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suprahierarchical natural saccharides -melecular recognition, superstructure, function-

Research Project

Project/Area Number 20245036
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Chemistry related to living body
Research InstitutionSojo University

Principal Investigator

SHINKAI Seiji  Sojo University, 工学部, 教授 (20038045)

Co-Investigator(Kenkyū-buntansha) TAMARU Shunichi  崇城大学, 工学部, 准教授 (10454951)
SHIRAKI Tomohiro  九州先端科学技術研究所, ナノテク研究室, 研究員 (10508089)
NUMATA Munenori  京都府立大学, 大学院・生命環境科学研究科, 准教授 (70423564)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2010: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2009: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Keywords多糖 / 分子認識 / 超構造 / ナノ材料 / 高分子
Research Abstract

The findings for this project are summarized as following; (1) s-1,3-glucans can form heterogeneous helical complex with nucleic acids, (2) s-1,3-glucans act as one-dimensional host toward carbon nanotube, polythiophene, gold nanoparticle,,dyes, etc., (3) the guest molecules entrapped in the helix of s-1,3-glucan show chiral properties ownig to the helical structure of host, (4) modified s-1,3-glucan allows to align the functional molecules, construct micro-size transportation system.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (47 results)

All 2010 2009 2008 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results) Presentation (26 results) Remarks (1 results)

  • [Journal Article] A Polysaccharide-Base Container Transportation System Powered by Molecular Motors2010

    • Author(s)
      Youichi TSUCHIYA, Tomotaka KOMORI, Minako HIRANO, Tomohiro SHIRAKI, Akira KAKUGO, Toru IDE, Jian-Ping GONG, Sunao YAMADA, Toshio YANAGIDA, Seiji SHINKAI
    • Journal Title

      Angewandte Chemie International Edition Vol.49, No.4

      Pages: 724-727

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermo- and Solvent-Responsive Polymer Complex Created from Supramolecular Complexation between a Helix-Forming Polysaccharide and a Cationic Polythiophene2010

    • Author(s)
      Tomohiro SUCHIYA, Arnab DAWN, Yoichi TSUCHIYA, Seiji SHINKAI,
    • Journal Title

      Journal of the American Chemical Society Vol.132, No.39

      Pages: 13928-13935

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoswitchable Supramolecular Hydrogels Formed by Cyclodextrins and Azobenzene Polymers2010

    • Author(s)
      Shingo TAMESUE, Yoshinori TAKASHIMA, Hiroyasu YAMAGUCHI, Seiji SHINKAI, Akira HARADA
    • Journal Title

      Angewandte Chemie International Edition Vol.49, No.41

      Pages: 7461-7464

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Polysaccharide-Based Container Transportation System Powered by Molecular Motors2010

    • Author(s)
      Youichi TSUCHIYA, Tomotaka KOMORI, Minako HIRANO, Tomohiro SHIRAKI, Akira KAKUGO, Toru IDE, Jian-Ping GONG, Sunao YAMADA, Toshio YANAGIDA, Seiji SHINKAI
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 49(4) Pages: 724-727

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Semiartificial Polysaccharide Can Provide a Unique Nanospace for the Construction of Supramolecular Dye-assembly2010

    • Author(s)
      Kouta SUGIKAWA, Munenori NUMATA, Kazuki SADA, Seiji SHINKAI
    • Journal Title

      Chemistry letters

      Volume: 39(5) Pages: 710-711

    • NAID

      10027182500

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermo- and Solvent-Responsive Polymer Complex Created from Supramolecular Complexation between a Helix-Forming Polysaccharide and a Cationic Polythiophene2010

    • Author(s)
      Tomohiro SHIRAKI, Arnab DAWN, Youichi TSUCHIYA, Seiji SHINKAI
    • Journal Title

      Journal of the American Chemical Society

      Volume: 132(39) Pages: 13928-13935

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoswitchable Supramolecular Hydrogels Formed by Cyclodextrins and Azobenzene Polymers2010

    • Author(s)
      Shingo TAMESUE, Yoshinori TAKASHIMA, Hiroyasu YAMAGUCHI, Seiji SHINKAI, Akira HARADA
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 49(41) Pages: 7461-7464

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Creation of supramolecular assemblies from a dipolar dye molecule by the template effect of 1,3-glucan polysaccharide2010

    • Author(s)
      S.Malik, N.Fujita, M.Numata, K.Ogura, S.Shinkai
    • Journal Title

      J.Mater.Chem.

