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Development of gamma prime-strengthened austenitic Fe-based superalloys - A new ultra high-temperature structural materials

Research Project

Project/Area Number 19K22053
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Review Section Medium-sized Section 26:Materials engineering and related fields
Research InstitutionKyoto University

Principal Investigator

INUI HARUYUKI  京都大学, 工学研究科, 教授 (30213135)

Co-Investigator(Kenkyū-buntansha) 岸田 恭輔  京都大学, 工学研究科, 准教授 (20354178)
新津 甲大  京都大学, 工学研究科, 助教 (90733890)
Project Period (FY) 2019-06-28 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2020: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2019: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords鉄基超合金 / 耐熱構造材料 / 2相組織 / 整合析出 / 格子ミスフィット / 高温強度 / クリープ / 単結晶 / Fe基超合金 / 超耐熱合金 / L12型金属間化合物 / 2相Cuboidal組織
Outline of Research at the Start

Ni基超合金の優れた耐熱性はFCC構造を基礎としたL12-Ni3Al(γ’)規則相がFCC-Ni(γ)相にCube-On-Cube方位関係で整合析出した2相組織に起因すると考えられ,このような2相Cuboidal組織をこれまで合金元素として考えられたことがないGeに着目しFe基合金で実現し,γ’相の相安定性の変化と高温力学特性の相関を確立しつつ,現在の耐熱鋼の630℃を遥かに超える耐用温度をもつ新規なFe基超合金耐熱鋼の開発を目指す.

Outline of Final Research Achievements

Although the excellent high-temperature properties of Ni-based superalloys have been considered to stem from two-phase cuboidal microstructures consisting of FCC (γ) and L12 (γ’) phases, such microstructures have never been formed in heat-resistant steel based on Fe. We have found that L12 solid solutions are formed continuously in the Fe3Ge-Ni3Ge pseudo-binary system and the L12 phase can coexists with FCC-(Fe,Ni) phase up to a chemical composition considerably rich in Fe, forming two-phase cuboidal microstructures. We have further elucidated some guiding principles for alloy design of Fe-based superalloys.

Academic Significance and Societal Importance of the Research Achievements

Fe-rich組成で優に50%を超えるγ’相をCube-On-Cube方位関係で整合析出させたγ-γ’2相組織を実現するのは世界初であり,高温材料や鉄鋼材料の多くの教科書に「Fe基の合金ではγ’相の相分率は10%を超えることはない」との記述を覆す学術的な意義を有する.このような2相組織は構造材料の耐熱性を向上させる上で有用であり,現在の耐熱鋼の耐用温度630℃を遥かに超える耐用温度をもつ新規な鉄基超合金の開発に繋がる研究であり,例えば火力発電所の発電効率を改善し,地球温暖化ガス排出量の大幅な削減に繋がり得るため社会的意義も大きい.

Report

(3 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • Research Products

    (42 results)

All 2021 2020 2019 Other

All Int'l Joint Research (8 results) Journal Article (7 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 7 results,  Open Access: 2 results) Presentation (25 results) (of which Int'l Joint Research: 11 results,  Invited: 11 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] オークリッジ国立研究所/オハイオ州立大学(米国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] ルール大学ボッフム校(ドイツ)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] パリ東大学(フランス)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] 浦頂工科大学(韓国)

    • Related Report
      2020 Annual Research Report
  • [Int'l Joint Research] オークリッジ国立研究所/オハイオ州立大学(米国)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] ルール大学ボッフム校 (ドイツ)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] パリ東大学(フランス)

    • Related Report
      2019 Research-status Report
  • [Int'l Joint Research] 浦頂工科大学(韓国)

    • Related Report
      2019 Research-status Report
  • [Journal Article] Effects of annealing on hardness, yield strength and dislocation structure in single crystals of the equiatomic Cr-Mn-Fe-Co-Ni high entropy alloy2021

    • Author(s)
      Zhou Dengshan、Chen Zhenghao、Ehara Kazuki、Nitsu Kodai、Tanaka Katsushi、Inui Haruyuki
    • Journal Title

      Scripta Materialia

      Volume: 191 Pages: 173-178

    • DOI

      10.1016/j.scriptamat.2020.09.039

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Plastic deformation of single crystals of the equiatomic Cr-Mn-Fe-Co-Ni high-entropy alloy in tension and compression from 10 K to 1273 K2021

    • Author(s)
      Kawamura Marino、Asakura Makoto、Okamoto Norihiko L.、Kishida Kyosuke、Inui Haruyuki、George Easo P.
    • Journal Title

      Acta Materialia

      Volume: 203 Pages: 116454-116454

    • DOI

      10.1016/j.actamat.2020.10.073

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] On the possibility of simultaneously achieving sufficient oxidation resistance and creep property at high temperatures exceeding 1000°C in Co-based superalloys2021

