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Development of water-hydrogen chemical exchange column packed with catalyst and hydrophilic packing in a random manner

Research Project

Project/Area Number 20246132
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear fusion studies
Research InstitutionNagoya University

Principal Investigator

YAMAMOTO Ichiro  Nagoya University, 大学院・工学研究科, 教授 (50023320)

Co-Investigator(Kenkyū-buntansha) SUGIYAMA Takahiko  名古屋大学, 大学院・工学研究科, 准教授 (90353440)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥25,740,000 (Direct Cost: ¥19,800,000、Indirect Cost: ¥5,940,000)
Fiscal Year 2010: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2009: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
Fiscal Year 2008: ¥7,670,000 (Direct Cost: ¥5,900,000、Indirect Cost: ¥1,770,000)
Keywordsトリチウム / 化学交換法 / 同位体分離 / 水素同位体分離 / 白金触媒 / 化学交換
Research Abstract

A water-hydrogen chemical exchange column, packed with catalyst and hydrophilic packing in a random manner, was developed for a water detritiation system of a fusion reactor. The optimal value of the catalyst packing ratio was found to be about 30 %. A mass balance model, named "Channeling stage model" was developed for separative analysis of the chemical exchange column. Very large separation factor between hydrogen and tritium was obtained experimentally with a random-packed trickle bed chemical exchange column of 1 m length. The maximum value was 19200 when the flow rate of hydrogen gas was 5 L/min. The absolute value and flow rate dependence of the separative performance were well predicted by the Channeling stage model.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (29 results)

All 2011 2010 2009 2008

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (22 results)

  • [Journal Article] A simulation model for transient response of a gas separation module using a hollow fiber membrane2011

    • Author(s)
      T.Sugiyama, N.Miyahara, M.Tanaka, et al
    • Journal Title

      Fusion Engineering Design

      Volume: (inpress)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Performance Tests of Tritium Separation by LPCE Column at TLK Facility2009

    • Author(s)
      T.Sugiyama, M.Tanaka, I.Cristescu, L.Doerr, S.Welte, R.Michling, Y.Asakura, T.Uda, I.Yamamoto
    • Journal Title

      Fusion Science and Technology 56[2]

      Pages: 861-866

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Performance Tests of Tritium Separation by LPCE Column at TLK Facility2009

    • Author(s)
      T.Sugiyama, I.Yamamoto, et al.
    • Journal Title

      Fusion Science and Technology 56[2]

      Pages: 861-866

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of the gas?liquid ratio on the optimum catalyst quantity for the CECE process with a homogeneously packed LPCE column2008

    • Author(s)
      T.Sugiyama, A.Ushida, I.Yamamoto
    • Journal Title

      Fusion Engineering and Design 83

      Pages: 1447-1450

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Development of an improved LPCE column for the TLK facility with the help of the channeling stage model2008

    • Author(s)
      T.Sugiyama, M.Tanaka, K.Munakata, Y.Asakura, T.Uda, I.Yamamoto, I.Cristescu, L.Doerr
    • Journal Title

      Fusion Engineering and Design 83

      Pages: 1442-1446

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of the gas-liquid ratio on the optimum catalyst quantity for the CECE process with a homogeneously packed LPCE column2008

    • Author(s)
      T. Sugiyama, I. Yamamoto
    • Journal Title

      Fusion Engineer ing and Design 83

      Pages: 1447-1450

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of an improved LPCE column for the TLK facility with the help of the channeling stage model2008

    • Author(s)
      T. Sugiyama, I. Yamamoto
    • Journal Title

      Fusion Engineering and Design 83

      Pages: 1442-1446

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Yamamoto Hydrogen-tritium isotope separation by CECE process with a randomly packed LPCE column2010

    • Author(s)
      杉山貴彦, 鈴木英治, 田中将裕
    • Organizer
      9th International Conference on Tritium Science and Technology
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2010-10-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Hydrogen-tritium isotope separation by CECE process with a randomly packed LPCE column2010

    • Author(s)
      T.Sugiyama, E.Suzuki, M.Tanaka, I.Yamamoto
    • Organizer
      9th International Conference on Tritium Science and Technology
    • Place of Presentation
      Nara, Japan奈良県新公会堂
    • Year and Date
      2010-10-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Successive hydrogen isotope separation/enrichment by pressure swing adsorption using SZ-13X column2010

    • Author(s)
      K.Kotoh, M.Tanaka, T.Tsuge, S.Moriyama, et al.
    • Organizer
      9th International Conference on Tritium Science and Technology
    • Place of Presentation
      Nara, Japan奈良県新公会堂
    • Year and Date
      2010-10-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Transient response simulation of tritium removal with gas separation membrane2010

    • Author(s)
      T.Sugiyama, N.Miyahara, M.Tanaka, et al.
    • Organizer
      26th Symposium on Fusion Technology
    • Place of Presentation
      Porto, Portogul
    • Year and Date
      2010-09-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] Studies on effects of tritium water on confinement materials and tritiated water processing2010

    • Author(s)
      T.Yamanishi, T.Hayashi, Y.Iwai, et al
    • Organizer
      26th Symposium on Fusion Technology
    • Place of Presentation
      Porto, Portogul
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 通り抜け段モデルによる化学交換塔の分離性能解析2010

