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Development and Application of Methods for Catalytic Asymmetric Synthesis of Planar-Chiral Metallocene Complexes

Research Project

Project/Area Number 20200051
Research Category

Grant-in-Aid for Scientific Research on Innovative Areas (Research a proposed research project)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Organic industrial materials
Research InstitutionHokkaido University

Principal Investigator

OGASAWARA Masamichi  Hokkaido University, 触媒化学研究センター, 准教授 (70301231)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥29,900,000 (Direct Cost: ¥23,000,000、Indirect Cost: ¥6,900,000)
Fiscal Year 2010: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Fiscal Year 2009: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Fiscal Year 2008: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
Keywordsメタロセン / 不斉合成 / 面不斉 / 均一系触媒 / 有機金属錯体 / 遷移金属触媒 / 光学活性 / メタセシス
Research Abstract

As shown in various planar-chiral metallocenylphosphine ligands, transition-metal complexes with planar chirality are useful chiral templates and have been utilized in asymmetric synthesis as chiral catalysts and chiral reagents. In spite of their usefulness, catalytic asymmetric reactions of preparing such planar-chiral compounds have bee extremely rare. In this research project, we have succeeded to develop various novel protocols of catalytically preparing planar-chiral metallocene derivatives in high enantiomeric purity. The methods we have developed include kinetic resolution of racemic planar-chiral metallocenes as well as asymmetric desymmetrization of planar-prochiral phosphaferrocenes. We have also demonstrated that our methods can be applicable to kinetic resolution of planar-chiral (η^6-arene)chromium complexes, indicating potential versatility of the protocols.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (75 results)

All 2011 2010 2009 2008 Other

All Journal Article (26 results) (of which Peer Reviewed: 26 results) Presentation (47 results) Book (2 results)

  • [Journal Article] Preparation of Osmium- 5-Phospholide Complexes and Their Reactions with Acyl Electrophiles : C=O Bond Cleavage and C-C Bond Formation within Metal-Coordination Sphere2011

    • Author(s)
      Ogasawara, M., Shintani, M., Watanabe, S., Sakamoto, T., Nakajima, K., Takahashi, T.
    • Journal Title

      Organometallics 30

      Pages: 1487-1492

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Osmium-η^5-Phospholide Complexes and Their Reactions with Acyl Electrophiles : C=O Bond Cleavage and C-C Bond Formation within Metal-Coordination Sphere2011

    • Author(s)
      小笠原正道
    • Journal Title

      Organometallics

      Volume: 30 Pages: 1487-1492

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of Planar-Chiral Phosphaferrocenes by Molybdenum-Catalyzed Asymmetric Interannular Ring-Closing Metathesis2010

    • Author(s)
      Ogasawara, M., Watanabe, S., Nakajima, K., Takahashi, T.
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 2136-2137

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenylsilanes and Their Application to S_E2' Chirality Transfer Reactions2010

    • Author(s)
      Ogasawara, M., Okada, A., Subbarayan, V., Sorgel, S., Takahashi, T.
    • Journal Title

      Org.Lett. 12

      Pages: 5736-5739

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of Planar-Chiral Phosphaferrocenes by Molybdenum-Catalyzed Asymmetric Interannular Ring-Closing Metathesis2010

    • Author(s)
      小笠原正道
    • Journal Title

      Journal of the American Chemical Society

      Volume: 132 Pages: 2136-2137

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenyl-silanes and Their Application to S_E2' Chirality Transfer Reactions2010

    • Author(s)
      小笠原正道
    • Journal Title

      Organic Letters

      Volume: 12 Pages: 5736-5739

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of Planar-Chiral Phosphaferrocenes by Molybdenum-Catalyzed Asymmetric Interannular Ring-Closing Metathesis2010

    • Author(s)
      小笠原正道
    • Journal Title

      Journal of the American Chemical Society 132

      Pages: 2136-2137

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Fluorinated Allenes via Palladium-Catalyzed Monofluoromethylation Using FBSM2009

    • Author(s)
      Ogasawara, M., Murakami, H., Furukawa, T., Takahashi, T., Shibata, N.
    • Journal Title

      Chem.Commun.

