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Creation of octahedral metal oxide molecular sieves and their new catalytic functions

Research Project

Project/Area Number 20246116
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionHokkaido University

Principal Investigator

UEDA WATARU  Hokkaido University, 触媒化学研究センター, 教授 (20143654)

Co-Investigator(Kenkyū-buntansha) TAKEGUCHI Tatsuya  北海道大学, 触媒化学研究, ンター・准教授 (30227011)
SADAKANE Masahiro  広島大学, 工学研究科, 准教授 (10342792)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥43,290,000 (Direct Cost: ¥33,300,000、Indirect Cost: ¥9,990,000)
Fiscal Year 2010: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Fiscal Year 2009: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2008: ¥23,660,000 (Direct Cost: ¥18,200,000、Indirect Cost: ¥5,460,000)
Keywords金属酸化物 / 酸素八面体配位 / モレキュラーシーブ / 小分子吸着 / 結晶構造 / 無機材料合成 / 酸化一還元特性 / 触媒反応 / 酸化-還元特性
Research Abstract

Metal oxides based on tetrahedra condensation have provided a variety of porous crystalline materials. The present researches focused on new octahedral metal oxide synthesis with micropores, their materials chemistry, and catalytic functions. Based on the successful synthesis of microporous crystalline Mo-V-O materials using unit-synthesis method, the method was applied to the synthesis of complex oxides with group 5(V, Nb, Ta) and 6(Mo,W) elements. Microporous complex oxides with a similar but ill-ordered structure to that of Mo-V-O were synthesized and showed solid-acid property, particularly to the system with water, and photocatalytic property as well. More research on the Mo-V-O materials in terms of micropore function revealed that the size of the micropore decreased by material reduction due to the enlargement of metal-oxygen bond and catalytic oxidation activity changed with a maximum, which implies that a micropore with a size to reactant alkane can effectively promotes the reaction.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (57 results)

All 2011 2010 2009 2008 Other

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (33 results) Book (7 results) Remarks (4 results)

  • [Journal Article] Atomic-Level Imaging of Mo-V-O Complex Oxide Phase Intergrowth, Grain Boundaries, and Defects using HAADF-STEM2010

    • Author(s)
      W.Pyrz, D.Blom, M.Sadakane, K.Kodato, W.Ueda, T.Vogt, D.Buttrey
    • Journal Title

      Proc.Natl.Acad.Sci.USA 107

      Pages: 6152-6157

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Atomic-Scale Investigation of Two-Component MoVO Complex Oxide Catalysts Using Aberration-Corrected High-Angle Annular Dark-Field Imaging2010

    • Author(s)
      W.D.Pyrz, D.A.Blom, M.Sadakane, K.Kodato, W.Ueda, T.Vogt, D.Buttrey
    • Journal Title

      Chem.Mater. 22(6)

      Pages: 2033-2040

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Atomic-Lebel Imaging of Mo-V-O Complex Oxide Phase Intergrowth, Grain Boundaries, and Defects using HAADF-STEM2010

    • Author(s)
      Pyrz, D.Blom
    • Journal Title

      Proc.Natl.Acad.Sci.USA

      Volume: 107巻 Pages: 6152-6157

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic-Scale Investigation of Two-Component MoVO Complex Oxide Catalysts Using Aberration-Corrected High-Angle Annular Dark-Field Imaging2010

    • Author(s)
      W.D.Pyrz
    • Journal Title

      Chem.Mater.

      Volume: 22巻 Pages: 2033-2040

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Orthorhombic Mo-V-Sb Oxide Species by Assembly of Pentagonal Mo_6O_<21> Polyoxometalate Building Blocks2009

    • Author(s)
      M.Sadakane, K.Yamagata, K.Kodato, K.Endo, K.Toriumi, Y.Ozawa, T.Ozeki, T.Nagai, Y.Matsui, N.Sakaguchi, W.D.Pyrz, D.J.Buttrey, D.A.Bolm, T.Vogt, W.Ueda
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 3782-3786

    • Related Report
      2010 Final Research Report 2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High Catalytic Efficiency of Nanostructured Molybdenum Trioxide in the Benzylation of Arenes and an Investigation of the Reaction Mechanism2009

    • Author(s)
      F.Wang, W.Ueda
    • Journal Title

      Chem.Eur.J. 15

      Pages: 742-753

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic behavior of AMoO_x(A=Ba, Sr)in oxidation of 2-propanol2009

