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High performance organic field effect transistors using polydiactyelene solid-state polymerized films

Research Project

Project/Area Number 20245046
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKyushu University

Principal Investigator

ADACHI Chihaya  Kyushu University, 工学研究院, 教授 (30283245)

Co-Investigator(Kenkyū-buntansha) YAHIRO Masayuki  九州大学, 未来化学創造センター, 助教 (40432877)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥40,430,000 (Direct Cost: ¥31,100,000、Indirect Cost: ¥9,330,000)
Fiscal Year 2010: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2009: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2008: ¥32,370,000 (Direct Cost: ¥24,900,000、Indirect Cost: ¥7,470,000)
Keywords有機FET / ポリジアセチレン / 移動度 / 固相重合 / LB膜 / 高速電子移動度 / 電子線照射 / ドーピング / 発光デバイス / Ambipolar / 高速移動度 / 真空蒸着 / レーザアニール
Research Abstract

The highest carrier mobility of polydiacetylene (PDA) thin films in field-effect transistors has been limited to less than 0.8cm^2 V-1 s-1, although the main chain conduction should show higher carrier mobility potentially. We revealed that the cause of the low carrier mobility is due to the presence of local upheaval regions generated by the volume change through the polymerization process of diacetylene monomers. In order to suppress the occurrence of the upheaval regions, we found that electron beam (EB) irradiation is effective, resulted in the highest carrier mobility of μmax=3.8cm^2V-1 s-1.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (33 results)

All 2011 2010 2009 2008 Other

All Journal Article (14 results) (of which Peer Reviewed: 4 results) Presentation (15 results) Book (3 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Highly conductive interface between a rubrene single crystal and a molybdenum oxide layer and its application in transistors2011

    • Author(s)
      H.Nakanotani, H.Kakizoe, C.Adachi
    • Journal Title

      Solid State Comm. 151

      Pages: 93-96

    • Related Report
      2010 Final Research Report
  • [Journal Article] Organic Electrodes Consisting of Dianthratetrathuafulvalene and Fullerene and Their Application in Organic Field Effect Transistors2011

    • Author(s)
      Takuji Kato, Chikako Origuchi, Masato Shinoda, Chihaya Adachi
    • Journal Title

      Jpn.J.Appl.Phys. 50

      Pages: 50202-50202

    • Related Report
      2010 Final Research Report
  • [Journal Article] High Carrier Mobility of 3.8 cm2V-1s-1 in Polydiacetylene Thin-Films Polymerized by Electron Beam Irradiation2011

    • Author(s)
      Takuji Kato, Chikako Origuchi, Kyoji Tsutsui, Yasukiyo Ueda, Chihaya Adachi
    • Journal Title

      J.Appl.Phys.Exp. 4

      Pages: 91601-91601

    • NAID

      10029622204

    • Related Report
      2010 Final Research Report
  • [Journal Article] Highly conductive interface between a rubrene single crystal and a molybdenum oxide layer and its application in transistors2011

    • Author(s)
      Hajime Nakanotani, Hayato Kakizoe, Chihaya Adachi
    • Journal Title

      Solid State Comm.

      Volume: 151 Pages: 93-96

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organic light-emitting diodes containing multilayers of organic single crystals2010

    • Author(s)
      H.Nakanotani, C.Adachi
    • Journal Title

      Appl.Phys.Lett. 96

      Pages: 53301-53301

    • Related Report
      2010 Final Research Report
  • [Journal Article] Emission color tuning in ambipolar organic single crystal field-effect transistors by dye-doping2010

    • Author(s)
      H.Nakanotani, M.Saito, H.Nakamura, C.Adachi
    • Journal Title

      Adv.Funct.Mat. 20

      Pages: 1610-1615

    • Related Report
      2010 Final Research Report
  • [Journal Article] Fluoro-substituted phenylene ethynylenes : acetylenic n-type organic semiconductors2010

    • Author(s)
      D.Matsuol, X.Yang, A.Hamada, K.Morimoto, T.Kato, M.Yahiro, C.Adachi, A.Orita, J.Otera
    • Journal Title

      Chem.Lett. 39

      Pages: 1300-1302

    • Related Report
      2010 Final Research Report
  • [Journal Article] Fluoro-substituted Phenyleneethynylenes : Acetylenic n-Type Organic Semiconductors2010

    • Author(s)
      Daisuke Matsuo, Xin Yang, Akiko Hamada, Kyo Morimoto, Takuji Kato, Masayuki Yahiro, Chihaya Adachi, Akihiro Orita, Junzo Otera
    • Journal Title

      Chem.Lett.

