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Structural Investigation of Photo-Excited States of Large Molecular Systems by using Laser-Induced Pulsed X-ray

Research Project

Project/Area Number 20245002
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

FUKUMURA Hiroshi  東北大学, 大学院・理学研究科, 教授 (50208980)

Co-Investigator(Kenkyū-buntansha) KAJIMOTO Shinji  東北大学, 大学院・理学研究科, 助教 (80463769)
ZHANPEISOV Nurbosyn  東北大学, 国際教育院, 准教授 (10326275)
Co-Investigator(Renkei-kenkyūsha) ZHANPEISOV Nurbosyn  東北大学, 国際教育院, 准教授 (10326275)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2010: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywordsレーザー誘起X線 / 時間分解X線回折 / 硫酸銅結晶 / 液体のX線回折 / レーザー誘起X線発生 / d-d遷移 / シクロヘキサン / 動径分布関数 / 光励起状態 / アゾベンゼン / X線光学系 / 四塩化炭素
Research Abstract

An ultrafast X-ray diffraction measurement system has been built up by using a pulsed X-ray source generated with the focusing of femtosecond laser pulses onto a suitable target. The system was utilized for measuring transient lattice changes of a few semiconductor and copper sulfate penta-hydrate crystals induced with photo-excitation. In addition, it has been shown that changes in the radial distribution function due to structural changes of photochromic molecules can be obtained from X-ray scattering patterns of the solution including the molecules as solutes.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (28 results)

All 2010 2009 2008

All Journal Article (14 results) (of which Peer Reviewed: 12 results) Presentation (14 results)

  • [Journal Article] 溶液内における光化学反応の新展開. 超高速時間分解X線散乱による反応ダイナミクス2010

    • Author(s)
      福村裕史
    • Journal Title

      化学

      Volume: 65 Pages: 70-71

    • Related Report
      2010 Final Research Report
  • [Journal Article] Photo-controlled phase separation and mixing of a mixture of water and 2-butoxyethanol caused by photochromic isomerisation of spiropyran2010

    • Author(s)
      S.Kajimoto, A.Mori, H.Fukumura
    • Journal Title

      PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIE NCES

      Volume: 9 Pages: 208-212

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] On the origin of the Raman band shifts for H-bonded complexes of normal alcohols and 2-butoxyethanol with water : A theoretical DFT and MP2 study2010

    • Author(s)
      N.U.Zhanpeisov, S.Takanashi, S.Kajimoto, H.Fukumura
    • Journal Title

      CHEMICAL PHYSICS LETTERS

      Volume: 491 Pages: 151-155

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A picoseconds Hard X-ray Study of the Fluorescence Dynamics of Anthracene Derivatives and 8-Hydroxyquinoline Complex Microcrystals2009

    • Author(s)
      H. Odaka, T. Miura, K. Hatanaka, S. Wiebel & H. Fukumura
    • Journal Title

      J. Phys. Chem. C

      Volume: 113 Pages: 11969-11974

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Circularly Polarized Femtosecond Laser-Induced Pulsed X-Ray Emission from Distilled Water2009

    • Author(s)
      D. Sato, S. Matsushima, H. Ono, S. Kajimoto, H. Fukumura & K. Hatanaka
    • Journal Title

      レーザー研究

      Volume: 37 Pages: 901-904

    • NAID

      10026195890

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Subdiffraction Limited, Remote Excitation of Surface Enhanced Raman Scattering.2009

    • Author(s)
      J.A. Hutchison, S.P. Centeno, H.Odaka, H.Fukumura, J.Hofkens, H.Uji-i
    • Journal Title

      NANO LETTERS 9

      Pages: 995-1001

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Picosecond Hard X-ray Study of the Fluorescence Dynamics of Anthracene Derivatives and 8-Hydroxyquinoline Complex Microcrystals.2009

    • Author(s)
      H.Odaka, T.Miura, K.Hatanaka, S.Wiebel, H.Fukumura
    • Journal Title

      Journal of Physical Chemistry C 113

      Pages: 11969-11974

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interaction of Single Water Molecule with a Single Graphite Layer : An Integrated ONIOM Study.2009

