Synthesis of Space-Controlled Lanthanide Complexes and Their Functionalization
| Project/Area Number |
20245014
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka City University |
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Principal Investigator |
TSUKUBE Hiroshi Osaka City University, 大学院・理学研究科, 教授 (00144725)
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| Co-Investigator(Kenkyū-buntansha) |
SHINODA Satoshi 大阪市立大学, 大学院・理学研究科, 准教授 (00285280)
MIYAKE Hiroyuki 大阪市立大学, 大学院・理学研究科, 准教授 (00271198)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥47,450,000 (Direct Cost: ¥36,500,000、Indirect Cost: ¥10,950,000)
Fiscal Year 2010: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2009: ¥25,610,000 (Direct Cost: ¥19,700,000、Indirect Cost: ¥5,910,000)
Fiscal Year 2008: ¥14,300,000 (Direct Cost: ¥11,000,000、Indirect Cost: ¥3,300,000)
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| Keywords | 希土類錯体 / 超分子 / 発光センシング / 分子認識 / キラリティー変換 / 金属タンパク / 円二色性スペクトル / 発光材料 / 希土類発光 / 近赤外発光 / コンビナトリアル合成 / 不斉転写 / トランスフェリン / フェリチン / センシング / 形態制御 / ナノスケール / アミノ酸 / コンビナトリアル / 情報変換 / タンパク配位子 / インテリジェント錯体 |
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| Research Abstract |
A series of lanthanide complexes have been developed, which had characteristic coordination spheres of 1 or 10 nm diameters. They offered selective luminescence and circular dichroism sensing of inorganic anions, amino acids, proton, and protein derivatives based on unique lanthanide coordination chemistry. The lanthanide complexes with octadentate cyclen ligands further exhibited enough high dynamism to mediate the chirality transfer processes.
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Report
(4 results)
Research Products
(64 results)
