Redox Conversion of Organic Reactive Intermediates
Project/Area Number |
20245008
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Research Category |
Grant-in-Aid for Scientific Research (A)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic chemistry
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Research Institution | Kyoto University |
Principal Investigator |
YOSHIDA Jun-ichi Kyoto University, 大学院・工学研究科, 教授 (30127170)
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Co-Investigator(Kenkyū-buntansha) |
NOKAMI Toshiki 京都大学, 大学院・工学研究科, 助教 (60402963)
|
Project Period (FY) |
2008 – 2010
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Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥48,100,000 (Direct Cost: ¥37,000,000、Indirect Cost: ¥11,100,000)
Fiscal Year 2010: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Fiscal Year 2009: ¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
Fiscal Year 2008: ¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
|
Keywords | 有機カチオン / 有機ラジカル / 有機アニオン / レドックス / 活性種 / 有機カチ |
Research Abstract |
Reduction of organic cations generated by the cation pool method and oxidation of organic anions generated by the anion flow method were studied. The resulting organic radical species could be effectively used for synthetic reactions. The results obtained in this study open new possibilities of redox conversion of organic reactive intermediates in organic synthesis.
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Report
(4 results)
Research Products
(126 results)
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[Journal Article] Glycosyl Sulfonium Ions as Storable Intermediates for Glycosylations2011
Author(s)
Nokami, T., Nozaki, Y., Saigusa, Y., Shibuya, A., Manabe, S., Ito, Y., Yoshida, J.
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Journal Title
Org.Lett. 13
Pages: 1544-1547
Related Report
Peer Reviewed
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[Journal Article]2011
Author(s)
Nagaki, A., Miyazaki. A., Tomida, Y., Yoshida, J.
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Journal Title
Chem.Eng.J. 167
Pages: 548-555
Related Report
Peer Reviewed
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[Journal Article] Glycosyl Sulfonium Ions as Storable Intermediates for Glycosylations2011
Author(s)
Nokami, T., Nozaki, Y., Saigusa, Y., Shibuya, A., Manabe, S., Ito, Y., Yoshida, J.
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Journal Title
Org.Lett.
Volume: 13
Pages: 1544-1547
Related Report
Peer Reviewed
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[Journal Article] Cross-Coupling in a Flow Microreactor. Space Integration of Lithiation and Murahashi Coupling2010
Author(s)
Nagaki, A., Kenmoku, A., Moriwaki, Y., Hayashi, A., Yoshida, J.
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Journal Title
Angew.Chem., Int.Ed. 49
Pages: 7543-7547
Related Report
Peer Reviewed
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[Journal Article] Generation and Reaction of Cyano-Substituted Aryllithium Compounds Using Microreactors2010
Author(s)
Nagaki, A., Kim, H., Usutani, H., Matsuo, C., Yoshida, J.
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Journal Title
Org.Biomol.Chem.(Selected by the Editorial Board of Synfacts (Synfacts 2010, 582.)) 8
Pages: 1212-1212
Related Report
Peer Reviewed
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[Journal Article] Cross-Coupling in a Flow Microreactor. Space Integration of Lithiation and Murahashi Coupling2010
Author(s)
Nagaki, A., Kenmoku, A., Moriwaki, Y., Hayashi, A., Yoshida, J.
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Journal Title
Angew.Chem., Int.Ed
Volume: 49
Pages: 7543-7547
Related Report
Peer Reviewed
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[Journal Article] Generation of Diarylcarbenium Ion Pools via Electrochemical C-H bond Dissociation.2009
Author(s)
Okajima, M., Soga, K., Watanabe, T., Terao, K., Nokami, T., Suga, S., Yoshida, J.
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Journal Title
Bull.Chem.Soc.Jpn 82
Pages: 594-599
NAID
Related Report
Peer Reviewed
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[Journal Article] Electro-initiated Coupling Reactions of N-Acyliminium Ion Pools with Arylthiomethylsilanes and Aryloxymethylsilanes2008
Author(s)
Suga, S., Shimizu, I., Ashikari, Y., Mizuno, Y., Maruyama, T., Yoshida, J.
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Journal Title
Chem.Lett. 37
Pages: 1008-1009
NAID
Related Report
Peer Reviewed
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[Journal Article] Iterative Molecular Assembly Based on the Cation Pool Method. Convergent Synthesis of Dendritic Molecules.2008
Author(s)
Nokami, T., Ohata, K.;, Inoue, M., Tsuyama, H., Shibuya, A., Soga, K., Okajima, M., Suga, S., Yoshida, J.
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Journal Title
J.Am.Chem.Soc. 130
Pages: 10864-10865
Related Report
Peer Reviewed
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[Journal Article] Microflow System Controlled Carbocationic Polymerization of Vinyl Ethers2008
Author(s)
Nagaki, A., Iwasaki, T., Kawamura, K., Yamada, D., Suga, S., Ando, T., Sawamoto, M., Yoshida, J.
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Journal Title
Chem.Asian J. 3
Pages: 1558-1558
Related Report
Peer Reviewed
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[Journal Article] An Electroinitiated Cation Chain Reaction : Intramolecular Carbon-Carbon Bond Formation between Thioacetal and Olefin Groups.2008
Author(s)
Matsumoto, K., Fujie, S., Ueoka, K., Suga, S., Yoshida, J.
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Journal Title
Angew.Chem., Int.Ed. 47
Pages: 2506-2508
Related Report
Peer Reviewed
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[Journal Article] An Electroinitiated Cation Chain Reaction : Intramolecular Carbon-Carbon Bond Formation between2008
Author(s)
Matsumoto, K., Fujie, S., Ueoka, K., Suga, S., Yoshida, J.
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Journal Title
Angew. Chem., Int. Ed. 47
Pages: 2506-2508
Related Report
Peer Reviewed
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[Journal Article] Iterative Molecular Assembly Based on the Cation Pool Method. Convergent Synthesis of Dendritic Molecules.2008
Author(s)
Nokami, T., Ohata, K., Inoue, M., Tsuyama, H., Shibuya, A., Soga
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Journal Title
J. Am. Chem. Soc. 130
Pages: 10864-10865
Related Report
Peer Reviewed
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