      Pages: 7366-7368

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unusual Transposition of Allenic Framework in Intramolecular Cyclization of Acetal-Tethered (Allenylmethyl)silanes2009

    • Author(s)
      Ogasawara, M., Okada, A., Murakami, H., Watanabe, S., Ge, Y., Takahashi, T.
    • Journal Title

      Org.Lett. 11

      Pages: 4240-4243

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Synthesis of Endocyclic Allenes and Their Application in Stereoselective [2+2]Cycloaddition with Ketenes2009

    • Author(s)
      Ogasawara, M., Okada, A., Nakajima, K., Takahashi, T.
    • Journal Title

      Org.Lett. 11

      Pages: 177-180

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Enantioselective Synthesis of Axially Chiral Allenes2009

    • Author(s)
      Ogasawara, M.
    • Journal Title

      Tetrahedron:Asymmetry 20

      Pages: 259-271

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Transition-Metal-Catalyzed Enantioselective Synthesis of Compounds with Non-Centrochirality2009

    • Author(s)
      Ogasawara, M., Watanabe, S.
    • Journal Title

      Synthesis

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] メタセシス反応を用いる面不斉メタロセン類の立体選択的合成法の開発2009

    • Author(s)
      小笠原正道・渡邉進
    • Journal Title

      触媒 51

      Pages: 583-587

    • NAID

      10026055014

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic Enantioselective Synthesis of Axially Chiral Allenes2009

    • Author(s)
      小笠原正道
    • Journal Title

      Tetrahedron : Asymmetry 20

      Pages: 259-271

    • Related Report
      2009 Annual Research Report 2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transition-Metal-Catalyzed Enantioselective Synthesis of Compounds with Non-Centrochirality2009

    • Author(s)
      小笠原正道
    • Journal Title

      Synthesis

      Pages: 1761-1785

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unusual Transposition of Allenic Framework in Intramolecular Cyclization of Acetal-Tethered(Allenylmethyl)silanes2009

    • Author(s)
      小笠原正道
    • Journal Title

      Organic Letters 11

      Pages: 4240-4243

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Fluorinated Allenes via Palladium-Catalyzed Monofluoromethylation Using FBSM2009

    • Author(s)
      小笠原正道
    • Journal Title

      Chemical Communications

      Pages: 7366-73678

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] メタセシス反応を用いる面不斉メタロセン類の立体選択的合成法の開発2009

    • Author(s)
      小笠原正道
    • Journal Title

      触媒 51

      Pages: 583-587

    • NAID

      10026055014

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Palladium-Catalyzed Synthesis of Endocyclic Allenes and Their Application in Stereoselective [2+2]Cvcloaddition with Ketenes2009

    • Author(s)
      小笠原正道
    • Journal Title

      Organic Letters 11

      Pages: 177-180

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transition-Metal-Catalyzed Enantioselective Synthesis of Compounds with Non-Centrochirality2009

    • Author(s)
      小笠原正道
    • Journal Title

      Synthesis (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of [4]- and [5]Ferrocenophanes by Ruthenium-Catalyzed Ring-Closing Ene-Yne Metathesis2008

    • Author(s)
      Ogasawara, M., Watanabe, S., Nakajima, K., Takahashi, T.
    • Journal Title

      Organometallics 27

      Pages: 6565-6569

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Synthesis of Planar-Chiral Ferrocenes by Mo- or Ru-Catalyzed Enantioselective Metathesis2008

    • Author(s)
      Ogasawara, M., Watanabe, S., Nakajima, K., Takahashi, T.
    • Journal Title

      Pure Appl.Chem. 80

      Pages: 1109-1113

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] パラジウム錯体触媒による置換アレン類の立体選択的合成法の開発とその応用2008

    • Author(s)
      小笠原正道
    • Journal Title

      有機合成化学協会誌 66

      Pages: 100-109

    • NAID

      10021173451

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Synthesis of Planar-Chiral Ferrocenes by Mo- or Ru-Catalyzed Enantioselective Metathesis2008

    • Author(s)
      小笠原正道
    • Journal Title

      Pure and Applied Chemistry 80

      Pages: 1109-1113

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of [41- and [5]Ferrocenophanes by Ruthenium-Catalyzed Ring-Closing Ene-Yne Metathesis2008

    • Author(s)
      小笠原正道
    • Journal Title

      Organometallics 27

      Pages: 6565-6569

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ring-Closing Metathesis within Chromium-Coordination Sphere : Facile Access to Phosphine-Chelate (π-Arene)chromium Complexes

    • Author(s)
      Ogasawara, M., Wu, W.-Y., Arae, S., Morita, T., Watanabe, S., Takahashi, T., Kamikawa, K.
    • Journal Title

      J.Organomet.Chem. in press

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Presentation] Catalytic Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes2011

