High performance organic field effect transistors using polydiactyelene solid-state polymerized films

• Project/Area Number: 20245046
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Kyushu University
• Principal Investigator: ADACHI Chihaya Kyushu University, 工学研究院, 教授 (30283245)
• Co-Investigator(Kenkyū-buntansha): YAHIRO Masayuki 九州大学, 未来化学創造センター, 助教 (40432877)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥40,430,000 (Direct Cost: ¥31,100,000、Indirect Cost: ¥9,330,000); Fiscal Year 2010: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2009: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000); Fiscal Year 2008: ¥32,370,000 (Direct Cost: ¥24,900,000、Indirect Cost: ¥7,470,000)
• Keywords: 有機FET / ポリジアセチレン / 移動度 / 固相重合 / LB膜 / 高速電子移動度 / 電子線照射 / ドーピング / 発光デバイス / Ambipolar / 高速移動度 / 真空蒸着 / レーザアニール

Research Abstract

The highest carrier mobility of polydiacetylene (PDA) thin films in field-effect transistors has been limited to less than 0.8cm^2 V-1 s-1, although the main chain conduction should show higher carrier mobility potentially. We revealed that the cause of the low carrier mobility is due to the presence of local upheaval regions generated by the volume change through the polymerization process of diacetylene monomers. In order to suppress the occurrence of the upheaval regions, we found that electron beam (EB) irradiation is effective, resulted in the highest carrier mobility of μmax=3.8cm^2V-1 s-1.

