| Budget Amount *help |
¥159,510,000 (Direct Cost: ¥122,700,000、Indirect Cost: ¥36,810,000)
Fiscal Year 2012: ¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2011: ¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2010: ¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2009: ¥26,000,000 (Direct Cost: ¥20,000,000、Indirect Cost: ¥6,000,000)
Fiscal Year 2008: ¥55,510,000 (Direct Cost: ¥42,700,000、Indirect Cost: ¥12,810,000)
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| Research Abstract |
A variety of methods for carbon-carbon bond formation have been developed by the aid of transition metal catalysts, which enabled introduction of congested secondary and tertiary alkyl groups into organic molecules, multi-component coupling incorporating unsaturated hydrocarbons such as alkynes and dienes, and cross coupling via cleavage of unreactive bonds such as C-F, C-O and C-H. These successful results demonstrated potent catalytic reactivities of anionic transition metal species as key intermediates in various synthetic reaction processes. Catalytic reactions for concomitant construct of carbon-carbon bonds and carbon-heteroatom bonds and those using electronically and/or structurally flexible metal complexes were also developed.
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