    • Author(s)
      Ogasawara, M.
    • Organizer
      Third UK/Japan Conference in Catalytic Asymmetric Synthesis, Oxford University
    • Place of Presentation
      Oxford, United Kingdam
    • Related Report
      2010 Final Research Report
  • [Presentation] ホスファメタロセン類の同一環フリーデル・クラフツ二重アシル化反応2011

    • Author(s)
      小笠原正道
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜市)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 不斉閉環メタセシス反応を利用した速度論分割による面不斉(ジヒドロインデニル)鉄(II)誘導体の不斉合成2011

    • Author(s)
      荒江祥永
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜市)
    • Related Report
      2010 Annual Research Report
  • [Presentation] モリブデン触媒不斉閉環メタセシスによる面不斉アレーンクロム錯体の速度論分割2011

    • Author(s)
      呉威毅
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜市)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 不斉炭素を持たない光学活性化合物の作り分け2010

    • Author(s)
      小笠原正道
    • Organizer
      36th JAIセミナーin東京
    • Place of Presentation
      大手町サンスカイルーム(東京)(招待講演)
    • Year and Date
      2010-12-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation of Novel Sterically Demanding Chiral Biarylbisphosphine Ligand and Its Application in Pd-Catalyzed Synthesis of Axially Chiral Allenes2010

    • Author(s)
      一尾裕章
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学(八王子市)
    • Year and Date
      2010-09-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Palladium-Catalyzed Direct Arylation of Unfunctionalized Arenes with Aryl Halides2010

    • Author(s)
      Velusamy Subbarayan
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学(八王子市)
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 不斉閉環メタセシス反応を用いた非対称1,2-ジアリルメタロセンの速度論分割2010

    • Author(s)
      荒江祥永
    • Organizer
      北海道支部2009年夏季研究発表会
    • Place of Presentation
      函館工専(函館市)
    • Year and Date
      2010-07-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Kinetic Resolution of Racemic Planar-Chiral Ferrocenylphosphines by Mo-Catalyzed Asymmetric Ring-Closing Metathesis2010

    • Author(s)
      小笠原正道
    • Organizer
      24th International Conference on Organometallic Chemistry
    • Place of Presentation
      Taipei (Taiwan)
    • Year and Date
      2010-07-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] 均一系触媒による非中心不斉の立体制御-軸不斉アレンと面不斉メタロセンのエナンチオ選択的合成法の開発と応用2010

    • Author(s)
      小笠原正道
    • Organizer
      有機合成化学協会東北支部・春の講演会
    • Place of Presentation
      東北大学(仙台市)
    • Year and Date
      2010-07-03
    • Related Report
      2010 Final Research Report
  • [Presentation] 均一系触媒による非中心不斉の立体制御2010

    • Author(s)
      小笠原正道
    • Organizer
      有機合成化学協会東北支部春の講演会
    • Place of Presentation
      東北大学(仙台市)(招待講演)
    • Year and Date
      2010-07-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] 配座の自由度を制限された螺旋不斉共役ジエンホスフィンの合成と応用2010

    • Author(s)
      中島光
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪市)
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] パラジウム触媒による軸不斉アルキルアレンの不斉合成2010

    • Author(s)
      小笠原正道
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪市)
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] パラジウム触媒環化反応による環状アレン、アレノファンの合成2010

    • Author(s)
      一尾裕章
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪市)
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis of 1,1'-Diallylmetallocenes : Catalytic Asymmetric Synthesis of Planar-Chiral Metallocenes2010

    • Author(s)
      Ogasawara, M.
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
    • Place of Presentation
      the Hilton Hotel, Honolulu, USA
    • Related Report
      2010 Final Research Report
  • [Presentation] Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis of 1,1'-Diallylmetallocenes : Catalytic Asymmetric Synthesis of Planar-Chiral Metallocenes2010

    • Author(s)
      小笠原正道
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Honolulu (Hawaii, USA)(招待講演)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of Phosphaosmocenes and Their Reactions with Acyl Electrophiles : C=O Cleavage and C-C Coupling within Metal-Coordination Sphere2010

    • Author(s)
      小笠原正道
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Honolulu (Hawaii, USA)(招待講演)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Pd-Catalyzed Aymmetric Synthesis of Unfunctionalized Axially Chiral Allenic Hydrocarbons2010

    • Author(s)
      小笠原正道
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Honolulu (Hawaii, USA)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and Application of Helically Chiral Phosphine Derivatives with Atropisomeric Dienyl Skeleton2010

    • Author(s)
      中島光
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Honolulu (Hawaii, USA)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of Cyclic Allenes and Allenophanes by Palladium-Catalyzed Cyclization of Malonate-Tethered 2-Bromo-1,3-dienes2010