    • Author(s)
      J.Kubo, W.Ueda
    • Journal Title

      Mater.Res.Bull. 44

      Pages: 906-912

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective oxidation of alcohols using novel crystalline Mo-V-O oxide as heterogeneous catalyst in liquid phase with molecular oxygen2009

    • Author(s)
      F.Wang, W.Ueda
    • Journal Title

      Catal.Today 144

      Pages: 358-361

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, characterization and catalytic performance of Mo-V-0 oxide layers linked by alkylamines2009

    • Author(s)
      Feng Wang
    • Journal Title

      Chemical Communications

      Pages: 1079-1081

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aerobic oxidation of alcohols over novel crystalline MoV-0 oxide2008

    • Author(s)
      Feng Wang
    • Journal Title

      Applied Catalysis A : General 346

      Pages: 155-163

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molybdenum-Vanadium based Molecular Sieves with a Microchannel of Corner-Sharing 7-Membered Metal-Oxide-Octahedron Ring2008

    • Author(s)
      Masahiro Sadakane
    • Journal Title

      Angewandte Chemie International Edition 47

      Pages: 2493-2496

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Steric effect on the catalytic performance of the selective oxidation of alcohols over novel crystalline Mo-V-0 oxide2008

    • Author(s)
      Feng Wang
    • Journal Title

      Topics in Catalysis 50

      Pages: 90-97

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Oxidation of Alcohols by Orthorhombic Mo-V-0 Phase with Molecular Oxygen2008

    • Author(s)
      Feng Wang
    • Journal Title

      Chemistry Letters 37

      Pages: 184-185

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 結晶性Mo_3VO_x触媒による炭化水素選択酸化反応2011

    • Author(s)
      村山徹
    • Organizer
      平成22年度高難度選択酸化反応研会シンポジウム
    • Place of Presentation
      東京工業大学百年記念館(東京都) 招待講演
    • Year and Date
      2011-01-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of Porous Molybdenum Niobium Oxide by Hydrothermal Method as a Solid Acid Catalyst2011

    • Author(s)
      T.Murayama
    • Organizer
      The 1st International Conference on MEXT Project of Integrated Research on Chemical Synthesis
    • Place of Presentation
      北海道大学創成科学研究棟(北海道)
    • Year and Date
      2011-01-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] New Complex Metal Oxides with Unit Network Structure relating to In dustrial Oxidation Catalysts2010

    • Author(s)
      W.Ueda
    • Organizer
      FUNDAMENTALS OF INDUSTRIAL CATALYSIS
    • Place of Presentation
      Kavli Royal Society Centre(イギリス) 招待講演
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mo-V-O系複合金属酸化物触媒を用いたアクロレイン選択酸化反応2010

    • Author(s)
      中谷浩介
    • Organizer
      第40回石油・石油化学討論会
    • Place of Presentation
      神戸国際会議場(神戸市)
    • Year and Date
      2010-11-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水熱合成法を用いたメソ孔を有するMo-Nb-O複合酸化物の合成2010

    • Author(s)
      村山徹
    • Organizer
      第40回石油・石油化学討論会
    • Place of Presentation
      神戸国際会議場(神戸市)
    • Year and Date
      2010-11-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mo_3VO_x触媒の構造特性および炭化水素選択酸化反応2010

    • Author(s)
      村山徹
    • Organizer
      第43回酸化反応討論会
    • Place of Presentation
      東京大学医学部教育研究棟鉄門記念講堂(東京都)
    • Year and Date
      2010-11-12
    • Related Report
      2010 Annual Research Report
  • [Presentation] 水熱合成法による5,6族元素を用いた多孔性固体酸複合酸化物の合成2010

    • Author(s)
      村山徹、陳俊利、高玉峻介、泉彰子、上田渉
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学甲府キャンパス(山梨)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 水熱合成法による5,6族元素を用いた多孔性固体酸複合酸化物の合成2010

    • Author(s)
      村山徹
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学甲府キャンパス(山梨県)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 複合酸化物触媒の構造と接触酸化反応に関する研究2010

    • Author(s)
      上田渉
    • Organizer
      第106回触媒討論会
    • Place of Presentation
      山梨大学甲府キャンパス(山梨県)
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] MO_3VO_x複合酸化物における細孔構造2010

