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Design of accumulated nano-wires and their anisotropic and singular electronic states studied by micro-optical polarized spectroscopy.

Research Project

Project/Area Number 20310066
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

KODAIRA Tetsuya  National Institute of Advanced Industrial Science and Technology, ナノシステム研究部門, 主任研究員 (40356994)

Co-Investigator(Kenkyū-buntansha) EJIMA Takeo  東北大学, 多元物質科学研究所, 准教授 (80261478)
IKEDA Takuji  独立行政法人産業技術総合研究所, コンパクト化学システム研究センター, 主任研究員 (60371019)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2010: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2009: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2008: ¥8,710,000 (Direct Cost: ¥6,700,000、Indirect Cost: ¥2,010,000)
Keywords顕微分光 / ゼオライト / ナノワイヤー / 可視領域分光 / 軟X線 / 粉末X線回折 / 顕微分光法 / 量子細線 / 自己組織化 / 光物性 / 単結晶 / 有機半導体 / 半導体量子細線 / ゼオライト単結晶 / 粉末X線回折法 / 光電子分光 / 一次元電子系 / 偏光分光
Research Abstract

By using single crystals of zeolite AlPO4-5 having one-dimensional (1D) micropores with an inner diameter of 0.7 nm, selenium which is a semiconductor material and anthracene that is aromatic molecules are loaded into the pores. Obeying to the small nano-space, we expected the guest materials exhibit anisotropic and unique electronic properties. Electronic state of selenium atoms in the 1D pores was similar to an isolated three fold helix extracted from bulk trigonal Se. In case of loading anthracene molecules, we expected π-π interaction between the adjacent molecules in the 1D pores because of the restricted orientation of the molecules in the small nano-space. Unfortunately, we could observe no phenomena originating from such interaction.

Report

(5 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Products Report
  • Research Products

    (51 results)

All 2011 2010 2009 2008 Other

All Journal Article (16 results) (of which Peer Reviewed: 15 results) Presentation (27 results) Patent(Industrial Property Rights) (8 results)

  • [Journal Article] Synthesis of Co-substituted Zeolites in the presence of cobalt complex with EDMA2011

    • Author(s)
      M.Kato, T.Ikeda, T.Kodaira, S.Takahashi
    • Journal Title

      Microporous Mesoporous Mater. 142

      Pages: 444-453

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and crystal structure of layered silicate HUS-1 with a halved SOD-cage topology2011

    • Author(s)
      T.Ikeda, Y.Oumi, K.Honda, T.Sano, K.Momma, F.Izumi
    • Journal Title

      Inorg.Chem. 50

      Pages: 2294-2301

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and crystal structure of layered silicate HUS-1 with a halved SOD-came topology2011

    • Author(s)
      T.Ikeda, Y.Oumi, K.Honda, T.Sano, K.Momma, F.Izumi
    • Journal Title

      Inorg.Chem.

      Volume: 50 Pages: 2294-2301

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Co-substituted Zeolites in the presence of cobalt complex with EDMA2011

    • Author(s)
      M.Kato, T.Ikeda, T.Kodaira, S.Takahashi
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 142 Pages: 444-453

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characters of the tetramethylammonium ion in ZK-4 zeolites depending on their Si/Al ratios2010

    • Author(s)
      T.Kodaira, T.Ikeda
    • Journal Title

      J.Phys.Chem.C 114

      Pages: 12885-12895

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 層状物質への相転移を始めとするAlPO_4-5の特異な性質とその利用2010

    • Author(s)
      小平哲也
    • Journal Title

      「第18ゼオライト夏の学校」テキスト(ゼオライト学会発行)

      Pages: 11-22

    • Related Report
      2010 Final Research Report
  • [Journal Article] High throughput and wide field of view EUV microscope for blur-free one-shot imaging of living organisms2010

    • Author(s)
      T.Ejima, F.Ishida, H.Murata, M.Toyoda, T.Harada, T.Tsuru, T.Hatano, M.Yanagihara, M.Yamamoto, H.Mizutani
    • Journal Title

      Opt.Express 18

      Pages: 7203-7209

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characters of the tetramethylammonium ion ZK-4 zeolites depending on their Si/Al ratios2010

    • Author(s)
      T.Kodaira, T.Ikeda
    • Journal Title

      J.Phys.Chem.C

      Volume: 114 Pages: 12885-12895

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High throughput and wide field of view EUV microscope for blur-free one-shot imaging of living organisms2010

    • Author(s)
      T.Ejima, F.Ishida, H.Murata, M.Toyoda, T.Hazada, T.Tsurn, T.Hatano, M.Yanagihara, M.Yamamoto, H.Mizutani
    • Journal Title

      Opt.Express

      Volume: 18 Pages: 7203-7209

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-dimensional detector for high resolution soft X-ray imaging2010

    • Author(s)
      T.Ejima, S.Ogasawara, T.Hatano, M.Yanagihara, M.Yamamoto
    • Journal Title

      Inorg.Chem.

