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Thermal engineering studies of double-hydrate formation : attempts toward establishing new energy-utilization technologies

Research Project

Project/Area Number 20246040
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Thermal engineering
Research InstitutionKeio University

Principal Investigator

MORI Yasuhiko  Keio University, 理工学部, 教授 (90051888)

Co-Investigator(Kenkyū-buntansha) YASUOKA Kenji  慶應義塾大学, 理工学部, 教授 (40306874)
OHMURA Ryo  慶應義塾大学, 理工学部, 准教授 (70356666)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥40,820,000 (Direct Cost: ¥31,400,000、Indirect Cost: ¥9,420,000)
Fiscal Year 2010: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2009: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
Fiscal Year 2008: ¥23,140,000 (Direct Cost: ¥17,800,000、Indirect Cost: ¥5,340,000)
Keywordsクラスレート水和物 / ガスハイドレート / ダブルハイドレート / 天然ガス貯蔵 / エネルギー貯蔵 / エネルギー利用 / エネルギー輸送・貯蔵 / 結晶成長 / 熱工学 / 分子動力学シミュレーション / 熱力学シミュレーション
Research Abstract

Experimental and theoretical studies about clathrate-hydrate formation have been performed to, expecting to contribute to establishing new energy-utilization technologies including the natural-gas storage/transport in the form of hydrates and the heat-pump technology utilizing a hydrate-forming substance as the working medium. Special attention has been paid for the utility of double hydrates in each of which cages of two (or three) different types are primarily occupied by guest molecules of different species. The issues of the studies performed under this contract cover a wide range of the spatial scale, extending from the microscopic kinetics of crystal growth to the heat and mass transfer in macroscopic multiphase systems.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report

Research Products

(42 results)

All 2011 2010 2009 2008 Other

All Journal Article (23 results) (of which Peer Reviewed: 23 results) Presentation (19 results)

  • [Journal Article] Thermodynamic properties of methane/water interface predicted by molecular dynamics simulations2011

    • Author(s)
      Ryuji Sakamaki, Amadeu K.Sum, Tetsu Narumi, Ryo Ohmura, Kenji Yasuoka
    • Journal Title

      Journal of Chemical Physics Vol.134

      Pages: 144702-144702

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Clathrate hydrate formation using liquid jets impinging on each other : an observational study using paired water jets or water and methylcyclohexane jets2011

    • Author(s)
      Koji Yamamura, Jun-ichi Fukuzaki, Yasuhiko H.Mori
    • Journal Title

      Chemical Engineering Science Vol.66, No.9

      Pages: 1844-1858

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Clathrate hydrate formation using liquid jets impinging on each other : an observational study using paired water jets or water and methylcyclohexane jets2011

    • Author(s)
      Koji Yamamura
    • Journal Title

      Chemical Engineering Science

      Volume: 66 Pages: 1844-1858

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal growth of clathrate hydrate in gas/liquid/liquid system : Variations in crystal growth behavior2011

    • Author(s)
      Yosuke Ishida
    • Journal Title

      Chemistry-A European Journal

      Volume: (掲載確定)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic properties of methane/water interface predicted by molecular dynamics simulations2011

    • Author(s)
      Ryuji Sakamaki
    • Journal Title

      The Journal of Chemical Physics

      Volume: 134

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Clathratehydrate formation from a hydrocarbon gas mixture : evolution of gas-phase composition in a hydrate-forming reactor2010

    • Author(s)
      Wataru Kondo, Hiroyuki Ogawa, Ryo Ohmura, Yasuhiko H.Mori
    • Journal Title

      Energy & Fuels Vol.24, No.12, No.12

      Pages: 6375-6383

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Impingement of liquid jets at atmospheric and elevated pressures : an observational study using paired water jets or water and methylcyclohexane jets2010

    • Author(s)
      Naohiro Yasuda, Koji Yamamura, Yasuhiko H.Mori
    • Journal Title

      Proceedings of the Royal Society A Vol.466, No.2124

      Pages: 3501-3526

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Clathrate hydrate crystal growth at the seawater/hydrophobic-guest-liquid Interface2010

    • Author(s)
      Riki Sakemoto, Hiroki Sakamoto, Kuniaki Shiraiwa, Ryo Ohmura, Tsutomu Uchida
    • Journal Title

      Crystal Growth & Design Vol.10, No.3

      Pages: 1296-1300

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Impingement of liquid jets at atmospheric and elevated pressures : an observational study using paired water jets or water and methylcyclohexane jets2010

    • Author(s)
      Naohiro Yasuda
    • Journal Title

      Proceedings of the Royal Society A

      Volume: 466 Pages: 3501-3526

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Clathrate-hydrate formation from a hydrocarbon gas mixture : evolution of gas-phase composition in a hydrate-forming reactor2010

