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Low temperature fabrication of Si02/SiC structure by use of surface nanopores formed by nitric acid oxidation method

Research Project

Project/Area Number 20246005
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionOsaka University

Principal Investigator

KOBAYASHI Hikaru  Osaka University, 産業科学研究所, 教授 (90195800)

Co-Investigator(Kenkyū-buntansha) MATSUMOTO Taketoshi  大阪大学, 産業科学研究所, 助教 (20390643)
YAMAGUCHI Shunro  大阪大学, 産業科学研究所, 助教 (40167698)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥50,050,000 (Direct Cost: ¥38,500,000、Indirect Cost: ¥11,550,000)
Fiscal Year 2010: ¥14,430,000 (Direct Cost: ¥11,100,000、Indirect Cost: ¥3,330,000)
Fiscal Year 2009: ¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
Fiscal Year 2008: ¥17,810,000 (Direct Cost: ¥13,700,000、Indirect Cost: ¥4,110,000)
KeywordsSiC / SiO2 / 低温酸化 / MOS / 硝酸酸化 / リーク電流 / 水素処理 / 界面準位 / MOS構造 / SiO_2 / 酸素原子 / 硝酸 / SiOC / 界面反応 / ナノ細孔 / 欠陥制御 / 界面制御 / 二酸化シリコン膜 / 電流-電圧特性 / 電気容量-電圧特性 / 電気特性
Research Abstract

We have developed a method of low temperature formation by use of nitric acid oxidation method. 3C-SiC surfaces can be atomically flattened by hydrogen treatment at 400℃, and SiO_2/SiC structure with good electrical characteristics can be formed by two-step nitric acid oxidation method using 40 and 68wt% HNO_3 solutions below 120℃. The leakage current density flowing through SiO_2 is high with no hydrogen treatment, but it can be decreased by approximately six orders of magnitude using the hydrogen treatment. We have also fabricated SiO_2/4H-SiC structure by use of nitric acid vapor oxidation method at 600℃. The oxidation proceeds only from step edges, and the initial oxidation rate for C-face is 2.8 times higher than that for Si-face. For the Si-face, SiOC species is formed at the interface, while it is not present for the C-face.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (52 results)

All 2011 2010 2009 2008 Other

All Journal Article (28 results) (of which Peer Reviewed: 28 results) Presentation (20 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Sub-micronmeter ultralow power TFT with 1.8nm NAOS SiO_2/20nm CVD SiON gate stack structure2011

    • Author(s)
      Y. Kubota, T. Matsumoto, S. Imai, M. Yamada, H. Tsuji, K. Taniguchi, S. Terakawa, H. Kobayashi
    • Journal Title

      IEEE Trans. 58(4)

      Pages: 1134-1140

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultra-low power TFT with gate oxide fabricated by nitric acid oxidation method2010

    • Author(s)
      T. Matsumoto, Y. Kubota, M. Yamada, H. Tsuji, T. Shimatani, Y. Hirayama, S. Terakawa, S. Imai, H. Kobayashi
    • Journal Title

      IEEE Electron Device Lett. 31(8)

      Pages: 821-823

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] SiO_2/Si structure having low leakage current fabricated by nitric acid oxidation method with Si source2010

    • Author(s)
      T. Yanase, M. Matsumoto, H. Kobayashi
    • Journal Title

      Electrochem.Solid-State Lett. 13(7)

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low temperature fabrication of 5~10nm SiO_2/Si structure using advanced nitric acid oxidation of silicon (NAOS) method2010

    • Author(s)
      Y. Fukaya, T. Yanase, Y. Kubota, S. Imai, T. Matsumoto, H. Kobayashi
    • Journal Title

      Appl.Surf.Sci. 256

      Pages: 5610-5613

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nitric acid oxidation of Si (NAOS) method for low temperature fabrication of SiO_2/Si and SiO_2/SiC structures2010

    • Author(s)
      H. Kobayashi, K. Imamura, W.-B. Kim, S.-S. Im, Asuha
    • Journal Title

      Appl.Surf.Sci. 256

      Pages: 5744-5756

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrathin SiO_2 layer with a low leakage current density formed with~100 % nitric acid vapor2010

    • Author(s)
      W.-B. Kim, T. Matsumoto, H. Kobayashi
    • Journal Title

      Nanotechnology 21

      Pages: 1152021-1152028

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nitric acid oxidation of SI method at 120℃ : HNO_3 concentration dependence2010

    • Author(s)
      K. Imamura, M. Takahashi, Asuha, Y. Hirayama, S. Imai, H. Kobayashi
    • Journal Title

      J.Appl.Phys. 107(5)