    • Author(s)
      紺谷岳史
    • Organizer
      第50回オーロラセミナー
    • Place of Presentation
      トーヤ温泉ホテル(北海道)
    • Year and Date
      2010-08-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of mesoporous molybdenum niobium oxide by hydrothermal method2010

    • Author(s)
      T.Murayama
    • Organizer
      TOCAT5/APCAT6 Post conference
    • Place of Presentation
      洞爺パークホテル天翔(北海道)
    • Year and Date
      2010-07-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Catalytic CC coupling reactions at benzylic position over molybdenum oxide2010

    • Author(s)
      F.Wang
    • Organizer
      TOCAT5/APCAT6
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2010-07-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mo_3VO_x as unique high-dimensionally structured porous materials and selective oxidation catalysts2010

    • Author(s)
      T.Konnya, K.Endou, S.Ohmura, T.Katou, T.Fujisawa, M.Sadakane, D.Buttrey, W.Ueda
    • Organizer
      TOCAT5/APCAT6
    • Place of Presentation
      コンベンションセンター(札幌)
    • Year and Date
      2010-07-20
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis of Layered W-V-O mixed metal oxide catalyst2010

    • Author(s)
      K.Nakatani
    • Organizer
      TOCAT5/APCAT6
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2010-07-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mo_3VO_x as unique high-dimensionally structured porous materials and selective oxidation catalysts2010

    • Author(s)
      T.Konnya
    • Organizer
      TOCAT5/APCAT6
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2010-07-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] 結晶構造場におけるアルカンの酸化的活性化2010

    • Author(s)
      上田渉
    • Organizer
      高難度選択酸化反応研究会シンポジウム
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2010-01-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] 酸素八面体モレキュラーシーブ態を有する結晶性Mo酸化物触媒2009

    • Author(s)
      上田渉
    • Organizer
      石油学会九州・沖縄支部30周年記念沖縄大会
    • Place of Presentation
      社団法人石油学会、沖縄産業支援センター
    • Year and Date
      2009-12-18
    • Related Report
      2010 Final Research Report
  • [Presentation] 酸素八面体モレキュラーシーブ態を有する結晶性Mo酸化物触媒2009

    • Author(s)
      上田渉
    • Organizer
      石油学会九州・沖縄支部30周年記念沖縄大会
    • Place of Presentation
      沖縄産業支援センター(沖縄)
    • Year and Date
      2009-12-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高次元構造化する固体選択酸化触媒2009

    • Author(s)
      上田渉
    • Organizer
      第42回酸化反応討論会
    • Place of Presentation
      東北大学片平キャンパス(宮城)
    • Year and Date
      2009-11-14
    • Related Report
      2009 Annual Research Report
  • [Presentation] New Complex Metal Oxide Catalysts for Chemical and Energy Conversion2009

    • Author(s)
      W.Ueda
    • Organizer
      19th Annual Saudi-Japan Symposium
    • Place of Presentation
      KFUPM(サウジアラビア・ダーラン)
    • Year and Date
      2009-11-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] 結晶性MoV複合酸化物生成におけるアニオン性ユニットの形成とカウンターカチオンの効果2009

    • Author(s)
      遠藤敬介、定金正洋、上田渉
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎大学(宮崎)
    • Year and Date
      2009-09-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] Redoxに伴う斜方晶Mo_3VO_x酸化物のミクロ細孔性変化2009

    • Author(s)
      大村俊平、古田戸克倫、定金正洋、上田渉
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎大学(宮崎)
    • Year and Date
      2009-09-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] 低炭素社会のための酸化触媒2009

    • Author(s)
      上田渉
    • Organizer
      触媒学会長野地区講演会
    • Place of Presentation
      信州大学(長野)
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] Microporous Materials Based on Octahedral Molybdenum Oxide2009

    • Author(s)
      W.Ueda, M.Sadakane, D.Buttrey
    • Organizer
      Europacat IX
    • Place of Presentation
      スペイン
    • Year and Date
      2009-09-02
    • Related Report
      2010 Final Research Report
  • [Presentation] Microporous Materials Based on Octahedral Molybdenum Oxide2009

    • Author(s)
      W.Ueda, M.Sadakane, D.Buttrey
    • Organizer
      Europacat IX
    • Place of Presentation
      サラマンカ大学(スペイン・サラマンカ)
    • Year and Date
      2009-09-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] Zeolitic Redox Mo_3VO_x Oxides with Micropore2009

