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Formation of Novel Graphitic Porous Nano-Carbon with Metal Atom Layers inside

Research Project

Project/Area Number 20310062
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionInstitute for Molecular Science

Principal Investigator

NISHI Nobuyuki  Institute for Molecular Science, 物質分子科学研究領域, 教授 (60013538)

Co-Investigator(Kenkyū-buntansha) JUDAI Ken  分子科学研究所, 物質分子科学研究領域, 助教 (60317302)
NISHIJO JunーIchi  分子科学研究所, 物質分子科学研究領域, 助教 (00390641)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥19,630,000 (Direct Cost: ¥15,100,000、Indirect Cost: ¥4,530,000)
Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2009: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2008: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
Keywordsナノ材料創製 / ナノ表面・界面 / ナノ機能材料 / ナノ構造形成・制御 / グラフェン / ナノカーボン / メソ多孔体 / スーパキャパシタ / 2次電池 / 触媒担持 / 燃料電池 / BET表面積
Research Abstract

In 2009, we have succeeded to synthesize Graphene-multiwalled Alveolate Carbon(GAC) that is made of mostly three layers of graphene sheets with inner charge-conductive layers and outer catalysis-supporting layers. This guarantees high chemical stability against oxidation-reduction chemical changes around catalysis sites. This structure is in contrast with the Mesoporous Carbon Nano-Dendrite(MCND) with mostly singly walled mesopores, while this structure is most favorable for fuel cell electrodes. Platinum nanoparticles are supported tightly inside the pores. Active surface area of the platinum surface amounts to more than 60m^2/g and this system works very well particularly at high relative humidity and aerobic condition. GAC is found to be suited for Lithium ion secondary battery anodes with silicon layers inside the pores. We are trying to design mass-productive industrial processes both of GAC and MCND.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (40 results)

All 2011 2010 2009 2008 Other

All Journal Article (17 results) (of which Peer Reviewed: 17 results) Presentation (4 results) Book (2 results) Remarks (5 results) Patent(Industrial Property Rights) (12 results)

  • [Journal Article] Weakferromagnetism and Strong Spin-Spin Interaction Mediated by the Mixed-Valence Ethynyl-TTF type Ligand2011

    • Author(s)
      西條純一,十代健,西信之
    • Journal Title

      Inorg.Chem. 50

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Weakferromagnetism and Strong Spin-Spin Interaction Mediated by the Mixed-Valence Ethynyl-TTF type Ligand2011

    • Author(s)
      西條純一
    • Journal Title

      Inorganic Chemistry

      Volume: 50

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultrafast Intersystem Crossing of 4-Thiothymidine in Aqueous Solution2010

    • Author(s)
      Yosuke Harada
    • Journal Title

      J.Phys.Chem.Lett.

      Volume: 1 Pages: 480-484

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A molecular picture of metal ion solvation : Infrared spectroscopy of Cu^+(NH_3)_n and Ag^+(NH_3)_n in the gas phase2009

    • Author(s)
      大橋和彦,井上一也,井野拓郎,佐々木淳,十代健,西信之,関谷博
    • Journal Title

      J.Molecular Liquid 147

      Pages: 71-76

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chromium Acetylide Complex Based Ferrimagnet and Weak Ferromagnet2009

    • Author(s)
      西條純一,十代健,沼尾茂悟,西信之
    • Journal Title

      Inorganic Chemistry 48

      Pages: 9402-9408

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of mesoporous carbon nano-dendrites with graphitic ultra-thin walls and their application to supercapacitor electrodes2009

    • Author(s)
      沼尾茂悟,十代健,西條純一,西信之
    • Journal Title

      Carbon 47

      Pages: 306-312

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ferromagnetic Interaction Between [Ni(bdt)_2]- Anions in [Mn_2(Saloph)_2(<μ>-OH)][Ni(bdt)_2](CH3CN)_22009

    • Author(s)
      西條純一,沼尾茂悟,十代健,西信之
    • Journal Title

      Polyhedron 28

      Pages: 1664-1667

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of crystal structure formation under microwave heating2009

    • Author(s)
      高山定次,加倉井一久,武田正康,松原明雄,西原良和,西條純一,佐野三郎,西信之,佐藤元泰
    • Journal Title

      Nucl.Instrum.Meth.A 600

      Pages: 246-249

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Infrared photodissociation spectroscopy of V^+(H_2O)_n(n=2-8) : Coordinative saturation of V^+ with four H_2O molecules2009