      Pages: 545031-545035

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nitric acid oxidation of Si (NAOS) method for low temperature fabrication of SiO_2/Si and SiO_2/SiC structures2010

    • Author(s)
      H.Kobayashi, K.Imamura, W.-B.Kim, S.-S.Im, Asuha
    • Journal Title

      Applied Surface Science

      Volume: 256 Pages: 5744-5756

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SiO_2/Si structure having low leakage current fabricated by nitric acid oxidation method with Si source2010

    • Author(s)
      T.Yanase, M.Matsumoto, H.Kobayashi
    • Journal Title

      Electrochemistry and Solid-State Letters

      Volume: 13

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low temperature fabrication of 5~10 nm SiO_2/Si structure using advanced nitric acid oxidation of silicon (NAOS) method2010

    • Author(s)
      Y.Fukaya, T.Yanase, Y.Kubota, S.Imai, T.Matsumoto, H.Kobayashi
    • Journal Title

      Applied Surface Science

      Volume: 256 Pages: 15610-5613

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrathin SiO_2 layer with a low leakage current density formed with~100% nitric acid vapor2010

    • Author(s)
      W.-B.Kim, T.Matsumoto, H.Kobayashi
    • Journal Title

      Nanotechnology

      Volume: 21

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrathin SiO_2 layer with a low leakage current density formed with~100% nitric acid vapor2010

    • Author(s)
      W.-B.Kim, T.Matsumoto, H.Kobayashi
    • Journal Title

      Nanotechnology 21

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nitric acid oxidation of Si method at 120℃ : HNO_3 concentration dependence2010

    • Author(s)
      K.Imamura, M.Takahashi, Asuha, Y.Hirayama, S.Imai, H.Kobayashi
    • Journal Title

      Journal of Applied Physics 107

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrathin SiO_2 layer with an extremely low leakage current density formed in high concentration nitric acid2009

    • Author(s)
      W.-B. Kim, T. Matsumoto, H. Kobayashi
    • Journal Title

      J.Appl.Phys. 105

      Pages: 1037091-1037096

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Band alignment of SiO_2/Si structure formed with nitric acid vapor below 500℃2009

    • Author(s)
      K. Imamura, M. Takahashi, S. Imai, H. Kobayashi
    • Journal Title

      Surf.Sci. 603(7)

      Pages: 968-972

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low temperature formation of SiO_2 thin films by nitric acid oxidation of Si (NAOS) and application to thin film transistor (TFT)2009

    • Author(s)
      T. Matsumoto, Asuha, W.-B. Kim, M. Yamada, S Imai, S. Terakawa, H. Kobayashi
    • Journal Title

      Microelectron.Eng. 86

      Pages: 1939-1941

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ultrathin SiO_2 layer with an extremely low leakage current density formed in high concentration nitric acid2009

    • Author(s)
      W-B.Kim, T.Matsumoto, H.Kobayashi
    • Journal Title

      Journal of Applied Physcis 105

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Band alignment of SiO_2/Si structure formed with nitric acid vapor below 500℃2009

    • Author(s)
      K.Imamura, M.Takahashi, S.Imai, H.Kobahashi
    • Journal Title

      Surface Science 603

      Pages: 968-972

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] On topographic properties of semiconductor surfaces and thin film systems2009

    • Author(s)
      S.Jurecka, H.Kobayashi, M.Takahashi, R.Brunner, M.Madani, E.Pincik
    • Journal Title

      Material Science Forum 609

      Pages: 275-279

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrathin SiO_2 layer on atomically flat Si(111) surfaces with excellent electrical characteristics formed by nitric acid oxidation method2008

    • Author(s)
      W.-B. Kim, Asuha, T. Matsumoto, H. Kobayashi
    • Journal Title

      Appl.Phys.Lett. 93

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nitric acid oxidation of 3C-SiC to fabricate MOS diodes with a low leakage current density2008

    • Author(s)
      M. Takahashi, S.-S. Im, M. Madani, H. Kobayashi
    • Journal Title

      J. Electrochem.Soc. 155(1)

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nitric Acid Oxidation Method to Form SiO_2/3C-SiC Structure at 120℃2008

    • Author(s)
      S.-S. Im, S. Terakawa, H. Iwasa, H. Kobayashi
    • Journal Title

      Appl.Surf.Sci. 254

      Pages: 3667-3671

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] SiC cleaning method by use of dilute HCN aqueous solutions2008

    • Author(s)
      M. Madani, Y.-L. Liu, M. Takahashi, H. Iwasa, H. Kobayashi
    • Journal Title

      J.Electrochem.Soc. 155(11)

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nitric acid method for fabrication of gate oxides in TFT2008

    • Author(s)
      S. Mizushima, S. Imai, Asuha, M. Tanaka, H. Kobayashi
    • Journal Title