    • Author(s)
      杉山貴彦, 山本一良
    • Organizer
      日本原子力学会「2010秋の大会」
    • Place of Presentation
      北海道大学,北海道
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] トリチウム除去用水分膜分離装置の透過係数と分離係数の評価2010

    • Author(s)
      島井栄允, 平林大介, 澤田佳代, 杉山貴彦, 榎田洋一, 山本一良
    • Organizer
      日本原子力学会「2010秋の大会」
    • Place of Presentation
      北海道大学,北海道
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 均一混合充填型水-水素化学交換塔による軽水素とトリチウムの同位体分離 (3)2010

    • Author(s)
      鈴木英治, 杉山貴彦, 山本一良
    • Organizer
      日本原子力学会 2010年春の年会
    • Place of Presentation
      茨城大学
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] トリチウム除去用水蒸気膜分離装置内の物質移動シミュレーション (3)2010

    • Author(s)
      宮原直哉, 杉山貴彦, 山本一良, 田中将裕
    • Organizer
      日本原子力学会 2010年春の年会
    • Place of Presentation
      茨城大学
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] 水-水素化学交換塔による軽水素とトリチウムの同位体分離2010

    • Author(s)
      杉山貴彦, 鈴木英治, 山本一良
    • Organizer
      第8回同位体科学研究会
    • Place of Presentation
      産業総合技術研究所臨界副都心センター
    • Year and Date
      2010-03-05
    • Related Report
      2010 Final Research Report
  • [Presentation] 水-水素化学交換塔による軽水素とトリチウムの同位体分離2010

    • Author(s)
      杉山貴彦, 鈴木英治, 山本一良
    • Organizer
      第8回 同位体科学研究会
    • Place of Presentation
      産業総合技術研究所 臨界副都心センター
    • Year and Date
      2010-03-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] 均一混合充填型水-水素化学交換塔による軽水素とトリチウムの同位体分離 (2)2009

    • Author(s)
      鈴木英治, 杉山貴彦, 山本一良
    • Organizer
      日本原子力学会中部支部 第41回研究発表会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2009-12-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] 均一混合充填型水-水素化学交換塔による軽水素とトリチウムの同位体分離2009

    • Author(s)
      鈴木英治, 杉山貴彦, 山本一良, 田中将裕
    • Organizer
      日本原子力学会「2009年秋の大会」
    • Place of Presentation
      東北大学
    • Year and Date
      2009-09-18
    • Related Report
      2010 Final Research Report
  • [Presentation] 均一混合充填型水-水素化学交換塔による軽水素とトリチウムの同位体分離2009

    • Author(s)
      鈴木英治, 杉山貴彦, 山本一良, 田中将裕
    • Organizer
      日本原子力学会 2009年秋の大会
    • Place of Presentation
      東北大学
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] トリチウム除去用水蒸気膜分離装置内の物質移動シミュレーション (2)2009

    • Author(s)
      宮原直哉, 杉山貴彦, 山本一良, 田中将裕
    • Organizer
      日本原子力学会 2009年秋の大会
    • Place of Presentation
      東北大学
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] 水-水素化学交換用白金触媒のH-T同位体交換性能評価2009

    • Author(s)
      横地弘章, 鈴木英治, 杉山貴彦, 山本一良
    • Organizer
      第7回同位体科学会
    • Place of Presentation
      サーモフィッシャーサイエンティフィック株式会社
    • Year and Date
      2009-03-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] 全還流型水-水素化学交換塔の分離性能解析2009

    • Author(s)
      鈴木英治, 杉山貴彦, 山本一良
    • Organizer
      第7回同位体科学会
    • Place of Presentation
      サーモフィッシャーサイエンティフィック株式会社
    • Year and Date
      2009-03-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] 水-水素化学交換用白金触媒のH-T同位体交換性能評価2008

    • Author(s)
      鈴木英治, 横地弘章, 宮田章弘, 杉山貴彦, 山本一良
    • Organizer
      日本原子力学会「2008年秋の大会」
    • Place of Presentation
      高知工科大学
    • Year and Date
      2008-09-06
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] Hydrogen isotope separation by combined electrolysis and random-packed chemical exchange column2008

    • Author(s)
      杉山貴彦, 山本一良
    • Organizer
      2nd Japan-China workshop on blanket and tritium technology
    • Place of Presentation
      Sendai, Miyagi, Japan
    • Related Report
      2010 Final Research Report
  • [Presentation] Hydrogen iso tope separation by comb ined electrolysis and random-packed chemi cal exchange column2008

    • Author(s)
      T. Sugiyama, I. Yamamoto
    • Organizer
      2nd Japan-China workshop on blanket and tritium technology
    • Place of Presentation
      Sendai City War Recons truetion Memorial Hall, Sendai, Miyagi Japan
    • Related Report
      2008 Annual Research Report
  • [Presentation] Performance Tests of Tritium Separation by LPCE Column at TLK Facility2008

    • Author(s)
      T. Sugiyama, I. Yamamoto
    • Organizer
      18th Topical meeting on the technology of fusion energy
    • Place of Presentation
      The Stanford Court Hotel, San Francisco, CA, USA
    • Related Report
      2008 Annual Research Report
  • [Presentation] 二重温度二重圧力水-水素化学交換塔による水素同位体分離プロセス2008

    • Author(s)
      鈴木英治, 杉山貴彦, 山本一良
    • Organizer
      第7回核融合エネルギー連合講演会
    • Place of Presentation
      青森市民ホール
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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