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カーバイド前駆体を用いた低温ナノポーラスグラフェン合成法の開発

Research Project

Project/Area Number 19K15389
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 28030:Nanomaterials-related
Research InstitutionTohoku University

Principal Investigator

韓 久慧  東北大学, 学際科学フロンティア研究所, 助教 (40823092)

Project Period (FY) 2019-04-01 – 2023-03-31
Project Status Discontinued (Fiscal Year 2022)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2022: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2021: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2020: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2019: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
KeywordsNanoporous graphene / Nanoporous carbon / Carbide mediation / Chemical dealloying / Electrocatalyst / Electrode / Single-atom catalysts / Porous carbon / Sodium ion battery / Composite / Metallic carbides / Dealloying / Na-ion battery / ナノポーラスグラフェン / カーバイド前駆体 / 低温グラフェン合成法
Outline of Research at the Start

We aim to develop a facile, low-cost and mass-production approach for fabricating multiscale 3D nanoporous graphene materials for a wide range of functional applications. This research will promote the commercial applications of 3D nanoporous graphene.

Outline of Annual Research Achievements

Through carbide mediation and chemical dealloying, new 3D nanoporous graphene, 3D nanoporous amorphous carbon, and 3D nanoporous graphene/carbon composite materials with precisely controlled structural features and desirable physicochemical properties have been developed. These new materials lead to the creation of advanced electrocatalysts and electrodes, such as mesoporous N-doped graphene for the oxygen reduction reaction, nanoporous graphene anchored Pt single-atom catalyst for electrochemical hydrogen production, mesoporous graphene/TiO2 composite for dense Li-ion battery anode, and nanoporous amorphous carbon for high-rate Na-ion battery anode. These 3D nanoporous graphene and carbon enable high-efficiency energy conversion and storage as a new class of functional materials.

Report

(4 results)
  • 2022 Annual Research Report
  • 2021 Research-status Report
  • 2020 Research-status Report
  • 2019 Research-status Report
  • Research Products

    (29 results)

All 2022 2021 2020 2019 Other

All Journal Article (14 results) (of which Int'l Joint Research: 14 results,  Peer Reviewed: 14 results) Presentation (12 results) (of which Int'l Joint Research: 8 results,  Invited: 6 results) Book (1 results) Remarks (2 results)

  • [Journal Article] 3D Continuously Porous Graphene for Energy Applications2022

    • Author(s)
      Han Jiuhui、Johnson Isaac、Chen Mingwei
    • Journal Title

      Advanced Materials

      Volume: 34 Issue: 15 Pages: 2108750-2108750

    • DOI

      10.1002/adma.202108750

    • Related Report
      2022 Annual Research Report 2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dealloyed nanoporous materials for electrochemical energy conversion and storage2022

    • Author(s)
      Sang Qinqin、Hao Shuo、Han Jiuhui、Ding Yi
    • Journal Title

      EnergyChem

      Volume: 4 Issue: 1 Pages: 100069-100069

    • DOI

      10.1016/j.enchem.2022.100069

    • Related Report
      2022 Annual Research Report 2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Bulk diffusion regulated nanopore formation during vapor phase dealloying of a Zn-Cu alloy2022

    • Author(s)
      Xia Yanjie、Lu Zhen、Han Jiuhui、Zhang Fan、Wei Daixiu、Watanabe Kentaro、Chen Mingwei
    • Journal Title

      Acta Materialia

      Volume: 238 Pages: 118210-118210

    • DOI

      10.1016/j.actamat.2022.118210

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrafine Nanoporous Intermetallic Catalysts by High-Temperature Liquid Metal Dealloying for Electrochemical Hydrogen Production2022

    • Author(s)
      Song Ruirui、Han Jiuhui、Okugawa Masayuki、Belosludov Rodion、Wada Takeshi、Jiang Jing、Wei Daixiu、Kudo Akira、Tian Yuan、Chen Mingwei、Kato Hidemi
    • Journal Title

      Nature Communications

      Volume: -

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrasmall AuPd nanoclusters on amine-functionalized carbon blacks as high-performance bi-functional catalysts for ethanol electrooxidation and formic acid dehydrogenation2022

    • Author(s)
      Cui Yuhuan、Zhao Ming、Zou Yining、Zhang Junyu、Han Jiuhui、Wang Zhili、Jiang Qing
    • Journal Title