      Volume: 20(41) Pages: 9022-9024

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Supramolecular Amphiphilies Created by Wrapping Poly(styrene) with the Helix-Forming β-1,3-Glucan Polysaccharide, Chemistry-2009

    • Author(s)
      Munenori NUMATA, Kenji KANEKO, Hitoshi TAMIAKI, Seiji SHINKAI
    • Journal Title

      A European Journal Vol.15, No.45

      Pages: 12338-12345

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Octadecylsilyl Silica Column Method for Extraction of Messenger RNA2009

    • Author(s)
      Taro KIMURA, Kazuo SAKURAI, Seiji SHINKAI
    • Journal Title

      Analytical Biochemistry 391(1)

      Pages: 72-73

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alignment of Polysaccharide-SWNT Composites by Metal-Ligand Interactions2009

    • Author(s)
      Youichi TSUCHIYA, Shuichi HARAGUCHI, Kouta SUGIKAWA, Tomohiro SHIRAKI, Kenji KANEKO, Seiji SHINKAI
    • Journal Title

      Chemistry Letters 38(8)

      Pages: 812-813

    • NAID

      10025125110

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantum Dots Arrangement and Energy Transfer Control via Charge-Transfer Complex Achieved on Poly (Phenylene Ethynylene)/Schizophyllan Nanowires2009

    • Author(s)
      Tomohiro SHIRAKI, Shuichi HARAGUCHI, Youichi TSUCHIYA, Seiji SHINKAI
    • Journal Title

      Chemistry An Asian Journal 4(9)

      Pages: 1434-1441

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of Polythophene Redox Potentials Based on Supramolecular Complexation with Helical Schizophyllan2009

    • Author(s)
      Shuichi HARAGUCHI, Youichi TSUCHIYA, Tomohiro SHIRAKI, Kazuki SADA, Seiji SHINKAI
    • Journal Title

      Chemical Communications 40

      Pages: 6086-6088

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] On the Helical Motif of the Complexes Created by Association of Helix-Formaing Schizophyllan (SPG) and Helix-Forming Polythiophene Derivatives2009

    • Author(s)
      Shuichi HARAGUCHI, Youichi TSUCHIYA, Tomohiro SHIRAKI, Kouta SUGIKAWA, Kazuki SADA, Seiji SHINKAI
    • Journal Title

      Chemistry-A European Journal 15(42)

      Pages: 11221-11228

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] "Supramolecular" Amphiphililes Created by Wrapping Poly (styrene) with the Helix-Forming ss-1, 3-Glucan Polysaccharide2009

    • Author(s)
      Munenori NUMATA, Kenji KANEKO, Hitoshi TAMIAKI, Seiji SHINKAI
    • Journal Title

      Chemistry-A European Journal 15(45)

      Pages: 12338-12345

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hierarchical Carbon Nanotube Assemblies Created by Sugar-Boric or Boronic Acid Interactions, Chemical2008

    • Author(s)
      Shingo TAMESUE, Munenori NUMATA, Kenji KANEKO, Tony D.JAMES, Seiji SHINKAI
    • Journal Title

      Communications No.37

      Pages: 4478-4480

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Polysaccharide-Templated Twisted Assemble of 2-Anilinonaphthalene-6-Sulfonic Acid2008

    • Author(s)
      Naohiko SHIMADA, Tadashi OKOBIRA, Yoichi TAKEDA, Seiji SHINKAI, Kazuo SAKURAI
    • Journal Title

      Journal of Polymer Science Part A-Polymer Chemistry z 64(4)

      Pages: 1440-1448

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Creation of Hierarchical Carbon Nanotube Assemblies through Alternative Packing of Complementary Semi-Artificial β-1, 3-Glucan/Carbon Nanotube Composites2008

    • Author(s)
      Munenori NUMATA, Kouta SUGIKAWA, Kenji KANEKO, Seiji SHINKAI
    • Journal Title

      Chemistry-A European Touurnal 14(8)

      Pages: 2398-2404

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Angle-Controlled Arrangement of Single-Walled Carbon Nanotubes Solubilised by 8-Quinolinol Metal Chelate Derivatives on Mica2008

    • Author(s)
      Kazuyuki NOBUSAWA, Atsushi IKEDA, Yasunori TANAKA, Mineo HASHIZUME, Jun-ichi KIKUCHI, Michihiro SHIRAKAWA, Tatsuya KITAHARA, Norifumi FUTITA, Sei ji SHINKAI
    • Journal Title

      Chemical Communications 15

      Pages: 1801-1803

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hierarchical Carbon Nanotube Assemblies Created by Sugar-Boric or Boronic Acid Interactions2008

