Transfer Printing of Conjugated Polymers form Metal to Insulator

• Project/Area Number: 20310053
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nanostructural science
• Research Institution: Ehime University
• Principal Investigator: SAKAGUCHI Hiroshi Ehime University, エネルギー理工学研究所, 教授 (30211931)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥19,760,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥4,560,000); Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2009: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000); Fiscal Year 2008: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
• Keywords: ナノ材料 / 自己組織化 / 表面・界面性 / ナノコンタクト / 表面・界面物性

Research Abstract

Molecular scale printing of polythiophene wires electrochemically fabricated on Au(111) into the insulating substrates such as glass and silicon dioxide was developed. By the use of this technique, we have succeeded in fabrication of FET devices.

Research Products

• [Journal Article] Controlof Self Organization in Conjugated Polymer Fibers (2010)
  • Author(s): S.Chuangchote, M.Fujita, T.Sagawa, H.Sakaguchi, S.Yoshikawa.
  • Journal Title: ACS Appl.Mater.Interfaces. 2(11) Pages: 2995-2997
  • Peer Reviewed
• [Journal Article] Control of Self Organization in Conjugated Polymer Fibers (2010)
  • Author(s): S.Chuangchote, et. al.
  • Journal Title: ACS Appl. Mater. Interfaces Volume: 2(11) Pages: 2995-2997
  • Peer Reviewed
• [Journal Article] Nanoprint Lithography of Gold Nanopatterns on Polyethylene Terephthalate (2009)
  • Author(s): J.Taniguchi, S.Ide, N.Unno, H.Sakaguchi.
  • Journal Title: Microelectronics Engineering 86 Pages: 590-595
  • Peer Reviewed
• [Journal Article] Nanohole Arrays Fabricated on Gold Surfaces by Total Wet Nanopatterning through Block Copolymer Masks (2009)
  • Author(s): R.Watanabe, K.Ito, T.Iyoda, H.Sakaguchi.
  • Journal Title: Japanese Journal of Applied Physics 48
  • NAID: 210000066932
  • Peer Reviewed
• [Journal Article] Nanoprint lithography of gold nanopatterns on polyethylene terephthalate (2009)
  • Author(s): J.Taniguchi, S.Ide, N.Unno, H.Sakaguchi
  • Journal Title: Microelectronics Engineering 86 Pages: 590-595
  • Peer Reviewed
• [Journal Article] Nanohole Arrays Fabricated on Gold Surfaces by Total Wet Nanopatterning through Block Copolymer Masks (2009)
  • Author(s): R.Watanabe, K.Ito, T.Iyoda, H.Sakaguchi
  • Journal Title: Japanese Journal of Applied Physics 48
  • NAID: 210000066932
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): 坂口浩司
  • Journal Title: 超分子サイエンス&テクノロジー(エヌ・ティー・エス出版) Pages: 612-617
• [Journal Article] Nanoprint lithography of gold nanopatterns onpolyethylene terephthalate
  • Author(s): J. Taniguchil, S. Idel, N. Unno, H. Sakaguchi
  • Journal Title: Microelectronics Engineering (印刷中)
  • Peer Reviewed
• [Presentation] ペリレン系ナノ炭素高分子の表面合成 (2011)
  • Author(s): 中江隆博、坂口浩司, 他
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2011-03-29
• [Presentation] 縮環芳香族化合物を用いるグラフェン物質の表面合成 (2011)
  • Author(s): 中江隆博、坂口浩司, 他
  • Organizer: 第40回記念フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 名古屋
  • Year and Date: 2011-03-08
• [Presentation] ペリレン系ナノ炭素高分子の表面合成 (2011)
  • Author(s): 中江隆博, 櫛田芳裕, 溝渕真吾, 佐藤久子, 坂口浩司
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学横浜キャンパス
• [Presentation] 縮環芳香族化合物を用いるグラフェン物質の表面合成 (2011)
  • Author(s): 中江隆博, 櫛田芳裕, 溝渕真吾, 大西竜二, 佐藤久子, 坂口浩司
  • Organizer: 第40回記念フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 名城大学名古屋
• [Presentation] Growth of single-molecular wires on a metal surface (2010)
  • Author(s): T.Nakae, H.Sakaguchi
  • Organizer: International Chemical Congress of Pacific Basin Societies
  • Place of Presentation: Hawaii, USA(招待講演)
  • Year and Date: 2010-12-15
• [Presentation] Molecular Wire Devices By the Use of Electrochemical Epitaxial Polymerization (2010)
  • Author(s): H.Sakaguchi
  • Organizer: The 5^<th> International Symposium on Integrated Molecular/Materials Engineering