    • Author(s)
      一尾裕章
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Honolulu (Hawaii, USA)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mo-Catalyzed Asymmetric Synthesis of Planar-Chiral Metallocenylphosphines and Their Application as Chiral Ligands2010

    • Author(s)
      荒江祥永
    • Organizer
      PACIFICHEM 2010
    • Place of Presentation
      Honolulu (Hawaii, USA)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 遷移金属触媒による非中心不斉の立体制御:軸不斉アレンと面不斉メタロセンの触媒的不斉合成2009

    • Author(s)
      小笠原正道
    • Organizer
      フルオロテクノロジーの育成と創薬、材料、エネルギー、環境への展開に関する研究会
    • Place of Presentation
      名古屋工業大学(名古屋市)
    • Year and Date
      2009-12-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] Catalytic Enantioselective Synthesis of Planar-Chiral Metallocenes2009

    • Author(s)
      小笠原正道
    • Organizer
      65th ACS Southwest Regional Meeting
    • Place of Presentation
      Camino Real Hotel(El Paso, USA)
    • Year and Date
      2009-11-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] Catalytic Asymmetric Synthesis of Planar-Chiral Metallocenylphosphine Derivatives2009

    • Author(s)
      小笠原正道
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      同志社大学(京都市)
    • Year and Date
      2009-09-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] Synthesis and Reactivity of Phosphaosmocenes2009

    • Author(s)
      小笠原正道
    • Organizer
      3rd Internaional Symposium on Synergy of Elements
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2009-08-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] 螺旋不斉共役ジエンの配座安定性と置換基の効果2009

    • Author(s)
      中島光
    • Organizer
      北海道支部2009年夏季研究発表会
    • Place of Presentation
      苫小牧工専(苫小牧市)
    • Year and Date
      2009-07-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] パラジウム触媒分子内環化反応による環状アレンの合成2009

    • Author(s)
      一尾裕章
    • Organizer
      北海道支部2009年夏季研究発表会
    • Place of Presentation
      苫小牧工専(苫小牧市)
    • Year and Date
      2009-07-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Transition-Metal-Catalyzed Enantioselective Synthesis of Planar-Chiral Transition-Metal Complexes2009

    • Author(s)
      小笠原正道
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学(船橋)
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] ホスファオスモセンの合成とその反応2009

    • Author(s)
      小笠原正道
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学(船橋)
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 不斉閉環メタセシス反応による面不斉フェロセニルホスフィンの触媒的不斉合成2009

    • Author(s)
      渡邉進
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学(船橋)
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] パラジウム触媒による軸不斉(フルオロアルキル)アレンの不斉合成2009

    • Author(s)
      村上栄敏
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学(船橋)
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Catalytic Asymmetric Synthesis of Planar-Chiral Metallocenes2009

    • Author(s)
      Ogasawara, M.
    • Organizer
      65th Southwest Regional Meeting of the American Chemical Society
    • Place of Presentation
      the Camino Real Hotel, El Paso, USA
    • Related Report
      2010 Final Research Report
  • [Presentation] Pd-Catalyzed Asymmetric Synthesis of Unfunctionalized Axially Chiral Allenic Hydrocarbons by Desulfonylation Approach : Total Synthesis of Extract from Australian Melolonthine Scarab Beetles2009

    • Author(s)
      小笠原正道
    • Organizer
      IKCOC-11
    • Place of Presentation
      リーガロイヤルホテル(京都市)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Catalytic Enantioselective Synthesis of Planar-Chiral Metallocenes Bearing Lewis-Basic Phosphorus and Their Application as Chiral Ligands2009

    • Author(s)
      渡邉進
    • Organizer
      IKCOC-11
    • Place of Presentation
      リーガロイヤルホテル(京都市)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 遷移金属触媒による非中心不斉の立体制御一軸不斉アレンと面不斉メタロセンの触媒的不斉合成2008

    • Author(s)
      小笠原正道
    • Organizer
      北海道大学グローバルCOEシンポジゥム
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2008-10-24
    • Related Report
      2008 Annual Research Report
  • [Presentation] Enantioselective Synthesis of Various Planar-Chiral Metallocenes Catalyzed by Chiral Mo or Ru-Carbene Complexes2008

    • Author(s)
      小笠原正道
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪府立大学(界市)
    • Year and Date
      2008-09-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 面不斉メタロセンの触媒的不斉合成と光学活性メタロセン・ポリマー合成への応用2008