      Applied Surface Science 254

      Pages: 3685-3689

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nitric acid oxidation of 3C-SiC to fabricate MOS diodes with a low leakage current density2008

    • Author(s)
      M. Takahashi, S. -S. Im, M. Madani, H. Kobayashi
    • Journal Title

      Journal of Electrochemical Society 155

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nitric acid oxidation method to form SiO_2/3C-SiC structure at 120℃2008

    • Author(s)
      S. S. Im, S. Terakawa, H. Iwasa, H. Kobayashi
    • Journal Title

      Applied Surface Science 254

      Pages: 3667-3671

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Properties of thick SiO_2/Si structure formed at 120℃ by use of two- step nitric acid oxidation method2008

    • Author(s)
      S. Imai, S. Mizushima, Asuha, W. -B. Kim, H. Kobayashi
    • Journal Title

      Applied Surface Science 254

      Pages: 8054-8058

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SiC cleaning method by use of dilute HCN aqueous solutions2008

    • Author(s)
      M. Madani, Y. -L. Liu, M. Takahashi, H. Iwasa, H. Kobayashi
    • Journal Title

      Journal of Electrochemical Society 155

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Ultra-low power TFTs with 10 nm stacked gate insulator fabricated by the nitric acid oxidation of Si (NAOS) method2010

    • Author(s)
      T.Matsumoto, M.Yamada, H.Tsuji, K.Taniguchi, Y.Kubota, S.Imai, S.Terakawa, H.Kobayashi
    • Organizer
      2010 International Electron Devices Meeting
    • Place of Presentation
      San Francisco, US
    • Year and Date
      2010-12-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] Characterization of ultra-low power thin film transistors (TFTs) with SiO_2 layer formed by the nitric acid oxidation of Si (NAOS) method2010

    • Author(s)
      T.Matsumoto, M.Yamada, H.Tsuji, K.Taniguchi, Y.Kubota, S.Imai, S.Terakawa, H.Kobayashi
    • Organizer
      7^<th> Solid State Surfaces and Interfaces
    • Place of Presentation
      Smolenice, Slovakia
    • Year and Date
      2010-11-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] Improvement of Si solar cell performance by new chemical methods : surface passivation, defect elimination, metal removal, and surface structure transfer2010

    • Author(s)
      小林光
    • Organizer
      7^<th> Solid State Surfaces and Interfaces
    • Place of Presentation
      Smolenice(スロバキア)招待講演
    • Year and Date
      2010-11-22
    • Related Report
      2010 Final Research Report
  • [Presentation] Characterization of ultra-low power thin film transistors (TFTs) with SiO_2 layer formed by the nitric acid oxidation of Si (NAOS) method2010

    • Author(s)
      松本健俊, 小林光
    • Organizer
      7^<th> Solid State Surfaces and Interfaces
    • Place of Presentation
      Smolenice(スロバキア)招待講演
    • Year and Date
      2010-11-22
    • Related Report
      2010 Final Research Report
  • [Presentation] Improvement of Si solar cell performance by new chemical methods : surface passivation, defect elimination, metal removal, and surface structure transfer2010

    • Author(s)
      H.Kobayashi, W.-B.Kim
    • Organizer
      7^<th> Solid State Surfaces and Interfaces
    • Place of Presentation
      Smolenice, Slovakia
    • Year and Date
      2010-11-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] 気相硝酸酸化(NAVOS)法によるSiO_2/4H-SiC構造の低温創製2010

    • Author(s)
      趙惠淑、松本健俊、岩佐仁雄、小林光
    • Organizer
      SiC及び関連ワイドバンドギャップ半導体研究会第19回講演会
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2010-11-14
    • Related Report
      2010 Final Research Report
  • [Presentation] 気相硝酸酸化法により低温形成したSiO_2/Si構造の低温創製2010

    • Author(s)
      趙惠淑、松本健俊、岩佐仁雄、小林光
    • Organizer
      第30回表面科学学術講演会
    • Place of Presentation
      大阪
    • Year and Date
      2010-11-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] 気相硝酸酸化(NAVOS)法によるSiO_2/4H-SiC構造の低温創製2010

    • Author(s)
      趙惠淑、松本健俊、岩佐仁雄、小林光
    • Organizer
      SiC及び関連ワイドバンドギャップ半導体研究会 第19回講演会
    • Place of Presentation
      茨城
    • Year and Date
      2010-10-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] 気相硝酸酸化法によるSiO_2/SiC構造の低温創製2010

    • Author(s)
      趙惠淑、松本健俊、岩佐仁雄、小林光
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学(大阪府)
    • Year and Date
      2010-09-23
    • Related Report
      2010 Final Research Report
  • [Presentation] 気相硝酸酸化法を用いたSiO_2/SiC構造の低温創製2010