    • Author(s)
      N.U. Zhanpeisov, G.M. Zhidomirov, H.Fukumura
    • Journal Title

      Journal of Physical Chemistry C 113

      Pages: 6118-6123

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      H.Fukumura, Y.Iwasawa, H.Masuhara, K.Uosaki, M.Irie
    • Journal Title

      Molecular Nano Dynamics, Volume 1 and 2(Wiley-VCH Verlag GmbH & CO. KGaA)

      Pages: 3-18

    • Related Report
      2009 Annual Research Report
  • [Journal Article] X-ray pulse emission from cesium chloride aqueous solutions when irradiated by double-pulsed femtosecond laser pulses2008

    • Author(s)
      K. Hatanaka, H. Ono & H. Fukumura
    • Journal Title

      Appl. Phys. Lett

      Volume: 93 Pages: 64103-64103

    • NAID

      120000775199

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hard X-ray generation using femtosecond irradiation of PbO glass2008

    • Author(s)
      K. Hatanaka, K. Yomogihata, H. Ono, K. Nagafuchi, H. Fukumura, M. Fukushima, T. Hashimoto, S. Juodkazis & H. Misawa
    • Journal Title

      J. Non-Cryst. Solids

      Volume: 345 Pages: 5485-5490

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chirp effect in hard X-ray generation from liquid target when irradiated by femtosecond pulses2008

    • Author(s)
      K. Hatanaka, T. Ida, H. Ono, S. Matsushima, H. Fukumura, S. Juodkazis & H. Misawa
    • Journal Title

      Opt. Express

      Volume: 17 Pages: 12650-12657

    • NAID

      120003728353

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] X-ray pulse emission from cesium chloride aqueous solutions when irradiated by double-pulsed femtosecond laser pulses2008

    • Author(s)
      K. Hatanaka, H. Ono, H. Fukumura
    • Journal Title

      APPLIED PHYSICS LETTERS 93

    • NAID

      120000775199

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chirp effect in hard X-ray generation from liquid target when irradiated by femtosecond pulses2008

    • Author(s)
      K. Hatanaka, T. Ida, H. Ono, S. Matsushima, et.al.
    • Journal Title

      Optics Express 16

      Pages: 12650-12657

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Laser-Induced X-ray Sources for Time-Resolved Diffraction of Transient States of Solids and in solutions2010

    • Author(s)
      S. Matsushima, H. Sotome, S. Kajimoto & H. Fukumura
    • Organizer
      6^<th> Asian Photochemistry Conference
    • Place of Presentation
      Wellington, New Zealand
    • Year and Date
      2010-11-16
    • Related Report
      2010 Final Research Report
  • [Presentation] Laser-Induced X-ray Sources for Time-Resolved Diffraction of Transient States of Solids and in Solutions2010

    • Author(s)
      S.Matsushima, H.Sotome, S.Kajimoto, H.Fukumura
    • Organizer
      6^<th> Asian Photochemistry Conference 2010
    • Place of Presentation
      ニュージーランド,ウェリントン
    • Year and Date
      2010-11-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] フェムト秒レーザー誘起パルスX線回折法による無機結晶の過渡的構造変化2010

    • Author(s)
      松島進一, 五月女光, 東遥介, 梶本真司, 福村裕史
    • Organizer
      第4回分子科学討論会2010大阪
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-14
    • Related Report
      2010 Final Research Report
  • [Presentation] X線散乱測定による溶液内4, 4'-ジヨードアゾベンゼンの光異性化反応の追跡2010

    • Author(s)
      五月女光, 小野林季, 松島進一, 梶本真司, 福村裕史, 大西和樹, 西川康明, 内田欣吾
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉
    • Year and Date
      2010-09-08
    • Related Report
      2010 Final Research Report
  • [Presentation] 溶液内光異性化過程の観測に向けたレーザー誘起パルスX線を用いたX線散乱測定2009

    • Author(s)
      五月女光, 小野林季, 松島進一, 小野博司, 梶本真司, 福村裕史, 大西和樹, 西川康明, 内田欣吾
    • Organizer
      2009年分子科学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2009-09-21
    • Related Report
      2010 Final Research Report
  • [Presentation] サブピコ秒時間分解X線回折を用いた硫酸銅五水和物単結晶の光励起に伴う超高速ダイナミクス2009