Research Products

• [Journal Article] Highly conductive interface between a rubrene single crystal and a molybdenum oxide layer and its application in transistors (2011)
  • Author(s): H.Nakanotani, H.Kakizoe, C.Adachi
  • Journal Title: Solid State Comm. 151 Pages: 93-96
• [Journal Article] Organic Electrodes Consisting of Dianthratetrathuafulvalene and Fullerene and Their Application in Organic Field Effect Transistors (2011)
  • Author(s): Takuji Kato, Chikako Origuchi, Masato Shinoda, Chihaya Adachi
  • Journal Title: Jpn.J.Appl.Phys. 50 Pages: 50202-50202
• [Journal Article] High Carrier Mobility of 3.8 cm2V-1s-1 in Polydiacetylene Thin-Films Polymerized by Electron Beam Irradiation (2011)
  • Author(s): Takuji Kato, Chikako Origuchi, Kyoji Tsutsui, Yasukiyo Ueda, Chihaya Adachi
  • Journal Title: J.Appl.Phys.Exp. 4 Pages: 91601-91601
  • NAID: 10029622204
• [Journal Article] Highly conductive interface between a rubrene single crystal and a molybdenum oxide layer and its application in transistors (2011)
  • Author(s): Hajime Nakanotani, Hayato Kakizoe, Chihaya Adachi
  • Journal Title: Solid State Comm. Volume: 151 Pages: 93-96
  • Peer Reviewed
• [Journal Article] Organic light-emitting diodes containing multilayers of organic single crystals (2010)
  • Author(s): H.Nakanotani, C.Adachi
  • Journal Title: Appl.Phys.Lett. 96 Pages: 53301-53301
• [Journal Article] Emission color tuning in ambipolar organic single crystal field-effect transistors by dye-doping (2010)
  • Author(s): H.Nakanotani, M.Saito, H.Nakamura, C.Adachi
  • Journal Title: Adv.Funct.Mat. 20 Pages: 1610-1615
• [Journal Article] Fluoro-substituted phenylene ethynylenes : acetylenic n-type organic semiconductors (2010)
  • Author(s): D.Matsuol, X.Yang, A.Hamada, K.Morimoto, T.Kato, M.Yahiro, C.Adachi, A.Orita, J.Otera
  • Journal Title: Chem.Lett. 39 Pages: 1300-1302
• [Journal Article] Fluoro-substituted Phenyleneethynylenes : Acetylenic n-Type Organic Semiconductors (2010)
  • Author(s): Daisuke Matsuo, Xin Yang, Akiko Hamada, Kyo Morimoto, Takuji Kato, Masayuki Yahiro, Chihaya Adachi, Akihiro Orita, Junzo Otera
  • Journal Title: Chem.Lett. Volume: 39 Pages: 1300-1302
  • NAID: 10027468618
  • Peer Reviewed
• [Journal Article] Emission color tuning in ambipolar organic single crystal field-effect transistors by dye-doping (2010)
  • Author(s): Hajime Nakanotani, Masatoshi Saito, Hiroaki Nakamura, Chihaya Adachi
  • Journal Title: Adv.Funct.Mat. Volume: 20 Pages: 1610-1615
  • Peer Reviewed
• [Journal Article] Control of the molecular orientation of a 2,2'-bithiophene-9,9'-dioctylfluorene copolymer by laser-annealing and subsequent enhancement of the FET characteristics (2009)
  • Author(s): K.Kubota, T.Kato, C.Adachi
  • Journal Title: Appl.Phys.Lett. 95 Pages: 73303-73303
• [Journal Article] Control of the molecular orientation of a 2, 2'-bithiophene-9, 9'-dioctylfluorene copolymer by laser-annealing and subsequent enhancement of the FET characteristics (2009)
  • Author(s): Korefumi Kubota, Takuji Kato, Chihaya Adachi
  • Journal Title: Applied Physics Letters 95 Pages: 73303-73303
  • Peer Reviewed
• [Journal Article] A high mobility ambipolar field effect transistor using a 2,6-diphenylbenzo[1,2-b:4,5-b']diselenophene/fullerene double layer (2008)
  • Author(s): S.Kinoshita, T.Sakanoue, M.Yahiro, K.Takimiya, H.Ebata, M.Ikeda, H.Kuwabara, C.Adachi
  • Journal Title: Solid State Comm. 145 Pages: 114-117
• [Journal Article] Finite difference time domain analysis of the light extraction efficiency in organic light-emitting field-effect transistors (2008)