      Journal of Energy Chemistry

      Volume: 68 Pages: 556-563

    • DOI

      10.1016/j.jechem.2021.12.029

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dynamic shrinkage of metal-oxygen bonds in atomic Co-doped nanoporous RuO2 for acidic oxygen evolution2022

    • Author(s)
      Wu Qiuli、Jiang Kang、Han Jiuhui、Chen Dechao、Luo Min、Lan Jiao、Peng Ming、Tan Yongwen
    • Journal Title

      Science China Materials

      Volume: 65 Issue: 5 Pages: 1262-1268

    • DOI

      10.1007/s40843-021-1912-8

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Effect of Local Atomic Structure on Sodium Ion Storage in Hard Amorphous Carbon2021

    • Author(s)
      Han Jiuhui、Johnson Isaac、Lu Zhen、Kudo Akira、Chen Mingwei
    • Journal Title

      Nano Letters

      Volume: 21 Issue: 15 Pages: 6504-6510

    • DOI

      10.1021/acs.nanolett.1c01595

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Nanoporous B13C2 towards Highly Efficient Electrochemical Nitrogen Fixation2021

    • Author(s)
      Lan Jiao、Luo Min、Han Jiuhui、Peng Ming、Duan Huigao、Tan Yongwen
    • Journal Title

      Small

      Volume: 17 Issue: 39 Pages: 2102814-2102814

    • DOI

      10.1002/smll.202102814

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Vapor phase dealloying kinetics of MnZn alloys2021

    • Author(s)
      Zhen Lu, Fan Zhang, Daixiu Wei, Jiuhui Han, Yanjie Xia, Jing Jiang, Mingwang Zhong, Akihiko Hirata, Kentaro Watanabe, Alain Karma, Jonah Erlebacher, Mingwei Chen
    • Journal Title

      Acta Materialia

      Volume: 212 Pages: 116916-116916

    • DOI

      10.1016/j.actamat.2021.116916

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Dilute molybdenum atoms embedded in hierarchical nanoporous copper accelerate the hydrogen evolution reaction2021

    • Author(s)
      Luo Min、Peng Wei、Zhao Yang、Lan Jiao、Peng Ming、Han Jiuhui、Li Hongju、Tan Yongwen
    • Journal Title

      Scripta Materialia

      Volume: 191 Pages: 56-61

    • DOI

      10.1016/j.scriptamat.2020.09.011

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Visualizing the {110} surface structure of equilibrium-form ZIF-8 crystals by low-dose Cs-corrected TEM2021

    • Author(s)
      Han Xiaocang、Chen Wenqian、Su Rui、Tian Yuan、Liu Pan、Guan Pengfei、Luo Min、Han Jiuhui、Cao Xiaoxiao、Pan Ming、Chen Mingwei
    • Journal Title

      Nanoscale

      Volume: 13 Issue: 31 Pages: 13215-13219

    • DOI

      10.1039/d1nr03829j

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Graphene-coated nanoporous nickel towards a metal-catalyzed oxygen evolution reaction2021

    • Author(s)
      Qiu Hua-Jun、Johnson Isaac、Chen Luyang、Cong Weitao、Ito Yoshikazu、Liu Pan、Han Jiuhui、Fujita Takeshi、Hirata Akihiko、Chen Mingwei
    • Journal Title

      Nanoscale

      Volume: 13 Issue: 24 Pages: 10916-10924

    • DOI

      10.1039/d1nr02074a

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Atomic Ni and Cu co-anchored 3D nanoporous graphene as an efficient oxygen reduction electrocatalyst for zinc-air batteries2021

    • Author(s)
      Cheng Yongtai、Wu Haofei、Han Jiuhui、Zhong Siying、Huang Senhe、Chu Shufen、Song Shuangxi、Reddy Kolan Madhav、Wang Xiaodong、Wu Shaoyi、Zhuang Xiaodong、Johnson Isaac、Liu Pan、Chen Mingwei
    • Journal Title

      Nanoscale

      Volume: 13 Issue: 24 Pages: 10862-10870

    • DOI

      10.1039/d1nr01612a

    • Related Report
      2021 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 3D Bimodal Porous Amorphous Carbon with Self-Similar Porosity by Low-Temperature Sequential Chemical Dealloying2021