    • Author(s)
      佐々木淳,大橋和彦,井上一也,今村利隆,十代健,西信之,関谷博
    • Journal Title

      Chem.Phys.Lett. 474

      Pages: 36-40

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ferromagnetic Interaction Between [Ni(bdt)_2]- Anions in [Mn_2(Saloph)_2(<μ>-OH)] [Ni(bdt)_2](CH3CN)_22009

    • Author(s)
      西條純一
    • Journal Title

      Polyhedron 28

      Pages: 1664-1667

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Investigation of crystal structure formation under microwave heating2009

    • Author(s)
      高山定次
    • Journal Title

      Nucl.Instrum.Meth.A 600

      Pages: 246-249

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chromium Acetylide Complex Based Ferrimagnet and Weak Ferromagnet2009

    • Author(s)
      西條純一
    • Journal Title

      Inorganic Chemistry 48

      Pages: 9402-9408

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of mesoporous carbon nano-dendrites with graphitic ultra-thin walls and their application to supercapacitor electrodes2009

    • Author(s)
      沼尾茂悟
    • Journal Title

      Carbon 47

      Pages: 306-312

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Coordination structures of the silver ion : infrared photodissociation spectroscopy of Ag^+(NH_3)_n(n=3-8)2008

    • Author(s)
      井上一也,大橋和彦,井野拓郎,佐々木淳,十代健,西信之,関谷博
    • Journal Title

      Phys.Chem.Chem.Phys. 10(Cover article)

      Pages: 3052-3062

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Size distribution of gold nanoparticles covered with thiol-terminated cyanobiphenyltype liquid crystal molecules studied with smallangle X-ray scattering and TEM2008

    • Author(s)
      日野和之,新谷理恵,森田剛,徳喜代,北野孝博,吉川英之,中野博史,西信之
    • Journal Title

      Chem.Phys.Lett. 460

      Pages: 173-177

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Increased Electric Conductance through Physisorbed Oxygen on Copper Nanocables Sheathed in Carbon2008

    • Author(s)
      十代健,沼尾茂悟,古屋亜理、西條純一,西信之
    • Journal Title

      J.Am.Chem.Soc. Communication 130

      Pages: 1142-1143

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Size distribution of gold nanoparticles covered with thiol-terminated cyanobiphenyltype liquid crystal molecules studied with smallangle X-ray scattering and TEM2008

    • Author(s)
      日野和之
    • Journal Title

      Chemical Physics Letters 460

      Pages: 173-177

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 多層グラフェン壁を持つ肺胞状炭素(Graphene-multiwalled Alveolate Carbon)の創成と次世代電池電極への応用2010

    • Author(s)
      西信之
    • Organizer
      第4回分子科学討論会
    • Place of Presentation
      大阪大学 豊中キャンパス(大阪府)
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] 多層グラフェン壁を持つ肺胞状炭素(Graphene-multiwalled Alveolate Carbon)の創成と次世代電池電極への応用2010

    • Author(s)
      西信之,太田明雄,沼尾茂悟,臼井千夏,水内和彦
    • Organizer
      分子科学討論会(4D10)
    • Place of Presentation
      大阪
    • Related Report
      2010 Final Research Report
  • [Presentation] 金属を担持した多孔質炭素ナノ樹状体の構造と機能2009

    • Author(s)
      沼尾成悟
    • Organizer
      ナノ学会第7回大会
    • Place of Presentation
      東京大学武田ホール(東京都)
    • Year and Date
      2009-05-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Mesoporous Carbon NanoDendrites with Graphene Walls and their Application to Supercapacitor Electrodes2009

    • Author(s)
      西信之,沼尾茂悟,十代健,西條純一,水内和彦
    • Organizer
      Hybrid Materials 2009
    • Place of Presentation
      Tours, France
    • Related Report
      2010 Final Research Report
  • [Book] クラスターの科学:機能性ナノ構造体の創成(ISBN978-4-946553-38-7 C3043)2009

    • Author(s)
      西信之,佃達也、斎藤真司、矢ケ崎琢磨
    • Total Pages
      153
    • Publisher
      米田出版
    • Related Report
      2010 Final Research Report
  • [Book] クラスターの科学:ナノ構造体の創成2009

    • Author(s)
      西信之
    • Total Pages
      152
    • Publisher
      米田出版
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://nishi-group.ims.ac.jp/