  • Author(s): R.Gehlhaar, M.Yahiro, C.Adachi
  • Journal Title: J.Appl.Phys. 104 Pages: 33116-33116
• [Journal Article] Blue-Light-Emitting Ambipolar Field-Effect Transistors Using an Organic Single Crystal of 1,4-Bis(4-methylstyryl)benzene (2008)
  • Author(s): H.Nakanotani, R.Kabe, M.Yahiro, T.Takenobu, Y.Iwasa, C.Adachi
  • Journal Title: Appl.Phys. Express 1 Pages: 91801-91801
  • NAID: 10025082410
• [Presentation] High performance organic field effect transistor by using main chain conduction, OPERA / G-COE joint hosting International Symposium & OPERA Winter School 2011 (2011)
  • Author(s): 加藤拓司, 安松真麻, 折口千佳子, 筒井恭二, 安達千波矢
  • Organizer: G-COE 17th Special Lecture by Distinguished Foreign Researcher
• [Presentation] 高性能・高機能OFET (2011)
  • Author(s): 加藤拓司, 安松真麻, 折口千佳子, 筒井恭二, 安達千波矢
  • Organizer: 第一回最先端有機光エレクトロニクスシンポジュウム
• [Presentation] 主鎖伝導FET-膜形状制御 (2011)
  • Author(s): 森本京, 折口稚佳子, 安松真麻, 森永秀一、加藤拓司、上田裕清、松本章一、安達千波矢
  • Organizer: 第一回最先端有機光エレクトロニクスシンポジュウム
• [Presentation] 分子配向制御したポリジアセチレン薄膜の構造 (2011)
  • Author(s): 大坪拓哉、三崎雅裕、石田謙司、上田裕清、加藤拓司、鳥居昌史、筒井恭治、松本章一、安達千波矢
  • Organizer: 第一回最先端有機光エレクトロニクスシンポジュウム
• [Presentation] 摩擦転写法によるポリジアセチレン一軸配向膜の作製 (2011)
  • Author(s): 大坪拓哉、三崎雅裕、石田謙司、上田裕清、加藤拓司、鳥居昌史、筒井恭治、松本章一、安達千波矢
  • Organizer: 春季第58回応用物理学関係連合講演
• [Presentation] ジアセチレン蒸着膜の紫外線重合過程のin-situ観察 (2011)
  • Author(s): 東條雄、三崎雅裕、石田謙司、上田裕清、加藤拓司、鳥居昌史、筒井恭治、安達千波矢
  • Organizer: 春季第58回応用物理学関係連合講演
• [Presentation] 裏面重合によるポリジアセチレン薄膜を用いたOFET高性能化 (2011)
  • Author(s): 森永秀一, 加藤拓司, 加藤喜峰, 安達千波矢
  • Organizer: 第58回 応用物理学関係連合講演会
  • Place of Presentation: 神奈川工科大学
• [Presentation] 新規有機電荷移動錯体を用いたall-有機トランジスター (2010)
  • Author(s): 加藤拓司、篠田雅人、安達千波矢
  • Organizer: 第57回 応用物理学会関係連合講演会
  • Place of Presentation: 東海大学湘南キャンパス
  • Year and Date: 2010-03-19
• [Presentation] High Performance Organic Field Effect Transistor by Using Main Chain Conduction (2010)
  • Author(s): Takuji Kato, Mao Yasumatsu, Chikako Origuchi, Kyoji Tsutsui, Chihaya Adachi
  • Organizer: 2^<nd> Asian Conference on Organic Electronics
  • Place of Presentation: ソウル大学、韓国
• [Presentation] 主鎖伝導を利用したポリジアセチレンLB膜の電界効果トランジスタ (2009)
  • Author(s): 田中 里多朗
  • Organizer: 第56回応用物理学関係連合講演会
  • Place of Presentation: 筑波大学
  • Year and Date: 2009-03-31
• [Presentation] 主鎖伝導を利用したポリジアセチレンLB膜の電界効果トランジスタ
  • Author(s): 田中里多朗、折口千佳子、加藤拓司、筒井恭二、安達千波矢
  • Organizer: 第56回応用物理学関係連合講演会
• [Presentation] Laser-annealを用いた有機半導体の高移動度化への取り組み
  • Author(s): 久保田是史、加藤拓司、安達千波矢
  • Organizer: 第56回応用物理学関係連合講演会
• [Presentation] 裏面重合によるポリジアセチレン薄膜を用いたOFETの高性能化
  • Author(s): 森永秀一、加藤拓司、加藤喜峰、安達千波矢
  • Organizer: 第58回応用物理学関係連合講演会
• [Presentation] 新規有機電荷移動錯体を用いたall-有機トランジスター
  • Author(s): 加藤拓司、篠田雅人、安達千波矢
  • Organizer: 2010年春季第57回応用物理学関係連合講演会
• [Presentation] organic field effect transistor using organic electrode consisted of novel TTF derivative/C60
  • Author(s): 加藤拓司, 折口千佳子, 篠田雅人, 安達千波矢
  • Organizer: ICSM2010
• [Book] 有機電極を用いた有機薄膜トランジス (2010)
  • Author(s): 加藤拓司、篠田雅人、折口稚佳子、山本諭、安達千波矢
  • Publisher: Ricoh Technical Reports 36
• [Book] 光技術コンタクト:有機発光トランジスタ-新しい有機発光デバイスの展開- (2010)
  • Author(s): 中野谷一、安達千波矢
  • Total Pages: 5
  • Publisher: (社)オプトメカトロニクス協会
• [Book] 光技術コンタクト:有機発光トランジスタ-新しい有機発光デバイスの展開
  • Author(s): 中野谷一、安達千波矢
  • Publisher: (社)オプトメカトロニクス協会
• [Patent(Industrial Property Rights)] 有機半導体素子及び有機電極 (2011)
  • Inventor(s): Takuji Kato, Satoshi Yamamoto, Toshiya Sagisaka, Takanori Tano, Masato Shinoda, Daisuke Goto, Shinji Matsumoto, Masataka Mohri, Keiichiro Yutani, Chihaya Adachi, Masafumi Torii
  • Industrial Property Rights Holder: 株式会社リコー九州大学
  • Filing Date: 2011-03-01
  • Overseas