    • Author(s)
      Han Jiuhui、Li Hongping、Lu Zhen、Huang Gang、Johnson Isaac、Watanabe Kentaro、Chen Mingwei
    • Journal Title

      Chemistry of Materials

      Volume: 33 Issue: 3 Pages: 1013-1021

    • DOI

      10.1021/acs.chemmater.0c04328

    • Related Report
      2020 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 3D nanoporous graphene-based platinum single-atom electrocatalysts for efficient hydrogen production2021

    • Author(s)
      Jiuhui Han
    • Organizer
      VANJ Conference 2021 (VANJ2021) - Bridging Academic and Industry
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 3D nanoporous graphene-based single-atom electrocatalysts for efficient hydrogen production2021

    • Author(s)
      Jiuhui Han
    • Organizer
      8th Workshop of Ensemble Project for Young Researchers
    • Related Report
      2021 Research-status Report
  • [Presentation] 3D nanoporous energy materials: The extension from metal to functional carbon structures2021

    • Author(s)
      Jiuhui Han
    • Organizer
      Dealloying Webinar
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of Local Atomic Structure on Sodium-Ion Storage in Hard Amorphous Carbon2021

    • Author(s)
      Jiuhui Han
    • Organizer
      日本金属学会2021年秋期(第169回)講演大会
    • Related Report
      2021 Research-status Report
  • [Presentation] 3D nanoporous carbon-based energy materials2021

    • Author(s)
      Jiuhui Han
    • Organizer
      Chinese Materials Conference 2021
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 2D graphene in a 3D architecture: New opportunities from bicontinuous nanoporous graphene2021

    • Author(s)
      Jiuhui Han
    • Organizer
      International Young Scholar Forum, The Institute of Physics, Chinese Academy of Science
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Development and characterization of 3D nanoporous graphene2021

    • Author(s)
      Jiuhui Han
    • Organizer
      The 32nd Chinese Chemical Society Congress
    • Related Report
      2021 Research-status Report 2020 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Carbide-mediated synthesis of functional nanoporous carbon materials2021

    • Author(s)
      Jiuhui Han
    • Organizer
      The 5th FRIS/DIARE Joint Workshop
    • Related Report
      2020 Research-status Report
  • [Presentation] Unveiling the lithium-oxygen electrochemistry by in situ liquid cell transmission electron microscopy2020

    • Author(s)
      Jiuhui Han
    • Organizer
      The 4th Symposium for The Core Research Cluster for Materials Science and the 3rd Symposium on International Joint Graduate Program in Materials Science
    • Related Report
      2020 Research-status Report
    • Int'l Joint Research
  • [Presentation] 2D graphene in a 3D architecture: Nanoporous graphene materials for emerging batteries2020

    • Author(s)
      Jiuhui Han
    • Organizer
      The 2nd FRIS/DIARE Joint Workshop
    • Related Report
      2020 Research-status Report
  • [Presentation] 3D microporous carbon by room-temperature chemical dealloying of metallic carbides2019

    • Author(s)
      Jiuhui Han
    • Organizer
      3rd International Symposium on Nanoporous Materials by Alloy Corrosion
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Three-dimensional nanoporous graphene materials: controllable synthesis and multifunctional applications2019

    • Author(s)
      Jiuhui Han
    • Organizer
      Chinese Materials Conference 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Book] 「リチウムイオン電池の分析、解析と評価技術 事例集」第7章第1節「リチウム空気電池における反応中のダイナミクス観察」2019

    • Author(s)
      韓 久慧,渡辺 健太郎,陳 明偉
    • Total Pages
      12
    • Publisher
      株式会社 技術情報協会
    • ISBN
      9784861047701
    • Related Report
      2019 Research-status Report
  • [Remarks] ハードカーボン内のナトリウムイオンの貯蔵メカニズムに関する新たなモデル

    • URL

      https://www.tohoku.ac.jp/japanese/2021/06/press20210628-01-carbon.html

    • Related Report
      2021 Research-status Report
  • [Remarks] 材料化学: 化学的脱合金化法を用いて新しい多孔質カーボン電極を合成

    • URL

      https://www.wpi-aimr.tohoku.ac.jp/jp/aimresearch/highlight/2021/20210531_001395.html

    • Related Report
      2021 Research-status Report

URL: 

Published: 2019-04-18   Modified: 2023-12-25  

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