      Volume: 39 Pages: 1300-1302

    • NAID

      10027468618

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Emission color tuning in ambipolar organic single crystal field-effect transistors by dye-doping2010

    • Author(s)
      Hajime Nakanotani, Masatoshi Saito, Hiroaki Nakamura, Chihaya Adachi
    • Journal Title

      Adv.Funct.Mat.

      Volume: 20 Pages: 1610-1615

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of the molecular orientation of a 2,2'-bithiophene-9,9'-dioctylfluorene copolymer by laser-annealing and subsequent enhancement of the FET characteristics2009

    • Author(s)
      K.Kubota, T.Kato, C.Adachi
    • Journal Title

      Appl.Phys.Lett. 95

      Pages: 73303-73303

    • Related Report
      2010 Final Research Report
  • [Journal Article] Control of the molecular orientation of a 2, 2'-bithiophene-9, 9'-dioctylfluorene copolymer by laser-annealing and subsequent enhancement of the FET characteristics2009

    • Author(s)
      Korefumi Kubota, Takuji Kato, Chihaya Adachi
    • Journal Title

      Applied Physics Letters 95

      Pages: 73303-73303

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A high mobility ambipolar field effect transistor using a 2,6-diphenylbenzo[1,2-b:4,5-b']diselenophene/fullerene double layer2008

    • Author(s)
      S.Kinoshita, T.Sakanoue, M.Yahiro, K.Takimiya, H.Ebata, M.Ikeda, H.Kuwabara, C.Adachi
    • Journal Title

      Solid State Comm. 145

      Pages: 114-117

    • Related Report
      2010 Final Research Report
  • [Journal Article] Finite difference time domain analysis of the light extraction efficiency in organic light-emitting field-effect transistors2008

    • Author(s)
      R.Gehlhaar, M.Yahiro, C.Adachi
    • Journal Title

      J.Appl.Phys. 104

      Pages: 33116-33116

    • Related Report
      2010 Final Research Report
  • [Journal Article] Blue-Light-Emitting Ambipolar Field-Effect Transistors Using an Organic Single Crystal of 1,4-Bis(4-methylstyryl)benzene2008

    • Author(s)
      H.Nakanotani, R.Kabe, M.Yahiro, T.Takenobu, Y.Iwasa, C.Adachi
    • Journal Title

      Appl.Phys. Express 1

      Pages: 91801-91801

    • NAID

      10025082410

    • Related Report
      2010 Final Research Report
  • [Presentation] High performance organic field effect transistor by using main chain conduction, OPERA / G-COE joint hosting International Symposium & OPERA Winter School 20112011

    • Author(s)
      加藤拓司, 安松真麻, 折口千佳子, 筒井恭二, 安達千波矢
    • Organizer
      G-COE 17th Special Lecture by Distinguished Foreign Researcher
    • Related Report
      2010 Final Research Report
  • [Presentation] 高性能・高機能OFET2011

    • Author(s)
      加藤拓司, 安松真麻, 折口千佳子, 筒井恭二, 安達千波矢
    • Organizer
      第一回最先端有機光エレクトロニクスシンポジュウム
    • Related Report
      2010 Final Research Report
  • [Presentation] 主鎖伝導FET-膜形状制御2011

    • Author(s)
      森本京, 折口稚佳子, 安松真麻, 森永秀一、加藤拓司、上田裕清、松本章一、安達千波矢
    • Organizer
      第一回最先端有機光エレクトロニクスシンポジュウム
    • Related Report
      2010 Final Research Report
  • [Presentation] 分子配向制御したポリジアセチレン薄膜の構造2011

    • Author(s)
      大坪拓哉、三崎雅裕、石田謙司、上田裕清、加藤拓司、鳥居昌史、筒井恭治、松本章一、安達千波矢
    • Organizer
      第一回最先端有機光エレクトロニクスシンポジュウム
    • Related Report
      2010 Final Research Report
  • [Presentation] 摩擦転写法によるポリジアセチレン一軸配向膜の作製2011

    • Author(s)
      大坪拓哉、三崎雅裕、石田謙司、上田裕清、加藤拓司、鳥居昌史、筒井恭治、松本章一、安達千波矢
    • Organizer
      春季第58回応用物理学関係連合講演
    • Related Report
      2010 Final Research Report
  • [Presentation] ジアセチレン蒸着膜の紫外線重合過程のin-situ観察2011

