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Mitigating Asphaltene Deposition Using Modified Polyvinyl Alcohol and Silica Nanoparticles

Research Project

Project/Area Number 19K15490
Research Category

Grant-in-Aid for Early-Career Scientists

Allocation TypeMulti-year Fund
Review Section Basic Section 31020:Earth resource engineering, Energy sciences-related
Research InstitutionKyushu University

Principal Investigator

Nguele Ronald  九州大学, 工学研究院, 助教 (50821401)

Project Period (FY) 2019-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2020: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2019: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
KeywordsCO2-EOR / Asphaltene / Nanofluid / Poly vinyl alcohol / Asphaltene deposition / Nanoparticle / Poly Vinyl Alcohol / Nanoparticles
Outline of Research at the Start

One of the major challenges of crude oil production using carbon dioxide (CO2) injection is the deposition of heavy fractions. These fractions consisting of asphaltenes, wax and/or resins, precipitate when the oil is expelled from underground.This research aims at alleviating the precipitation in asphaltenes by treating the crude oil with modified poly-vinyl alcohol (mPVA) and stabilized nanofluids (NF). mPVA and NF are expected to scavenge asphaltenes, which are in suspension in the crude oil.

Outline of Final Research Achievements

It was found that asphaltenes, extracted from dead crude oils develop a stronger affinity with the silica nanofluid film leading to a preferential adsorption. Also, the research showed that the adsorption is proportional with the aromatic core, and inversely proportional to heteroatom contents. It was further highlighted that asphaltene solubility is rather dependent of the size of the aromatic core and the amount of embedded heteroatoms.

Academic Significance and Societal Importance of the Research Achievements

the present research proposed a hybrid production scheme in which the nanofluid should be injected ahead of the carbon dioxide. This approach promotes the adsorption the polar asphaltenes onto the surface of the nanoparticles allowing thereby oil dissolution by CO2.

Report

(3 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • Research Products

    (2 results)

All 2021

All Journal Article (1 results) (of which Int'l Joint Research: 1 results) Book (1 results)

  • [Journal Article] Asphaltene behavior at the interface oil-nanofluids: Implications to adsorption2021

    • Author(s)
      Nguele R. and Sasaki K.
    • Journal Title

      Colloids and Surfaces A: Physicochemical and Engineering Aspects

      Volume: 622 Pages: 126630-126630

    • DOI

      10.1016/j.colsurfa.2021.126630

    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Book] Advances in Micro- and Nanofluidics2021

    • Author(s)
      Ronald Nguele, Katia Nchimi Nono and Kyuro Sasaki
    • Total Pages
      21
    • Publisher
      IntechOpen
    • Related Report
      2020 Annual Research Report

URL: 

Published: 2019-04-18   Modified: 2022-01-27  

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