt04836g

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Adsorption Properties of Methane, Ethane, and Hexane on Mesoporous Organic Polymers Prepared by the Flash Freezing Method2020

    • Author(s)
      Koyama Ryoichi、Tsunoda Fujika、Ichinose Izumi、Kanoh Hirofumi
    • Journal Title

      Langmuir

      Volume: 36 Issue: 9 Pages: 2184-2190

    • DOI

      10.1021/acs.langmuir.9b03159

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Presentation] しなやかな構造をもつガス分離材の特性 -柔軟構造をもつMOFを中心に-2021

    • Author(s)
      加納博文
    • Organizer
      石油学会九州・沖縄支部 第44回講演会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] ポーラスシリコンの磁性に対するヨウ素吸着の影響2021

    • Author(s)
      瀬端隼人、加納博文
    • Organizer
      、第24回ヨウ素学会シンポジウム
    • Related Report
      2021 Annual Research Report
  • [Presentation] ポーラスシリコンの磁性に影響を及ぼす要因の検討2021

    • Author(s)
      瀬端隼人、加納博文
    • Organizer
      第72回 コロイドおよび界面化学討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ELM-11の77 KでのN2に対する2段階ゲート現象2021

    • Author(s)
      上代洋、加納博文
    • Organizer
      第34回日本吸着学会研究発表会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ELM-11による窒素-酸素混合ガス分離の検討2021

    • Author(s)
      岩崎翼、小山良一、上代洋、加納博文
    • Organizer
      第34回日本吸着学会研究発表会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ELM-11 の N2吸収における超緩慢ゲート現象2021

    • Author(s)
      吉留樹、上代洋、佐藤伸哉、加納博文
    • Organizer
      第34回日本吸着学会研究発表会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 二酸化炭素を削減できるナノ材料2021

    • Author(s)
      加納博文
    • Organizer
      千葉市科学館 大人が楽しむ科学教室2021
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 二酸化炭素吸蔵反応を示すNa2CO3ーカーボンナノコンポジットにおけるナノ制約効果2021

    • Author(s)
      岩崎翼、加納博文
    • Organizer
      第48回炭素材料学会年会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Elastic Layer-structured MOF-13 (ELM-13) の ゲート現象に基づく選択的 O2 吸収反応2020

    • Author(s)
      小山良一、上代洋、加納博文
    • Organizer
      第71回 コロイドおよび界面化学討論会
    • Related Report
      2020 Research-status Report
  • [Presentation] 二次元層状MOF(ELM-13)の結晶構造と 吸着分離特性2020

    • Author(s)
      近藤 篤、上代 洋、田中 秀 樹、加納 博文
    • Organizer
      第71回 コロイドおよび界面化学討論会
    • Related Report
      2020 Research-status Report
  • [Presentation] PDMS 樹脂の有機溶媒に対する吸収および膨潤特性2020

    • Author(s)
      井上 瑞基 、イスマイル イドゥアン 、加納博文、一ノ瀬 泉
    • Organizer
      第71回 コロイドおよび界面化学討論会
    • Related Report
      2020 Research-status Report
  • [Presentation] A simple adsorption method of iodine or iodide on nanocarbon and its application to pseudocapacitor2020

    • Author(s)
      戴 楨穎、加納博文
    • Organizer
      第 47 回 炭素材料学会年会
    • Related Report
      2020 Research-status Report
  • [Presentation] Gas Adsorption Properties of Mesoporous Organic Polymers2019

    • Author(s)
      R. Koyama, F. Tsunoda, I. Ichinose, and H. Kanoh
    • Organizer
      International Symposium on Adsorption 2019 (Japan Adsorption 2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] CO2 Capture of Na2CO3-Carbon Nanocomposite under Moist Conditions2019

    • Author(s)
      T. Nasiman and H. Kanoh
    • Organizer
      13th International Symposium on Fundamentals of Adsorption (FOA13)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Effect of Carbon Nanopores on Amyloid Formation of Denatured Concanavalin A2019

    • Author(s)
      D. Hane and H. Kanoh
    • Organizer
      Okinawa Colloids 2019: An International Conference on Colloid & Surface Science Celebrating the 70th Anniversary of the Divisional Meeting of DCSC, CSJ
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] O2 adsorption by Nanostructured Magnetite-Carbon Composite2019

    • Author(s)
      Y. Hirano and H. Kanoh
    • Organizer
      Okinawa Colloids 2019: An International Conference on Colloid & Surface Science Celebrating the 70th Anniversary of the Divisional Meeting of DCSC, CSJ
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation and characterization of magnetic nanostructured silicon2019

    • Author(s)
      M. Inoue and H. Kanoh
    • Organizer
      Okinawa Colloids 2019: An International Conference on Colloid & Surface Science Celebrating the 70th Anniversary of the Divisional Meeting of DCSC, CSJ
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Selective O2 sorption based on a gate phenomenon of ELM-112019

    • Author(s)
      R. Koyama and H. Kanoh
    • Organizer
      Okinawa Colloids 2019: An International Conference on Colloid & Surface Science Celebrating the 70th Anniversary of the Divisional Meeting of DCSC, CSJ
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] ELM-11のゲート現象に基づく選択的酸素吸収2019

    • Author(s)
      小山良一、上代洋、加納博文
    • Organizer
      第33回日本吸着学会研究発表会
    • Related Report
      2019 Research-status Report
  • [Presentation] 磁場下でのマグネタイト担持活性炭素繊維による酸素吸着2019

    • Author(s)
      平野柚人、加納博文
    • Organizer
      第33回日本吸着学会研究発表会
    • Related Report
      2019 Research-status Report
  • [Presentation] 湿潤条件下における炭酸カリウムーカーボンコンポジットによる二酸化炭素吸蔵2019

    • Author(s)
      ナシマ トルスン、加納博文
    • Organizer
      第46回炭素材料学会年会
    • Related Report
      2019 Research-status Report

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Published: 2019-04-18   Modified: 2023-01-30  

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