    • Author(s)
      Shingo TAMESUE, Munenori NUMATA, Kenji KANEKO, Tony D. JAMES, Seiji SHINKAI
    • Journal Title

      Chemical Communications 37

      Pages: 4478-4480

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Molecular design of dynamic polymer-polymer recognition systems inspired by novel helix-forming polysaccharides2010

    • Author(s)
      新海征治
    • Organizer
      PACIFICHEM2010
    • Place of Presentation
      Honolulu
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Artificial container transportation system.2010

    • Author(s)
      Youichi TSUCHIYA, Tomotaka, KOMORI, Tomohiro SHIRAKI, Akira KAKUGO, Jian-Ping GONG, Toshio YANAGIDA, Seiji SHINKAI
    • Organizer
      PACIFICHEM2010
    • Place of Presentation
      Honolulu
    • Year and Date
      2010-12-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Design of stimuli-responsive macromolecular complexes using helix-forming polysaccharides.2010

    • Author(s)
      Tomohiro. Shiraki, Arnab Dawn, T.Le ; Youichi Tsuchiya, Seiji Shinkai
    • Organizer
      PACIFICHEM2010
    • Place of Presentation
      Honolulu
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] Dynami Polymer-Polymer Recognition Systems Inspired by Novel Helix-Forming Polysaccharides2010

    • Author(s)
      新海征治
    • Organizer
      International Symposium on Advances of Supramolecular and NanoBio Chemistry
    • Place of Presentation
      Gyeongsang National University, Jinju, Korea
    • Related Report
      2010 Final Research Report
  • [Presentation] Dynamic Polymer-Polymer Recognition Systems Inspired by Novel Helix-Forming Polysaccharides2010

    • Author(s)
      Seiji SHINKAI
    • Organizer
      International Symposium on Advances of Supramolecular and NanoBio Chemistry
    • Place of Presentation
      Gyeongsang National University, Jinju, Korea
    • Related Report
      2010 Annual Research Report
  • [Presentation] Photo-swichable Hydrogel Formed b Cyclodextrin and Azobenzene Polymers2010

    • Author(s)
      Shingo TAMESUE, Yoshinori TAKASHIMA, Hiroyasu YAMAGUCHI, Seiji SHINKAI, Akira HARADA
    • Organizer
      5th International Symposium on Macrocyclic and Supramolecular Chemistry
    • Place of Presentation
      奈良県新公会堂
    • Related Report
      2010 Annual Research Report
  • [Presentation] Novel Polysaccharide-Based Container Transportation System Powered by Molecular Motors2010

    • Author(s)
      Youichi TSUCHIYA, Tomotaka KOMORI, Tomohiro SHIRAKI, Toshio YANAGIDA, Seiji SHINKAI
    • Organizer
      5th International Symposium on Macrocyclic and Supramolecular Chemistry
    • Place of Presentation
      奈良県新公会堂
    • Related Report
      2010 Annual Research Report
  • [Presentation] 超分子ファスナーを用いた光刺激応答性カーボンナノチューブヒドロゲルの作成2010

    • Author(s)
      為末真吾・高島義徳・山口浩靖・新海征治・原田明
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 撥油性界面の光パターニング2010

    • Author(s)
      原口修一・小川雅司・坂上恵・土屋陽一・白木智丈・後藤修・新海征治・柿本秀信・山田武・奥本健二・中谷修平
    • Organizer
      日本化学会第90回春季年会
    • Place of Presentation
      近畿大学(大阪)
    • Related Report
      2009 Annual Research Report
  • [Presentation] 多点認識から構築される分子システム群2009

    • Author(s)
      新海征治
    • Organizer
      分子情報生命科学シンポジウム
    • Place of Presentation
      理化学研究所
    • Year and Date
      2009-12-21
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] ミオシン-TPySPG/SWNT複合体を用いた生体内運動機構の解明を目指して2009

    • Author(s)
      土屋陽一, 新海征治
    • Organizer
      分子情報生命科学シンポジウム2009
    • Place of Presentation
      福岡市産学連携交流センター
    • Year and Date
      2009-05-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] 糖鎖ラッピングによるナノ材料コンテナ輸送モデルの構築2009

    • Author(s)
      土屋陽一, 小森智貴, 平野美奈子, 井出徹, 柳田敏雄, 山田淳, 新海征治
    • Organizer
      分子情報生命科学シンポジウム2009
    • Place of Presentation
      福岡市産学連携交流センター
    • Year and Date
      2009-05-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] シクロデキストリン側鎖修飾β-1, 3-グルカンを鋳型として用いた機能性高分子の超分子集合体形成と光スイッチング2009