    • Author(s)
      小笠原正道
    • Organizer
      京都大学グローバルCOE有機若手ワークショップ
    • Place of Presentation
      京都大学(京都市)
    • Year and Date
      2008-09-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] 均一系触媒による遷移金属錯体の立体選択的分子変換一面不斉メタロセンの触媒的不斉合成の開発2008

    • Author(s)
      小笠原正道
    • Organizer
      有機化学と無機化学の交流シンポジウム
    • Place of Presentation
      岡山大学(岡山)
    • Year and Date
      2008-07-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 8族ホスファメタロセン類の合成と反応2008

    • Author(s)
      新谷穣
    • Organizer
      北海道支部2008年夏季研究発表会
    • Place of Presentation
      北見工業大学(北見市)
    • Year and Date
      2008-07-19
    • Related Report
      2008 Annual Research Report
  • [Presentation] ホモアレニルシランの分子内環化における特異なallene-to-allene転位反応とその反応機構2008

    • Author(s)
      村上栄敏
    • Organizer
      北海道支部2008年夏季研究発表会
    • Place of Presentation
      北見工業大学(北見市)
    • Year and Date
      2008-07-19
    • Related Report
      2008 Annual Research Report
  • [Presentation] Insituで発生させたモリブデンーカルベン錯体による面不斉メタロセン類の触媒的不斉合成2008

    • Author(s)
      渡邉進
    • Organizer
      北海道支部2008年夏季研究発表会
    • Place of Presentation
      北見工業大学(北見市)
    • Year and Date
      2008-07-19
    • Related Report
      2008 Annual Research Report
  • [Presentation] Ring-Opening Metathesis Polymerization of Planar-Chiral Butadiene Bridged Ferrocenobhanes2008

    • Author(s)
      小笠原正道
    • Organizer
      23rd International Conference on Organometallic Chemistry
    • Place of Presentation
      Rennes (France)
    • Year and Date
      2008-07-14
    • Related Report
      2008 Annual Research Report
  • [Presentation] Enantioselective Synthesis of Planar-Chiral Metallocenes by Mo- or Ru-Catalyzed Interannular Ring-Closing Metathesis2008

    • Author(s)
      渡邉進
    • Organizer
      23^<rd> International Conference on Organometallic Chemistry
    • Place of Presentation
      Rennes(France)
    • Year and Date
      2008-07-14
    • Related Report
      2008 Annual Research Report
  • [Presentation] Transition-Metal-Catalyzed Asymmetric Synthesis of Planar-Chiral Metallncenes2008

    • Author(s)
      小笠原正道
    • Organizer
      Taiwan-Japan International Symposium on Organic Chemistry and Molecular Science
    • Place of Presentation
      Taipei (Taiwan)
    • Year and Date
      2008-04-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenvlsilanes and Their Application in Chirality Transfer Reactions2008

    • Author(s)
      小笠原正道
    • Organizer
      235th ACS National Meeting
    • Place of Presentation
      New Orleans (USA)
    • Year and Date
      2008-04-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] Enantioselective Synthesis of Planar-Chiral Ferrocenes by Asymmetric Ring-Closing Metathesis2008

    • Author(s)
      渡邉進
    • Organizer
      235th ACS National Meeting
    • Place of Presentation
      New Orleans (USA)
    • Year and Date
      2008-04-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] 面不斉メタロセンの触媒的不斉合成と光学活性メタロセン・ポリマー合成への応用2008

    • Author(s)
      小笠原正道
    • Organizer
      京都大学グローバルCOE有機若手ワークショップ、京都大学グローバルCOEプログラム
    • Place of Presentation
      京都大学大学院理学研究科(京都市)
    • Related Report
      2010 Final Research Report
  • [Book] 合成有機化学 反応機構によるアプローチ(原著:Parashar, R.K.Reaction Mechanisms in Organic Synthesis, Wiley Interscience)2011

    • Author(s)
      柴田高範・小笠原正道・鹿又宣弘・斉藤慎一・庄司満訳
    • Total Pages
      436
    • Publisher
      東京化学同人
    • Related Report
      2010 Final Research Report
  • [Book] Compounds with All-Carbon Functions : Cumulenes and Allenes(Product Class 1 : Cumulenes In Science of Synthesis, Houben-Weyl, Methods of Molecular Transformations : Vol. 44)(Krause, N., ed.)2008

    • Author(s)
      Ogasawara, M.
    • Publisher
      Georg Thieme Verlag : Stuttgart
    • Related Report
      2010 Final Research Report

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Published: 2008-04-01   Modified: 2018-03-28  

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