  • Place of Presentation: Changzhou, China(招待講演)
  • Year and Date: 2010-09-19
• [Presentation] Growth of single-molecular wires on a metal surface (2010)
  • Author(s): 中江隆博, 坂口浩司
  • Organizer: 2010 International Chemical Congress of Pacific Basin Societies(p.491)(Invited)
  • Place of Presentation: Honolulu, Hawaii
• [Presentation] Molecular Wire Devices By the Use of Electrochemical Epitaxial Polymerization (2010)
  • Author(s): 坂口浩司
  • Organizer: The 5^<th> International Symposium on Integrated Molecular/Materials Engineering
  • Place of Presentation: Changzhou, China
• [Presentation] Symmetric Halogenated Polyaromatic Compounds : Synthesis and Behavior-Towards 2D Network Polymer (2010)
  • Author(s): 中江隆博, 坂口浩司
  • Organizer: International Conference of Synthetic Metals 2010
  • Place of Presentation: Kyoto
• [Presentation] 二次元ポリマーを志向したベンゾ[b]トリチオフェンの合成と挙動 (2009)
  • Author(s): 中江隆博, 夏井裕子, 坂口浩司
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 松山
  • Year and Date: 2009-11-07
• [Presentation] グラフェンナノリボンを目的とした置換ジベンゾ[a,h]アントラセンの合成 (2009)
  • Author(s): 中江隆博, 大西竜二, 坂口浩司
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 松山
  • Year and Date: 2009-11-07
• [Presentation] グラフェンナノリボンを目的としたN,N-ジアルキル-3,4,9,10-テトラブロモペリレン-1,6,7,12-ビスイミドの合成 (2009)
  • Author(s): 中江隆博, 稲垣良太, 坂口浩司
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 松山
  • Year and Date: 2009-11-07
• [Presentation] グラフェンナノリボンを目的としたN, N-ジアルキル-3, 4, 9, 10-テトラブロモペリレン-1, 6, 7, 12-ビスイミドの合成 (2009)
  • Author(s): 中江隆博, 稲垣良太, 坂口浩司
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 松山
  • Year and Date: 2009-11-07
• [Presentation] グラフェンナノリボンを目的とした置換ジベンゾ [a, h] アントラセンの合成 (2009)
  • Author(s): 中江隆博, 大西竜二, 坂口浩司
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 松山
  • Year and Date: 2009-11-07
• [Presentation] 二次元ポリマーを志向したベンゾ [b] トリチオフェンの合成と挙動 (2009)
  • Author(s): 中江隆博, 夏井裕子, 坂口浩司
  • Organizer: 日本化学会西日本大会
  • Place of Presentation: 松山
  • Year and Date: 2009-11-07
• [Presentation] Electrochemical Epitaxial Polymerization of Single Molecular Wires for Devices (2009)
  • Author(s): 坂口浩司
  • Organizer: The 4th International Symposium onIntegrated Molecular Materials Engineering(Invited)
  • Place of Presentation: Chengdu, China
  • Year and Date: 2009-10-26
• [Presentation] Electrochemical Epitaxial Polymerization of Single Molecular Wires for Devices (2009)
  • Author(s): 坂口浩司
  • Organizer: The 4th International Symposium on Integrated Molecular Materials Engineering
  • Place of Presentation: Chengdu, China
  • Year and Date: 2009-10-26
• [Presentation] 電気化学エピタキシャル重合による1分子細線の形成と機能 (2009)
  • Author(s): 坂口浩司
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本
  • Year and Date: 2009-09-16
• [Presentation] Electrochemical Epitaxial Polymerization of Single Molecular Wires (2009)
  • Author(s): 坂口浩司
  • Organizer: International Meeting on Interdiciplinary Chemistry 2009(Invited)
  • Place of Presentation: Ikaho JAPAN
  • Year and Date: 2009-07-18
• [Presentation] Electrochemical Epitaxial Polymerization of Single Molecular Wires (2009)
  • Author(s): 坂口浩司
  • Organizer: International Meeting on Interdisciplinary Chemistry 2009
  • Place of Presentation: Ikaho, Japan
  • Year and Date: 2009-07-18
• [Presentation] 電気化学エピタキシャル重合で形成した1分子細線列の構造と機能 (2009)
  • Author(s): 坂口浩司
  • Organizer: CREST有機太陽電池シンポジウム
  • Place of Presentation: 京都
  • Year and Date: 2009-07-14
• [Presentation] 電気化学エピタキシャル重合により形成した分子細線の構造と機能 (2009)
  • Author(s): 坂口浩司
  • Organizer: 電気化学会第76大会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-29
• [Presentation] 電気化学エピタキシャル重合による1分子細線の形成と機能 (2009)
  • Author(s): 坂口浩司
  • Organizer: 第58回高分子討論会(招待講演)
  • Place of Presentation: 熊本
• [Presentation] 電気化学エピタキシャル重合で形成した1分子細線列の構造と機能 (2009)
  • Author(s): 坂口浩司
  • Organizer: CREST有機太陽電池シンポジウム(招待講演)
  • Place of Presentation: 京都