    • Author(s)
      東條雄、三崎雅裕、石田謙司、上田裕清、加藤拓司、鳥居昌史、筒井恭治、安達千波矢
    • Organizer
      春季第58回応用物理学関係連合講演
    • Related Report
      2010 Final Research Report
  • [Presentation] 裏面重合によるポリジアセチレン薄膜を用いたOFET高性能化2011

    • Author(s)
      森永秀一, 加藤拓司, 加藤喜峰, 安達千波矢
    • Organizer
      第58回 応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規有機電荷移動錯体を用いたall-有機トランジスター2010

    • Author(s)
      加藤拓司、篠田雅人、安達千波矢
    • Organizer
      第57回 応用物理学会関係連合講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2010-03-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] High Performance Organic Field Effect Transistor by Using Main Chain Conduction2010

    • Author(s)
      Takuji Kato, Mao Yasumatsu, Chikako Origuchi, Kyoji Tsutsui, Chihaya Adachi
    • Organizer
      2^<nd> Asian Conference on Organic Electronics
    • Place of Presentation
      ソウル大学、韓国
    • Related Report
      2010 Annual Research Report
  • [Presentation] 主鎖伝導を利用したポリジアセチレンLB膜の電界効果トランジスタ2009

    • Author(s)
      田中 里多朗
    • Organizer
      第56回応用物理学関係連合講演会
    • Place of Presentation
      筑波大学
    • Year and Date
      2009-03-31
    • Related Report
      2008 Annual Research Report
  • [Presentation] 主鎖伝導を利用したポリジアセチレンLB膜の電界効果トランジスタ

    • Author(s)
      田中里多朗、折口千佳子、加藤拓司、筒井恭二、安達千波矢
    • Organizer
      第56回応用物理学関係連合講演会
    • Related Report
      2010 Final Research Report
  • [Presentation] Laser-annealを用いた有機半導体の高移動度化への取り組み

    • Author(s)
      久保田是史、加藤拓司、安達千波矢
    • Organizer
      第56回応用物理学関係連合講演会
    • Related Report
      2010 Final Research Report
  • [Presentation] 裏面重合によるポリジアセチレン薄膜を用いたOFETの高性能化

    • Author(s)
      森永秀一、加藤拓司、加藤喜峰、安達千波矢
    • Organizer
      第58回応用物理学関係連合講演会
    • Related Report
      2010 Final Research Report
  • [Presentation] 新規有機電荷移動錯体を用いたall-有機トランジスター

    • Author(s)
      加藤拓司、篠田雅人、安達千波矢
    • Organizer
      2010年春季第57回応用物理学関係連合講演会
    • Related Report
      2010 Final Research Report
  • [Presentation] organic field effect transistor using organic electrode consisted of novel TTF derivative/C60

    • Author(s)
      加藤拓司, 折口千佳子, 篠田雅人, 安達千波矢
    • Organizer
      ICSM2010
    • Related Report
      2010 Final Research Report
  • [Book] 有機電極を用いた有機薄膜トランジス2010

    • Author(s)
      加藤拓司、篠田雅人、折口稚佳子、山本諭、安達千波矢
    • Publisher
      Ricoh Technical Reports 36
    • Related Report
      2010 Final Research Report
  • [Book] 光技術コンタクト:有機発光トランジスタ-新しい有機発光デバイスの展開-2010

    • Author(s)
      中野谷一、安達千波矢
    • Total Pages
      5
    • Publisher
      (社)オプトメカトロニクス協会
    • Related Report
      2010 Annual Research Report
  • [Book] 光技術コンタクト:有機発光トランジスタ-新しい有機発光デバイスの展開

    • Author(s)
      中野谷一、安達千波矢
    • Publisher
      (社)オプトメカトロニクス協会
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 有機半導体素子及び有機電極2011

    • Inventor(s)
      Takuji Kato, Satoshi Yamamoto, Toshiya Sagisaka, Takanori Tano, Masato Shinoda, Daisuke Goto, Shinji Matsumoto, Masataka Mohri, Keiichiro Yutani, Chihaya Adachi, Masafumi Torii
    • Industrial Property Rights Holder
      株式会社リコー九州大学
    • Filing Date
      2011-03-01
    • Related Report
      2010 Annual Research Report
    • Overseas

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Published: 2008-04-01   Modified: 2016-04-21  

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