    • Author(s)
      松島進一, 五月女光, 梶本真司, 畑中耕治, 池田憲昭, 福村裕史
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      桐生
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report
  • [Presentation] Ultrafast X-ray Diffraction Study on the d-d Transition of Copper Sulfate Pentahydrate Single Crystals2009

    • Author(s)
      S. Matsushima, H. Sotome, S. Kajimoto, K. Hatanaka, N. Ikeda, H. Fukumura
    • Organizer
      Global COE Summer School 2009
    • Place of Presentation
      仙台
    • Year and Date
      2009-08-21
    • Related Report
      2010 Final Research Report
  • [Presentation] ULTRAFAST X-RAY PULSE GENERATION AND ITS APPLICATION TO TIME-RESOLVED DIFFRACTION OF INORGANIC SOLIDS2009

    • Author(s)
      S. Matsushima, H. Odaka, H. Ono, K. Hatanaka, H. Sotome, S. Kajimoto & H. Fukumura
    • Organizer
      XXIV International Conference on Photochemistry
    • Place of Presentation
      Toledo, Spain
    • Year and Date
      2009-07-24
    • Related Report
      2010 Final Research Report
  • [Presentation] ULTRAFAST X-RAY PULSE GENERATION AND ITS APPLICATIONTO TIME-RESOLVED DIFFRACTION OF INORGANIC SOLIDS.2009

    • Author(s)
      S.Matsushima, H.Odaka, H.Ono, K.Hatanaka, H.Sotome, S.Kajimoto, H.Fukumura
    • Organizer
      International Conference on Photochemistry
    • Place of Presentation
      スペイン、トレド
    • Year and Date
      2009-07-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] X-ray Diffraction Studies of a Structural dynamics with Ligand Field Absorption of a Copper Sulfate Pentahydrate Single Crystal2009

    • Author(s)
      S. Matsushima, S. Kajimoto, K. Hatanaka, H. Fukumura, C. W. Schneider, T. Lippert
    • Organizer
      JSPS-KOSEF Asian Science Seminar : Frontiers of the Photocatalysis and Photochemistry of Advanced Materials
    • Place of Presentation
      川崎
    • Year and Date
      2009-03-04
    • Related Report
      2010 Final Research Report
  • [Presentation] Ultrafast X-ray Diffraction Study of Structural Dynamics of Ligand-field Excited States of Copper Sulfate Pentahydrate2009

    • Author(s)
      S. Matsushima, S. Kajimoto, K. Hatanaka, H. Fukumura, C. W. Schneider, T. Lippert
    • Organizer
      Asian Science Seminar 2009
    • Place of Presentation
      Kawasaki, Japan
    • Related Report
      2008 Annual Research Report
  • [Presentation] Table-top laser-induced x ray and its application to analytical chemistry and physical chemistry2008

    • Author(s)
      Hiroshi Fukumura
    • Organizer
      Seminar at University of Melbourne
    • Place of Presentation
      Melbourne, Australia
    • Year and Date
      2008-12-02
    • Related Report
      2008 Annual Research Report
  • [Presentation] X-ray Intensity Increase due to transient Phenomena Induced by Femtosecond Laser Double Pulse Irradiation onto Aqueous Solution Films2008

    • Author(s)
      H. Ono, K. Hatanaka & H. Fukumura
    • Organizer
      Global COE Summer School
    • Place of Presentation
      仙台
    • Year and Date
      2008-08-18
    • Related Report
      2010 Final Research Report
  • [Presentation] Towards Sub-picoseconds Time-resolved X-ray Diffraction Measurement of a Copper(II)Sulfate Pentahydrate Single Crystal2008

    • Author(s)
      S. Matsushima, K. Ono, T. Yokota, K. Hatanaka & H. Fukumura
    • Organizer
      Global COE Summer School
    • Place of Presentation
      仙台
    • Year and Date
      2008-08-18
    • Related Report
      2010 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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