    • Author(s)
      Wataru Kondo
    • Journal Title

      Energy & Fuels

      Volume: 24 Pages: 6375-6383

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Clathrate Hydrate Crystal Growth at the Seawater/Hydrophobic-Guest-Liquid Interface2010

    • Author(s)
      Riki Sakemoto
    • Journal Title

      Crystal Growth & Design 10

      Pages: 1296-1300

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase Equilibrium for Structure H Hydrate Formed with Methane plus Cycloheptane, Cycloheptanone, Oxacycloheptane2010

    • Author(s)
      Takahiro Kozaki
    • Journal Title

      Journal of Chemical & Engineering Data DOI : 10.1021/je9010745(掲載確定)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Clathrate-hydrate formation by water spraying onto a porous metal plate exuding a hydrophobic liquid coolant2009

    • Author(s)
      Shinya Fujita, Kuniyoshi Watanabe, Yasuhiko H.Mori
    • Journal Title

      AIChE Journal Vol.55, No.4

      Pages: 1056-1064

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Forming a structure-H hydrate using water and methylcyclohexane jets impinging on each other in a methane atmosphere2009

    • Author(s)
      Murakami Tetsuya, Hisashi Kuritsuka, Hideyuki Fujii, Yasuhiko H.Mori
    • Journal Title

      Energy & Fuels Vol.23, No.3

      Pages: 1619-1625

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic simulations of isobaric hydrate-forming operations for natural gas storage2009

    • Author(s)
      Hiroyuki Ogawa, Naotaka Imura, Tatsuya Miyoshi, Ryo Ohmura, Yasuhiko H.Mori
    • Journal Title

      Energy & Fuels Vol.23, No.2

      Pages: 849-856

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of the clathrate Hydrate Formed with Methane and Propan-1-ol2009

    • Author(s)
      Keita Yasuda
    • Journal Title

      Industrial & Engineering Chemistry Research 48

      Pages: 9335-9337

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ethanol-Methane Clathrate Hydrate Formation in the System CH_4-C_2H_5OH-H_2O : Confirmation of Structure II Hydrate Formation2009

    • Author(s)
      Keita Yasuda
    • Journal Title

      Journal of Physical Chemistry C 113

      Pages: 12598-12601

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] グラフィックカードを用いた水表面張力の高速分子動力学シミュレーション2009

    • Author(s)
      坂牧隆司
    • Journal Title

      情報処理学会論文誌コンピューティングシステム 2

      Pages: 89-97

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Statistical-Thermodynamics Modeling of Clathrate Hydrate Forming Systems Suitable as Working Media of a Hydrate-Based Refrigeration System2009

    • Author(s)
      Fumihito Takeuchi
    • Journal Title

      International Journal of Thermophysics 30

      Pages: 1838-1852

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermodynamic simulations of isobaric hydrate-forming operations for natural gas storage2009

    • Author(s)
      Hiroyuki Ogawa
    • Journal Title

      Energy & Fuels 23

      Pages: 849-856

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Forming a structure-H hydrate using water and methylcyclohexane jets impinging on each other in a methane atmosphere2009

    • Author(s)
      Tetsuya Murakami
    • Journal Title

      Energy & Fuels 23

      Pages: 1619-1625

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Clathrate-hydrate formation by water spraying onto a porous metal plate exuding a hydrophobic liquid coolant2009

    • Author(s)
      Shinya Fujita
    • Journal Title

      AIChE Journal 55

      Pages: 1056-1064

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal growth of clathrate hydrate in gas/liquid/liquid system : Variations in crystal growth behavior

    • Author(s)
      Yosuke Ishida, Riki Sakemoto, Ryo Ohmura
    • Journal Title

      Chemistry-A European Journal

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Presentation] Crystal growth of structure II hydrate on a water droplet in contact with hydrophobic gas and liquid guest substances2010

    • Author(s)
      Yosuke Ishida
    • Organizer
      11th International Conference on Physics and Chemistry of Ice
    • Place of Presentation
      札幌市
    • Year and Date
      2010-09-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] Understanding thermodynamics of clathrate hydrates toward energy/environment technology innovations2010

    • Author(s)
      Ryo Ohmura
    • Organizer
      IUPAC International Conference on Chemical Thermodynamics (ICCT 2010)
    • Place of Presentation
      つくば市
    • Year and Date
      2010-08-03
    • Related Report
      2010 Final Research Report
  • [Presentation] Understanding thermodynamics of clathrate hydrates toward energy/environment technology innovations2010

    • Author(s)
      Ryo Ohmura
    • Organizer
      IUPAC International Conference on Chemical Thermodynamics(ICCT 2010)
    • Place of Presentation
      つくば市
    • Year and Date
      2010-08-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] Clathrate hydrates-key materials for symbiotic energy technologies2010