    • Author(s)
      趙惠淑、松本健俊、岩佐仁雄、小林光
    • Organizer
      物理学会2010年秋季大会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] 気相硝酸酸化法により低温形成したSiO_2/Si構造の物性と電気特性2010

    • Author(s)
      田中峻介、趙惠淑、松本健俊、岩佐仁雄、小林光
    • Organizer
      物理学会2010年秋季大会
    • Place of Presentation
      大阪
    • Year and Date
      2010-09-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] Nitric acid oxidation of Si (NAOS) method for the formation of gate oxides in TFT2009

    • Author(s)
      小林光
    • Organizer
      Progress in Surface, Interface and Thin Film Science 2009
    • Place of Presentation
      フェレンツェ(イタリア)
    • Year and Date
      2009-11-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Defect Passivation Etch-less Cleaning for Semiconductor Devices : Zero Emission Process2009

    • Author(s)
      小林光
    • Organizer
      International Symposium on Advanced Ceramics and Technology for Sustainable Energy Application
    • Place of Presentation
      台北(台湾)
    • Year and Date
      2009-11-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] Nitric acid oxidation of Si method for fabrication of Si/SiO_2 structure at 120℃ and its application to thin film transistors2009

    • Author(s)
      小林光
    • Organizer
      VI International Workshop on Semiconductor Surface Passivation
    • Place of Presentation
      ザコパネ(ポーランド)
    • Year and Date
      2009-09-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] Defect passivation etch-less cleaning method for improvement of Sisolar cell characteristics2009

    • Author(s)
      小林光
    • Organizer
      The 6^<th> International Conference on High-Performance Ceramics
    • Place of Presentation
      ハルビン(中国)
    • Year and Date
      2009-08-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] SiC cleaning method by use of dilute HCN aqueous solutions2008

    • Author(s)
      M. Madani, Y. -L. Liu, M. Takahashi, H. Iwasa, H. Kobayashi
    • Organizer
      6^<th> Solid State Surfaces and Interfaces
    • Place of Presentation
      Smolenice(スロバキア国)
    • Year and Date
      2008-11-26
    • Related Report
      2008 Annual Research Report
  • [Presentation] SiC cleaning method by use of dilute HCN aqueous solutions2008

    • Author(s)
      M. Madani, Y. Y. L. Liu, M. Takahashi, H. Iwasan, H. Kobayashi
    • Organizer
      International Symposium on Surface Science and Nanotechnology
    • Place of Presentation
      東京
    • Year and Date
      2008-11-12
    • Related Report
      2008 Annual Research Report
  • [Presentation] Low temperature nitric acid oxidation of Si (NAOS) for fabrication of gate oxides in LSI and TFT2008

    • Author(s)
      小林光
    • Organizer
      The 1st International Symposium on Hybrid Materials and Processing
    • Place of Presentation
      Busan, Korea
    • Year and Date
      2008-10-27
    • Related Report
      2010 Final Research Report
  • [Presentation] HCN水溶液による4H-SiC表面上の吸着金属の完全除去2008

    • Author(s)
      高橋昌男, マダニ・モハマド, 劉〓伶, 岩佐仁雄, 小林光
    • Organizer
      日本物理学会
    • Place of Presentation
      岩手
    • Year and Date
      2008-09-23
    • Related Report
      2008 Annual Research Report
  • [Presentation] Nitric acid oxidation of Si at 120℃ to fabricate MOS Structure with excellent electrical characteristics2008

    • Author(s)
      小林光
    • Organizer
      1st International Conference on Thin Films and Porous Materials
    • Place of Presentation
      Zeralda, Algiers, Algeria
    • Year and Date
      2008-05-19
    • Related Report
      2010 Final Research Report
  • [Book] SiCパワーデバイス最新技術第11章SiCパワーデバイス用酸化膜の形成方法2010

    • Author(s)
      松本健俊、小林光
    • Publisher
      サイエンス&テクノロジー株式会社
    • Related Report
      2010 Final Research Report
  • [Book] SiCパワーデバイス最新技術 第11章SiCパワーデバイス用酸化膜の形成方法2010

    • Author(s)
      松本健俊、小林光
    • Total Pages
      21
    • Publisher
      サイエンス&テクノロジー株式会社
    • Related Report
      2010 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://www.sanken.osaka-u.ac.jp/labs/fcm/index.html

    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 半導体装置及びその製造方法2010

    • Inventor(s)
      小林光
    • Industrial Property Rights Holder
      小林光
    • Industrial Property Number
      2010-196672
    • Filing Date
      2010-09-02
    • Related Report
      2010 Annual Research Report 2010 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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