    • Author(s)
      為末真吾, 高島義徳, 山口浩靖, 新海征治, 原田明
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 金属配位子を有するβ-1, 3-グルカンを用いたSWNT複合体の錯形成挙動2009

    • Author(s)
      土屋陽一, 原口修一, 杉川幸太, 白木智丈, 新海征治
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] らせん天然高分子をテンプレー卜としたクロロフィル分子の配列制御2009

    • Author(s)
      木下大希, 沼田宗典, 国枝道雄, 民秋均, 杉川幸太, 佐田和己, 新海征治
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] らせん天然高分子によるラッピングを利用した人エクロロソームの創製2009

    • Author(s)
      叶野徹, 沼田宗典, 民秋均, 新海征治
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] New Functional Polymer Composites Created from Helix-Forming Polysaccharides2009

    • Author(s)
      Seiji SHINKAI, Shuichi HARAGUCHI, Yoichi TSUCHIYA, Tomohiro SHIRAKI
    • Organizer
      The 4th Joint International Symposium on Macrocyclic & Supramolecular Chemistry, June, Maastricht, 2009
    • Place of Presentation
      オランダ・マーストリヒト
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] 糖センサーの開発と多糖類のナノ・バイオ応用2009

    • Author(s)
      新海征治
    • Organizer
      有機合成セミナー「次世代材料開発を担う合成技術」
    • Place of Presentation
      大阪市立工業研究所
    • Related Report
      2009 Annual Research Report
  • [Presentation] Container Transportation Model System by Using Polysaccharide2009

    • Author(s)
      Youichi TSUCHIYA, Tomotaka KOMORI, Minako HIRANO, Tomohiro SHIRAKI, Akira KAKUGO, Toru IDE, Jian-Ping GONG, Sunao YAMADA, Toshio YANAGIDA, Seiji SHINKAI
    • Organizer
      The 1st FAPS Polymer Congress
    • Place of Presentation
      名古屋国際会議場
    • Related Report
      2009 Annual Research Report
  • [Presentation] Photo-Energy Transfer Control through Charge-Transfer Complex Formation on Hybrid Nanowires Composed of Poly (Phenylene Ethynylene)/Schizophyllan Complex and Quantum Dot2009

    • Author(s)
      Tomohiro SHIRAKI, Shuichi HARAGUCHI, Youichi TSUCHIYA, Seiji SHINKAI
    • Organizer
      The 1st FAPS Polymer Congress
    • Place of Presentation
      名古屋国際会議場
    • Related Report
      2009 Annual Research Report
  • [Presentation] ss-1, 3-グルカンの包接機能の利用による構造制御されたナノ複合材料の創製2009

    • Author(s)
      白木智丈, 田丸俊一, 新海征治
    • Organizer
      新学術領域-分子ナノシステムの創発化学-「平成21年度第一回全体会議」
    • Place of Presentation
      札幌
    • Related Report
      2009 Annual Research Report
  • [Presentation] Arrangement of Functional Molecules through the Use of Semi-Artificial ss-1, 3-Glucans2009

    • Author(s)
      Kouta SUGIKAWA, Munenori NUMATA, Kenji KANEKO, Kazuki SADA, Seiji SHINKAI
    • Organizer
      The 4th Joint International Symposium on Macrocyclic & Supramolecular Chemistry, June, Maastricht, 2009
    • Place of Presentation
      オランダ・マーストリヒト
    • Related Report
      2009 Annual Research Report
  • [Presentation] 分子配列が生み出す"形"と"機能"について2008

    • Author(s)
      新海征治
    • Organizer
      茅コンファレンス「21世紀物性科学の展望」
    • Place of Presentation
      東京
    • Related Report
      2010 Final Research Report
  • [Presentation] 分子配列が生み出す"形"ど機能"について2008

    • Author(s)
      新海征治
    • Organizer
      茅コンファレンス「21世紀物性科学の展望」
    • Place of Presentation
      東京
    • Related Report
      2008 Annual Research Report
  • [Presentation] Supra-macromolecular Chemistry2008

    • Author(s)
      新海征治
    • Organizer
      Yamada Conference on Topological Molec ules
    • Place of Presentation
      兵庫
    • Related Report
      2008 Annual Research Report
  • [Presentation] 「偶然」と「失敗」を生かす新アイデアの創成2008

    • Author(s)
      新海征治
    • Organizer
      第25回有機合成化学セミナー
    • Place of Presentation
      熊本
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.nano.sojo-u.ac.jp/laboratory/newlab/index.html

    • Related Report
      2010 Final Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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