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.ims.ac.jp/know/material/nishi/nishi.html

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://nishi-group.ims.ac.jp/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.ims.ac.jp/know/material/nishi/nishi.html

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://nishi-group.ims.ac.jp/

    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 炭素ナノ構造体2010

    • Inventor(s)
      西信之・安達紀和・大場保幸・山田学・加美謙一郎・水内和彦
    • Industrial Property Rights Holder
      西信之・安達紀和・大場保幸・山田学・加美謙一郎・水内和彦
    • Industrial Property Number
      2010-207936
    • Filing Date
      2010-09-16
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 炭素ナノ構造体、金属担持炭素ナノ構造体、リチウムイオン2次電池、炭素ナノ構造体の製造方法、及び金属担持炭素ナノ構造体の製造方法2010

    • Inventor(s)
      西信之・安達紀和・大場保幸・山田学・加美謙一郎・水内和彦
    • Industrial Property Rights Holder
      西信之・安達紀和・大場保幸・山田学・加美謙一郎・水内和彦
    • Industrial Property Number
      2010-179686
    • Filing Date
      2010-08-10
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 炭素ナノ構造体、金属担持炭素ナノ構造体、リチウムイオン2次電池、炭素ナノ構造体の製造方法、及び金属担持炭素ナノ構造体の製造方法2010

    • Inventor(s)
      西信之
    • Industrial Property Rights Holder
      自然科学研究機構・株式会社デンソー・新日鐵化学株式会社
    • Industrial Property Number
      2010-207936
    • Filing Date
      2010-08-10
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 炭素ナノ構造体2010

    • Inventor(s)
      西信之
    • Industrial Property Rights Holder
      自然科学研究機構・株式会社デンソー・新日鐵化学株式会社
    • Industrial Property Number
      2010-207936
    • Filing Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 非水電解液電池用負極及び非水電解液電池2009

    • Inventor(s)
      山本康平、安達紀和、梅本久、山田学、西信之、沼尾茂悟
    • Industrial Property Rights Holder
      山本康平、安達紀和、梅本久、山田学、西信之、沼尾茂悟
    • Industrial Property Number
      2009-109857
    • Filing Date
      2009-04-28
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 非水電解液電池用負極及び非水電解液電池2009

    • Inventor(s)
      西信之
    • Industrial Property Rights Holder
      自然科学研究機構・株式会社デンソー
    • Industrial Property Number
      2009-109857
    • Filing Date
      2009-04-28
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属内包樹状炭素ナノ構造物、炭素ナノ構造体、金属内包樹状炭素ナノ構造物の作製方法、炭素ナノ構造体の作製方法、及びキャパシタ2008

    • Inventor(s)
      西信之・沼尾茂悟・十代健・西條純一・水内和彦
    • Industrial Property Rights Holder
      西信之・沼尾茂悟・十代健・西條純一・水内和彦
    • Filing Date
      2008-12-09
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 金属内包樹状炭素ナノ構造物、炭素ナノ構造体、金属内包樹状炭素ナノ構造物の作製方法、炭素ナノ構造体の作製方法、及びキャパシタ2008

    • Inventor(s)
      西信之・沼尾茂悟・十代健・西條純一・水内和彦
    • Industrial Property Rights Holder
      西信之・沼尾茂悟・十代健・西條純一・水内和彦
    • Filing Date
      2008-12-09
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 水素吸蔵ナノワイヤ、及び水素吸蔵ナノワイヤの製造方法2008

    • Inventor(s)
      西信之・十代健・水内和彦
    • Industrial Property Rights Holder
      西信之・十代健・水内和彦
    • Industrial Property Number
      2008-281741
    • Acquisition Date
      2008-10-31
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 炭素ナノ構造体を用いたキャパシタ2008

    • Inventor(s)
      西信之・沼尾茂悟・水内和彦
    • Industrial Property Rights Holder
      西信之・沼尾茂悟・水内和彦
    • Industrial Property Number
      2008-120233
    • Filing Date
      2008-05-02
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 金属内包樹状炭素ナノ構造物, 炭素ナノ構造体, 金属内包樹状炭素ナノ構造物の作製方法, 炭素ナノ構造体の作製方法, 及びキャパシタ

    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属内包樹状炭素ナノ構造物, 炭素ナノ構造体, 金属内包樹状炭素ナノ構造物の作製方法, 炭素ナノ構造体の作製方法, 及びキャパシタ

    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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