• [Presentation] Electrochemical Epitaxial Polymerization of Single Conjugated-Polymer Wires on Surface (2008)
  • Author(s): 坂口浩司
  • Organizer: 8th International Conference on Nano-Molecular Electronics(Invited)
  • Place of Presentation: Kobe, Japan
  • Year and Date: 2008-12-16
• [Presentation] Electrochemical Epitaxial Polymerization of Single Conjugated-Polymer Wires on Surface (2008)
  • Author(s): H. Sakaguchi
  • Organizer: 8th International Conference on Nano-Molecular Electronics
  • Place of Presentation: Kobe, Japan
  • Year and Date: 2008-12-16
• [Presentation] Electrochemical Epitaxial Polymerization of Single-Molecular Wires (2008)
  • Author(s): 坂口浩司
  • Organizer: International Symposium on Engineering Micro/Nano-Materials based on Self-Assembling and Self-Organization(Invited)
  • Place of Presentation: Tokyo, Japan
  • Year and Date: 2008-12-08
• [Presentation] Electrochemical Epitaxial Polymerization of Single-Molecular Wires (2008)
  • Author(s): H. Sakaguchi
  • Organizer: International Symposium on Engineering Micro/Nano-Materials based on Self-Assembling and Self-Organization
  • Place of Presentation: Tokyo, Japan
  • Year and Date: 2008-12-08
• [Presentation] Electrochemical Epitaxial Polymerization of conjugated-Polymer Wires (2008)
  • Author(s): 坂口浩司
  • Organizer: 3^<rd> International symposium on Integrated Molecular/Materials Engineering (ISIMME)(p.66)(Invited)
  • Place of Presentation: Xi'an, China
  • Year and Date: 2008-11-07
• [Presentation] Electrochemical Epitaxial Polymerization of conjugated-Polymer Wires (2008)
  • Author(s): H. Sakaguchi
  • Organizer: 3^<rd> International symposium on Integrated Molecular/Materials Engineering (ISIMME)
  • Place of Presentation: Xi' an, China
  • Year and Date: 2008-11-07
• [Presentation] Nanoprint Lithography of Metal Nano-patterns on Plastic Films (2008)
  • Author(s): J. Taniguchi, S. Ide, N. Unno, H. Sakaguchi
  • Organizer: 34^<th> International Conference on Micro-and Nano-Engineering (MNE2008)
  • Place of Presentation: Athens, Greece
  • Year and Date: 2008-09-15
• [Presentation] 導電性高分子ワイヤーの分子スケール転写 (2008)
  • Author(s): 坂口浩司
  • Organizer: 第4回有機太陽電池シンポジウム(招待講演)
  • Place of Presentation: 京都
  • Year and Date: 2008-07-17
• [Presentation] 導電性高分子ワイヤーの分子スケール転写 (2008)
  • Author(s): 坂口浩司
  • Organizer: 第4回有機太陽電池シンポジウム
  • Place of Presentation: 京都
  • Year and Date: 2008-07-17
• [Presentation] Direct Printing of Metal Nano-Patterns on Plastic Films Using Hard Stamp Nanoprint Lithography (2008)
  • Author(s): 谷口淳, 井手翔一, 海野徳幸, 坂口浩司
  • Organizer: The 1st International Conference on nanoManufacturing (nanoMan2008)
  • Place of Presentation: ID164, Singapore
  • Year and Date: 2008-07-15
• [Presentation] Direct Printing of Metal Nano-Patterns on Plastic Films Using Hard Stamp Nanoprint Lithography (2008)
  • Author(s): J. Taniguchi, S. Ide, N. Unno, H. Sakaguchi
  • Organizer: The lst International Conference onnanoManufacturing (nanoMan2008)
  • Place of Presentation: Singapore
  • Year and Date: 2008-07-15
• [Presentation] ナノプリント技術による金属微細パターン転写 (2008)
  • Author(s): 井手翔一, 海野徳幸, 谷口淳, 坂口浩司
  • Organizer: プラスチック成形加工学会
  • Place of Presentation: 東京
  • Year and Date: 2008-06-25
• [Presentation] Nanoprint Lithography of Metal Nano-patterns on Plastic Films (2008)
  • Author(s): 谷口淳, 井手翔一, 海野徳幸, 坂口浩司
  • Organizer: 34^<th> International Conference on Micro-and Nano-Engineering(MNE2008)
  • Place of Presentation: Athens, Greece
• [Book] 導電性高分子ワイア (2009)
  • Author(s): 坂口浩司
  • Publisher: 「超分子サイエンス&テクノロジー」エヌ・ティー・エス出版
• [Book] 単一分子ワイヤーの超階層制御 (2009)
  • Author(s): 坂口浩司
  • Publisher: 「次世代共役ポリマーの超階層制御と革新機能」シーエムシー出版
• [Book] 電気化学エピタキシャル重合によるポリチオフェン単一分子細線の作製 (2009)
  • Author(s): 坂口浩司
  • Publisher: 「有機薄膜太陽電池の最新技術II」シーエムシー出版
• [Book] 有機薄膜太陽電池の最新技術II (2009)
  • Author(s): 坂口浩司
  • Publisher: シーエムシー出版
• [Book] 次世代共役ポリマーの超階層制御と革新機能 (2009)
  • Author(s): 坂口浩司
  • Publisher: シーエムシー出版