    • Author(s)
      Yasuhiko H.Mori
    • Organizer
      Workshop on Symbiotic Technologies, Renewable Energy 2010
    • Place of Presentation
      横浜市
    • Year and Date
      2010-07-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 疎水性冷却液が滲出する多孔質面上への水噴霧による構造H水和物生成2010

    • Author(s)
      佐田圭史
    • Organizer
      第47回日本伝熱シンポジウム
    • Place of Presentation
      札幌市
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 炭化水素系混合ガスからのクラスレート水和物生成(生成容器内気相の組成変化挙動)2010

    • Author(s)
      近藤航
    • Organizer
      第47回日本伝熱シンポジウム
    • Place of Presentation
      札幌市
    • Year and Date
      2010-05-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] フルオロカーボンハイドレートの熱力学的安定性2009

    • Author(s)
      竹内史人
    • Organizer
      第23回分子シミュレーション討論会
    • Place of Presentation
      名古屋市
    • Year and Date
      2009-12-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] CUDAを用いた分子間相互作用計算高速化ライブラリの評価および気液界面物性の計算2009

    • Author(s)
      坂牧隆司
    • Organizer
      第23回分子シミュレーション討論会
    • Place of Presentation
      名古屋市
    • Year and Date
      2009-11-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] エタノール-メタン-水系におけるエタノール-メタンハイドレートの生成2009

    • Author(s)
      安田啓太
    • Organizer
      北海道大学低温科学研究所共同利用研究集会「H_2Oを科学する」
    • Place of Presentation
      札幌市
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Calculation of Thermodynamics Properties on Methane/Water Interface Using Fast Molecular Dynamics Simulation2009

    • Author(s)
      坂牧隆司
    • Organizer
      The 3rd Mini-Symposium on Liquids
    • Place of Presentation
      岡山市
    • Year and Date
      2009-06-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] クラスレート水和物生成に及ぼす界面活性剤の効果(メタン+エタン+プロパン混合ガスからの水和物生成について)2009

    • Author(s)
      安東直毅
    • Organizer
      第46回日本伝熱シンポジウム
    • Place of Presentation
      京都市
    • Year and Date
      2009-06-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] 疎水性冷却液が滲出する多孔質面上への水噴霧によるメタン水和物生成2009

    • Author(s)
      花田純一郎
    • Organizer
      第46回日本伝熱シンポジウム
    • Place of Presentation
      京都市
    • Year and Date
      2009-06-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] 水/メタン気液界面の分子動力学シミュレーション2009

    • Author(s)
      坂牧隆司
    • Organizer
      第46回日本伝熱シンポジウム
    • Place of Presentation
      京都市
    • Year and Date
      2009-06-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] シクロペンタン-海水界面におけるクラスレート水和物の結晶成長2008

    • Author(s)
      酒本 力
    • Organizer
      北海道大学低温科学研究所共同利用研究集会「H_2Oを科学する」
    • Place of Presentation
      札幌市
    • Year and Date
      2008-09-12
    • Related Report
      2008 Annual Research Report
  • [Presentation] Molecular dynamics simulation of adsorption on water/methane interface2008

    • Author(s)
      Ryuji Sakamaki
    • Organizer
      15th International Conference on the Properties of Water and Steam
    • Place of Presentation
      Berlin, Germany.
    • Year and Date
      2008-09-08
    • Related Report
      2010 Final Research Report
  • [Presentation] Molecular dynamics simulation of adsorption on water/methane interface2008

    • Author(s)
      Ryuji Sakamaki
    • Organizer
      15th International Conference on the Properties of Water and Steam
    • Place of Presentation
      Berlin, Germany
    • Year and Date
      2008-09-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] Thermodynamic simulations of isobaric hydrate-forming operations for natural gas storage2008

    • Author(s)
      Hiroyuki Ogawa
    • Organizer
      6th International Conference on Gas Hydrates
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2008-07-08
    • Related Report
      2008 Annual Research Report
  • [Presentation] Forming a structure-H hydrate using water and methylcyclohexane jets impinging on each other in a methane atmosphere2008

    • Author(s)
      Hideyuki Fujii
    • Organizer
      6th International Conference on Gas Hydrates
    • Place of Presentation
      Vancouver, Canada
    • Year and Date
      2008-07-07
    • Related Report
      2008 Annual Research Report
  • [Presentation] 炭化水素系混合ガスと大分子ゲスト物質からのクラスレート水和物生成(気相組成測定に基づく水和物生成挙動の検討(続報) )2008

    • Author(s)
      小川裕之
    • Organizer
      第45回日本伝熱シンポジウム
    • Place of Presentation
      つくば市
    • Year and Date
      2008-05-21
    • Related Report
      2008 Annual Research Report

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Published: 2008-03-31   Modified: 2016-04-21  

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