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Realization of field-induced superconductivity in surface-functionalized diamonds

Research Project

Project/Area Number 19K22133
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Review Section Medium-sized Section 29:Applied condensed matter physics and related fields
Research InstitutionKyoto University (2020)
Institute for Molecular Science (2019)

Principal Investigator

Suda Masayuki  京都大学, 工学研究科, 准教授 (80585159)

Project Period (FY) 2019-06-28 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2020: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2019: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Keywordsダイヤモンド / 超伝導 / 表面修飾 / 電気二重層トランジスタ / 電界効果 / キャリアドーピング
Outline of Research at the Start

ダイヤモンドはあらゆる物質中で最高クラスのデバイ温度を持ち、常圧における高温超伝導実現の候補物質であるにもかかわらず、最高転移温度はわずか11.4 Kに留まっている。これは、ホウ素の添加に伴う"乱れ"の影響によるものであると考えられており、乱れを排除したダイヤモンドにおいては100 Kクラスの転移温度が実現すると指摘されている。本研究では、ダイヤモンド表面に化学修飾を施すことでポテンシャルの乱れを最小化したダイヤモンドを作製し、電気二重層トランジスタを作製することで、最終的に静電キャリアドーピングによる電界誘起高温超伝導の実現を目指す。

Outline of Final Research Achievements

Diamond has the highest Debye temperature which was reported to be 2200 K and therefore, high Tc superconductivity can be expected in carrier-doped diamond. However, the highest Tc for boron0-doped diamond reported so far in diamond is 11.4 K. it is considered that the effect of disorder strongly suppresses the value of Tc.In this work, we fabricated the electric-double-layer transistor with surface-modified diamond as a channel to realize field-induced carrier-doping without disorder. In this novel device, we observed field-induced insulator-to-metal transition in surface-modified diamond. Furthermore, field-induced superconductivity in diamond will be realized by optimizing the method for surface functionalization.

Academic Significance and Societal Importance of the Research Achievements

BCS型(従来型)と呼ばれる超伝導体は長らく30 K付近が「BCSの壁」であるとされ、超伝導研究分野での主役を非従来型に明け渡していた。しかしながら、2014年末に高圧下の硫化水素が銅酸化物の最高転移温度を大きく超える190 Kで超伝導転移すると報告され、現在では、室温超伝導も確認された。こうして、BCS型超伝導体の可能性が再考されることになったが、水素化物の超伝導転移には超高圧力が必要であり、その応用は極めて難しい。一方で、本研究計画が実現されれば、常圧固体物質における室温超伝導実現への第一歩となるであろうと考えられ、学術的・社会的意義を持つ研究であると考えらえる。

Report

(3 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • Research Products

    (17 results)

All 2021 2020 2019

All Journal Article (7 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 7 results,  Open Access: 3 results) Presentation (10 results) (of which Int'l Joint Research: 3 results,  Invited: 7 results)

  • [Journal Article] Terahertz-field-induced polar charge order in electronic-type dielectrics2021

    • Author(s)
      Yamakawa H.、Miyamoto T.、Morimoto T.、Takamura N.、Liang S.、Yoshimochi H.、Terashige T.、Kida N.、Suda M.、Yamamoto H. M.、Mori H.、Miyagawa K.、Kanoda K.、Okamoto H.
    • Journal Title

      Nature Communications

      Volume: 12 Issue: 1 Pages: 953-953

    • DOI

      10.1038/s41467-021-20925-x

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Bulk Grain-Boundary Materials from Nanocrystals2021

    • Author(s)
      Nagaoka Yasutaka、Suda Masayuki、Yoon Insun、Chen Na、Yang Hanjun、Liu Yuzi、Anzures Brendan A.、Parman Stephen W.、Wang Zhongwu、Gr?nwald Michael、Yamamoto Hiroshi M.、Chen Ou
    • Journal Title

      Chem

      Volume: 7 Issue: 2 Pages: 509-525

    • DOI

      10.1016/j.chempr.2020.12.026

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Quantum Phase Transition in Organic Massless Dirac Fermion System α-(BEDT-TTF)2I3 under Pressure2020

    • Author(s)
      Yoshinari Unozawa, Yoshitaka Kawasugi, Masayuki Suda, Hiroshi M. Yamamoto, Reizo Kato, Yutaka Nishio, Koji Kajita, Takao Morinari, and Naoya Tajima
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 89 Issue: 12 Pages: 123702-123702

    • DOI

      10.7566/jpsj.89.123702

    • NAID

      40022436756

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of thiophene/furan substitution on organic field effect transistor properties of arylthiadiazole based organic semiconductors2020