    • Author(s)
      W.Ueda, S.Ohmura, K.Kodato, T.Kuranishi, F.Wang, M.Sadakane, D.Buttrey
    • Organizer
      ZMPC2009
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2009-08-06
    • Related Report
      2010 Final Research Report
  • [Presentation] Zeolitic Redox Mo_3VO_x Oxides with Micoropore2009

    • Author(s)
      W.Ueda, S.Ohmura, K.Kodato, T.Kuranishi, F.Wang, M.Sadalane, D.Buttrey
    • Organizer
      ZMPC2009
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2009-08-06
    • Related Report
      2009 Annual Research Report
  • [Presentation] W置換型斜方晶系Mo-V-O系複合金属酸化物の合成2009

    • Author(s)
      中谷浩介、定金正洋、上田渉
    • Organizer
      第49回オーロラセミナー
    • Place of Presentation
      登別万世閣(北海道)
    • Year and Date
      2009-07-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] Catalytically Selective Oxidation of Alcohols over Crystalline Mo-V-O Complex Oxide2009

    • Author(s)
      F.Wang, W.Ueda
    • Organizer
      6th World Congress on Oxidation Catalysis
    • Place of Presentation
      リール大学(フランス・リール)
    • Year and Date
      2009-07-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] 結晶性Mo_3Vo_x触媒を用いた水中エタン選択酸化挙動2009

    • Author(s)
      定金正洋、藤澤拓己、上田渉
    • Organizer
      石油学会第52回年会
    • Place of Presentation
      タワーホール堀越(東京)
    • Year and Date
      2009-05-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] Mo-V系結晶性複合金属酸化物触媒のビルディングブロック式生成機構2008

    • Author(s)
      定金正洋
    • Organizer
      第38回石油・石油化学討論会
    • Place of Presentation
      国立オリンピック記念青少年総合センター(東京)
    • Year and Date
      2008-11-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] レドックス性斜方晶Mo3V0x酸化物の細孔特性2008

    • Author(s)
      大村俊平
    • Organizer
      第102回触媒討論会
    • Place of Presentation
      名古屋大学(名古屋)
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] Zeolitic Crystalline Mo3V0x oxides active for catalytic selective oxidation2008

    • Author(s)
      Wataru Ueda
    • Organizer
      The 14th International Congress on Catalysis
    • Place of Presentation
      COEX, Seoul, Korea(韓国、ソウル)
    • Year and Date
      2008-06-18
    • Related Report
      2008 Annual Research Report
  • [Book] 表面科学,32(モリブデン酸化物の多様な構造を活用した酸化触媒の創製)2010

    • Author(s)
      上田渉
    • Related Report
      2010 Final Research Report
  • [Book] ふぇらむ,96(触媒反応を起こす表面領域構造の高次化)2010

    • Author(s)
      上田渉
    • Related Report
      2010 Final Research Report
  • [Book] Porous Materials2010

    • Author(s)
      M.Sadakane
    • Publisher
      WILEY
    • Related Report
      2010 Annual Research Report
  • [Book] ふえらむ2010

    • Author(s)
      上田渉
    • Publisher
      社団法人日本鉄鋼協会
    • Related Report
      2010 Annual Research Report
  • [Book] 表面科学2010

    • Author(s)
      上田渉
    • Publisher
      社団法人日本表面科学会
    • Related Report
      2010 Annual Research Report
  • [Book] Turning Points in Solid-State, Materials and Surface Science, A Book in Celebration of the Life and Work of Sir John Meurig Thomas(Edited by K.D.M.Harris and P.P.Edwards)(Structural Organization of Catalytic Functions in Mo-Based Selective Oxidation Catalysts)2008

    • Author(s)
      M.Sadakane, W.Ueda
    • Related Report
      2010 Final Research Report
  • [Book] Turning Points in Solid-State, Materials and Surface Science, A Book in Celebration of the Life and Work of Sir John Meurig Thomas2008

    • Author(s)
      Masahiro Sadakane
    • Publisher
      Royal Society of Chemistry
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://www.cat.hokudai.ac.jp/ueda/index.html

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.cat.hokudai.ac.jp/ueda/index.htm

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.cat.hokudai.ac.jp/ueda/

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.cat.hokudai.ac.jp/ueda/

    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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