    • Author(s)
      Chen Zhenghao、Okamoto Norihiko L.、Chikugo Kazuyoshi、Inui Haruyuki
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 858 Pages: 157724-157724

    • DOI

      10.1016/j.jallcom.2020.157724

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Micropillar compression deformation of single crystals of Fe3Ge with the L12 structure2021

    • Author(s)
      Chen Zhenghao、Inui Haruyuki
    • Journal Title

      Acta Materialia

      Volume: 208 Pages: 116779-116779

    • DOI

      10.1016/j.actamat.2021.116779

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Prediction of Face-Centered Cubic Single-Phase Formation for Non-Equiatomic Cr–Mn–Fe–Co–Ni High-Entropy Alloys Using Valence Electron Concentration and Mean-Square Atomic Displacement2020

    • Author(s)
      Niitsu Kodai、Asakura Makoto、Yuge Koretaka、Inui Haruyuki
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 61 Issue: 9 Pages: 1874-1880

    • DOI

      10.2320/matertrans.MT-M2020144

    • NAID

      130007890400

    • ISSN
      1345-9678, 1347-5320
    • Year and Date
      2020-09-01
    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Strategy for managing both high strength and large ductility in structural materials-sequential nucleation of different deformation modes based on a concept of plaston2020

    • Author(s)
      Tsuji Nobuhiro、Ogata Shigenobu、Inui Haruyuki、Tanaka Isao、Kishida Kyosuke、Gao Si、Mao Wenqi、Bai Yu、Zheng Ruixiao、Du Jun-Ping
    • Journal Title

      Scripta Materialia

      Volume: 181 Pages: 35-42

    • DOI

      10.1016/j.scriptamat.2020.02.001

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Pattern formation mechanism of directionally-solidified MoSi2/Mo5Si3 eutectic by phase-field simulation2020

    • Author(s)
      Zhu Chuanqi、Koizumi Yuichiro、Chiba Akihiko、Yuge Koretaka、Kishida Kyosuke、Inui Haruyuki
    • Journal Title

      Intermetallics

      Volume: 116 Pages: 106590-106590

    • DOI

      10.1016/j.intermet.2019.106590

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Presentation] ハイエントロピー合金研究の現状と展望2021

    • Author(s)
      乾 晴行
    • Organizer
      2021年度日本鉄鋼協会チタンフォーラム研究発表会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Plastic deformation of the equiatomic Cr-Co-Ni single crystalline high entropy alloys2021

    • Author(s)
      李 楽、黒岩 省吾、伊藤 充洋、陳 正昊、岸田 恭輔、乾 晴行
    • Organizer
      日本金属学会2021年春期(第168回)講演大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Cr添加がγ/γ’二相Fe基超合金の耐酸化性と力学特性に与える影響2021

    • Author(s)
      姚 宏偉、陳 正昊、乾 晴行
    • Organizer
      日本金属学会2021年春期(第168回)講演大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Cr-Co-Ni等原子量合金単結晶の力学特性に及ぼす熱処理条件の影響2021

    • Author(s)
      伊藤 充洋、Li Le、岸田 恭輔、乾 晴行
    • Organizer
      日本金属学会2021年春期(第168回)講演大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] マイクロピラー単結晶L12-Fe3Geの塑性変形2021

    • Author(s)
      陳 正昊、岡本 範彦、乾 晴行
    • Organizer
      日本金属学会2021年春期(第168回)講演大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ハイエントロピー合金の特異な力学特性の支配因子解明2020

    • Author(s)
      乾 晴行,土谷 浩一,佐藤 裕之,田中 將己,橋本 直幸,増野 敦信,谷本 久典,金 熙榮,花咲 徳亮,田中 克志
    • Organizer
      日本金属学会2020年秋期(第167回)講演大会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Co基超合金における耐酸化性とクリープ特性が両立する可能性2020

    • Author(s)
      陳 正昊,岡本範彦,乾晴行
    • Organizer
      日本金属学会2020年秋期(第167回)講演大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] L12-Fe3Ge 単結晶の塑性変形2020

    • Author(s)
      陳 正昊,岡本範彦,乾晴行
    • Organizer
      日本金属学会2020年秋期(第167回)講演大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Plastic Deformation of Single Crystals of a Cr-Fe-Co-Ni Equiatomic Medium Entropy Alloy2020

    • Author(s)
      Ashif Equbal, Kazuki Ehara
    • Organizer
      2020 MRS Virtual Spring/Fall Meeting & Exhibit
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mo添加NbSi2/Nb5Si3共晶合金の微細組織と力学特性2020

    • Author(s)
      上村 遙、武田 康誠、岸田 恭輔、乾 晴行
    • Organizer
      日本金属学会2020年春期(第166回)講演大会
    • Related Report
      2019 Research-status Report
  • [Presentation] L12-Fe3Geマイクロピラー単結晶圧縮試験2020