    • Author(s)
      Pachariyangkun Anna、Suda Masayuki、Hadsadee Sarinya、Jungsuttiwong Siriporn、Nalaoh Phattananawee、Pattanasattayavong Pichaya、Sudyoadsuk Taweesak、Yamamoto Hiroshi M.、Promarak Vinich
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 8 Issue: 48 Pages: 17297-17306

    • DOI

      10.1039/d0tc04982d

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chirality-Induced Spin-Polarized State of a Chiral Crystal CrNb3S62020

    • Author(s)
      Inui Akito、Aoki Ryuya、Nishiue Yuki、Shiota Kohei、Kousaka Yusuke、Shishido Hiroaki、Hirobe Daichi、Suda Masayuki、Ohe Jun-ichiro、Kishine Jun-ichiro、Yamamoto Hiroshi M.、Togawa Yoshihiko
    • Journal Title

      Physical Review Letters

      Volume: 124 Issue: 16 Pages: 166602-166602

    • DOI

      10.1103/physrevlett.124.166602

    • Related Report
      2020 Annual Research Report 2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrolyte-Gating-Induced Metal-Like Conduction in Nonstoichiometric Organic Crystalline Semiconductors under Simultaneous Bandwidth Control2019

    • Author(s)
      H. Ito, Y. Edagawa, J. Pu, H. Akutsu, M. Suda, H. M. Yamamoto, Y. Kawasugi, R. Haruki, R. Kumai, T. Takenobu
    • Journal Title

      Phys. Status Solidi

      Volume: 13 Issue: 10 Pages: 162-175

    • DOI

      10.1002/pssr.201900162

    • Related Report
      2019 Research-status Report
    • Peer Reviewed
  • [Journal Article] Light-driven molecular switch for reconfigurable spin filters2019

    • Author(s)
      Suda Masayuki、Thathong Yuranan、Promarak Vinich、Kojima Hirotaka、Nakamura Masakazu、Shiraogawa Takafumi、Ehara Masahiro、Yamamoto Hiroshi M.
    • Journal Title

      Nature Communications

      Volume: 10 Issue: 1 Pages: 2455-2455

    • DOI

      10.1038/s41467-019-10423-6

    • Related Report
      2019 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] Charge-to-Spin Current Conversion by Chiral Molecules2021

    • Author(s)
      Masayuki Suda
    • Organizer
      日本化学会第101春季年会・アジア国際シンポジウム
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 分子キラリティによる電流/スピン流変換機能の創出2020

    • Author(s)
      須田理行
    • Organizer
      第943回分子研コロキウム
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] Generation and Manipulation of Spin-polarized Current by Chiral Molecules2020

    • Author(s)
      Masayuki Suda
    • Organizer
      CSJ Asian International Symposium
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] キラリティ制御によるスピン偏極電流の生成と制御2019

    • Author(s)
      須田理行
    • Organizer
      「物質階層原理研究」&「ヘテロ界面研究」 合同春合宿
    • Related Report
      2019 Research-status Report
  • [Presentation] 分子キラリティ制御に基づくスピン偏極電流の生成と外場制御2019

    • Author(s)
      須田理行
    • Organizer
      早稲田高等研究所 Top Runners’ Lecture Collection 「物質の構造と対称性がもたらす電磁交差応答の最前線マルチフェロイクスとスピ ントロニクス」
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Photo-control of Solid-state Electronic Properties by Interface Molecular Engineering2019

    • Author(s)
      Masayuki Suda
    • Organizer
      RIKEN Symposium on Advanced Molecular Materials and their Applications
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Light-driven Molecular Switch for Reconfigurable Spin Filters2019

    • Author(s)
      Masayuki Suda, Hiroshi M. Yamamoto
    • Organizer
      Chiral-induced Spin Selectivity and Its Related Phenomena (The 80th Okazaki Conference)
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] 分子キラリティ制御によるスピン偏極電流の生成と制御2019

    • Author(s)
      須田理行
    • Organizer
      有機固体若手の会2019冬の学校
    • Related Report
      2019 Research-status Report
  • [Presentation] Light-driven Molecular Switch for Reconfigurable Spin Filters2019

    • Author(s)
      Suda Masayuki、Thathong Yuranan、Promarak Vinich、Kojima Hirotaka、Nakamura Masakazu、Shiraogawa Takafumi、Ehara Masahiro、 Yamamoto Hiroshi M.
    • Organizer
      13th International Symposium on Crystalline Organic Metals, Superconductors and Magnets
    • Related Report
      2019 Research-status Report
    • Int'l Joint Research
  • [Presentation] 機能性有機単分子膜を利用した固体物性の外場制御2019

    • Author(s)
      須田理行
    • Organizer
      第10回 分子アキテクトニクス研究会
    • Related Report
      2019 Research-status Report
    • Invited

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Published: 2019-07-04   Modified: 2022-01-27  

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