      Volume: 50 Pages: 811-814

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High throughput and wide field of view EUV microscope for blur-free one-shot imaging of living organisms2010

    • Author(s)
      T.Ejima, 他9名
    • Journal Title

      Optics Express 18

      Pages: 7203-7209

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pseudo-micropores formed by one-dimensional framework with hydrogen bonding in CsHSi_2O_5 observed by synchrotron powder diffraction and solid-state2008

    • Author(s)
      T.Ikeda, T.Nishide, H.Nakajima, A.Kawai, Y.Kiyozumi, T.Kodaira, F.Mizukami
    • Journal Title

      MAS NMR 32

      Pages: 2108-2115

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pseudo-micropores formed by one-dimensional framework with hydrogen bonding in CsHSi_2O_5 observed by synchrotron powder diffraction and solid-state MAS NMR2008

    • Author(s)
      T. Ikeda, T. Nishide, H. Nakajima, A. Kawai, Y. Kiyozumi, T. Kodaira, F. Mizukami
    • Journal Title

      New Journal of Chemistry 32

      Pages: 2108-2115

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Cs-Aluminosilicate Zeolites and Thermal Phase Transformation from BIK to CAS Frameworks2008

    • Author(s)
      M. Kato, T. Ikeda, K. Tsutsumi
    • Journal Title

      Microporous and Mesoporous Materials 117

      Pages: 551-560

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of two-dimensional detector for detecting high resolution soft X-ray image

    • Author(s)
      T.Ejima, S.Ogasawara, T.Hatano, M.Yanagihara, M.Yamamoto
    • Journal Title

      AIP conference proceedings Accepted

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SAMRAI : A novel variably polarized angle-resolved photoemission beamline in the VUV region at UVSOR-II

    • Author(s)
      S.Kimura, T.Ejima, 他10名
    • Journal Title

      Review of Scientific Instruments Accepted

    • NAID

      120002414442

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 多目的(透過・反射・ラマン[発光])顕微分光装置の開発2011

    • Author(s)
      関川知宏, 関谷隆夫, 小平哲也
    • Organizer
      2011年春季第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学(厚木市)
    • Year and Date
      2011-03-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] ゼオライトLTAI(ZK-4)の合成メカニズムとその新規応用2011

    • Author(s)
      小平哲也
    • Organizer
      住友化学(株)石油化学品研究所講演会
    • Place of Presentation
      住友化学(姉ヶ崎市)
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] LTA(ZK-4)合成におけるテトラメチルアンモニウムイオンの役割2010

    • Author(s)
      小平哲也, 池田拓史
    • Organizer
      第26回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京)
    • Year and Date
      2010-12-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] ゼオライト転換法で合成された新規層状ケイ酸塩の結晶構造解析2010

    • Author(s)
      池田卓史, 本田昂太郎, 佐野庸治, 近江靖則
    • Organizer
      第26回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京)
    • Year and Date
      2010-12-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] 多目的(透過・反射・ラマン[発光])顕微分光装置の開発2010

    • Author(s)
      関川知宏, 関谷隆夫, 小平哲也
    • Organizer
      2011年春季第58回応用物理学関係連合講演会
    • Place of Presentation
      東京
    • Year and Date
      2010-12-02
    • Related Report
      2010 Final Research Report
  • [Presentation] LTA(ZK-4)合成におけるテトラメチルアンモニウムイオンの役割2010

    • Author(s)
      小平哲也, 池田拓史
    • Organizer
      第26回ゼオライト研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2010-12-02
    • Related Report
      2010 Final Research Report
  • [Presentation] 種々のゼオライトへのアントラセンの吸着とその性状2010

    • Author(s)
      小平哲也, 眞子祥子, 西出利一, 池田拓史
    • Organizer
      第26回ゼオライト研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2010-12-02
    • Related Report
      2010 Final Research Report
  • [Presentation] 種々のゼオライトへのアントラセンの吸着とその性状2010

    • Author(s)
      小平哲也, 眞子祥子, 西出利一, 池田拓史
    • Organizer
      第26回ゼオライト研究発表会
    • Place of Presentation
      タワーホール船堀(東京)
    • Year and Date
      2010-12-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 結晶構造から見るゼオライトおよびその類縁化合物の基礎特性2010

    • Author(s)
      池田卓史
    • Organizer
      GIC22年度第22回研修セミナープログラム
    • Place of Presentation
      産総研東北センター(仙台市)
    • Year and Date
      2010-10-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] その場観察可能な密着型軟X線顕微鏡の開発2010