    • Author(s)
      陳 正昊、岡本 範彦、乾 晴行
    • Organizer
      日本金属学会2020年春期(第166回)講演大会
    • Related Report
      2019 Research-status Report
  • [Presentation] Single-crystal mechanical properties of equiatomic CrMnFe-CoNi high-entropy alloy and its derivative equiatomic quaternary and ternary medium-entropy alloys2019

    • Author(s)
      Haruyuki Inui
    • Organizer
      2019 DPG Spring Meeting
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Single-Crystal Mechanical Properties of FCC High- and Medium-Entropy Alloys2019

    • Author(s)
      Haruyuki Inui
    • Organizer
      Possibilities and Limitations of Quantitative Materials Modeling and Characterization 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノ・メゾ構造を制御した先進構造材料の創成2019

    • Author(s)
      乾 晴行
    • Organizer
      第60回本多記念賞、第16回本多フロンティア賞および第40回本多記念研究奨励賞 贈呈式ならびに記念講演
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Mechanical Properties of Single Crystals of Cr-Co-Ni Equiatomic Medium Entropy Alloy2019

    • Author(s)
      Ehara Kazuki, Makoto Asakura, Kodai Niitsu, Kyosuke Kishida, Haruyuki Inui
    • Organizer
      Beyond Nickel-Based Superalloys III
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of MoSi2/Mo5Si3-based in-situ composites for ultra-high temperature applications2019

    • Author(s)
      Kyosuke Kishida, Haruyuki Inui
    • Organizer
      Beyond Nickel-Based Superalloys III
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Single-crystal Mechanical Properties of Equiatomic CrMnFeCoNi High-entropy Alloy and its Derivative Equiatomic Quaternary and Ternary Medium-entropy Alloys2019

    • Author(s)
      Haruyuki Inui, Kyosuke Kishida, Kodai Niitsu
    • Organizer
      Materials Structure & Micromechanics of Fracture (MSMF9)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] MoSi2/Mo5Si3共晶一方向凝固材の微細組織と力学特性に及ぼす凝固条件の影響2019

    • Author(s)
      武田康誠、岸田恭輔、乾晴行
    • Organizer
      日本金属学会2019年秋期(第165回)講演大会
    • Related Report
      2019 Research-status Report
  • [Presentation] FCCハイエントロピー合金の塑性変形と微視組織2019

    • Author(s)
      新津甲大、江原和輝、Ashif Equbal、浅倉誠仁、岸田恭輔、乾 晴行
    • Organizer
      日本金属学会2019年秋期(第165回)講演大会
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Cr-Co-Ni等原子量合金単結晶の塑性変形における熱活性化過程2019

    • Author(s)
      江原和輝、新津甲大、岸田恭輔、乾 晴行
    • Organizer
      日本金属学会2019年秋期(第165回)講演大会
    • Related Report
      2019 Research-status Report
  • [Presentation] Plastc deformaton behavior of singlecrystalline Cr-Co-Ni equiatomic medium entropy alloy2019

    • Author(s)
      Kazuki Ehara
    • Organizer
      Intermetallics 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Microstructure optmisaton of directonally solidifed MoSi2/Mo5Si3 eutectc composites2019

    • Author(s)
      Kosei Takeda
    • Organizer
      Intermetallics 2019
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] Single-crystal Mechanical Properties of Equiatomic CrMnFeCoNi High-entropy Alloy and Its Derivative Equiatomic Quaternary and Ternary Medium-entropy Alloys2019

    • Author(s)
      Haruyuki Inui,Kyosuke Kishida, Koudai Niitsu, Easo George
    • Organizer
      World Congress on High Entropy Alloys (HEA 2019)
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Effects of Heat-Treatment on Mechanical Properties of Equiatomic CrMnFeCoNi High-Entropy Alloy and Its Derivative Equiatomic Quaternary and Ternary Medium-Entropy Alloys2019

    • Author(s)
      Haruyuki Inui, Kodai Niitsu, Kyosuke Kishida
    • Organizer
      2019 MRS FALL MEETING & EXHIBIT
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Materials Parameters in Designing FCC High-entropy Alloys2019

    • Author(s)
      Haruyuki Inui, Koudai Niitsu,Kyosuke Kishida, Easo George
    • Organizer
      TMS 2020 Annual Meeting & Exhibition
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Remarks] 京都大学大学院工学研究科材料工学専攻乾研究室ホームページ

    • URL

      http://imc.mtl.kyoto-u.ac.jp/

    • Related Report
      2020 Annual Research Report 2019 Research-status Report
  • [Patent(Industrial Property Rights)] 合金およびその製造方法2020

    • Inventor(s)
      乾晴行,アファンディ アハマド,ヤオ ホンウェイ 外2名
    • Industrial Property Rights Holder
      乾晴行,アファンディ アハマド,ヤオ ホンウェイ 外2名
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2020-134415
    • Filing Date
      2020
    • Related Report
      2020 Annual Research Report

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Published: 2019-07-04   Modified: 2022-01-27  

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