    • Author(s)
      石田史彦, 江島丈雄, 柳原美広
    • Organizer
      第71回応用物理学学会学術講演会
    • Place of Presentation
      長崎大学(長崎市)
    • Year and Date
      2010-09-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 層状物質への相転移を始めとするAIPO4-5の特異な性質とその利用2010

    • Author(s)
      小平哲也
    • Organizer
      第18回ゼオライト夏の学校
    • Place of Presentation
      長良川スポーツセンター(岐阜市)
    • Year and Date
      2010-09-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] その場位相計測法を用いた定在波発光分光測定による埋もれたFe/Si界面の電子状態測定2010

    • Author(s)
      江島丈雄、後藤智宏、神野貴義、倉光康太, 柳原美広
    • Organizer
      日本物理学会 第65回年次大会
    • Place of Presentation
      岡山大学(岡山市)
    • Year and Date
      2010-03-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] 透過型軟X線反射多層膜顕微鏡を用いた生体試料の観察2010

    • Author(s)
      石田史彦、江島丈雄、柳原美広、水谷治央
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学湘南キャンパス(平塚市)
    • Year and Date
      2010-03-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] Development of I..PP light source for extreme ultraviolet microscope2010

    • Author(s)
      T.Ejima, S.Aizawa, M.Furudate, T.Hatano, M.Yanagihara
    • Organizer
      37th Internatinal Conference on Vacuum Ultra Violet and X-ray Physics
    • Place of Presentation
      Vancouver(Canada)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Super Hierarchical Microscope in EUV Region2010

    • Author(s)
      T.Ejima, M.Toyoda, T.Tsuru, T.Hatano, M.Yanagihara
    • Organizer
      The 10th international conference on X-ray microscopy
    • Place of Presentation
      Chicago, Illinois(U.S.A)
    • Related Report
      2010 Annual Research Report
  • [Presentation] ゼオライトの新規応用法の開拓-高集積ナノ材料創製場としての利用-2009

    • Author(s)
      小平哲也
    • Organizer
      産総研 コンパクト化学プロセス研究センター「研究成果発表会」
    • Place of Presentation
      秋葉原ダイビル(東京秋葉原)
    • Year and Date
      2009-12-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] AlPO_4-5から得られる層状結晶AlPO-NSの形成過程2009

    • Author(s)
      小平哲也, 池田拓史, 奈幡明子, 江島丈雄
    • Organizer
      第25回ゼオライト研究発表会
    • Place of Presentation
      北九州
    • Year and Date
      2009-11-25
    • Related Report
      2010 Final Research Report
  • [Presentation] AlPO_4-5へのS, Se, Teの吸着2009

    • Author(s)
      小平哲也, 池田拓史, 眞子祥子, 江島丈雄
    • Organizer
      第25回ゼオライト研究発表会
    • Place of Presentation
      北九州
    • Year and Date
      2009-11-25
    • Related Report
      2010 Final Research Report
  • [Presentation] AIPO_4-5へのS,Se,Teの吸着2009

    • Author(s)
      小平哲也、池田拓史、眞子祥子、江島丈雄
    • Organizer
      第25回ゼオライト研究発表会
    • Place of Presentation
      西日本総合展示場(北九州市)
    • Year and Date
      2009-11-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] AIPO_4-5から得られる層状結晶AIPO-NSの形成過程2009

    • Author(s)
      小平哲也、池田拓史、奈幡明子、江島丈雄
    • Organizer
      第25回ゼオライト研究発表会
    • Place of Presentation
      西日本総合展示場(北九州市)
    • Year and Date
      2009-11-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] X-ray emission spectra of "buried" Fe/Si interfaces using standing wave method with in-situ phase determination technique2009

    • Author(s)
      T.Ejima, T.Goto, T.Jinno, K.Kuramitsu, M.Yanagihara
    • Organizer
      11-th International Conference on Electronic Spectroscopy and Structures
    • Place of Presentation
      Nara(Japan)
    • Year and Date
      2009-10-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] Development of Two-dimensional Detector for Detecting High Resolution Soft X-ray Image2009

    • Author(s)
      T.Ejima, S.Ogasawara, T.Hatano, M.Yanagihara, M.Yamamoto
    • Organizer
      The 10th International Conference on Synchrotron Radiation Instrumentation
    • Place of Presentation
      Merborne(Australia)
    • Year and Date
      2009-09-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] 生体試料観察のための高空間分解能極紫外顕微鏡の開発2009

    • Author(s)
      江島丈雄、豊田光紀、原田哲男、津留俊英、羽多野忠、柳原美廣、山本正樹
    • Organizer
      第6回東北大学バイオサイエンスシンポジウム
    • Place of Presentation
      仙台国際センター(仙台市)
    • Year and Date
      2009-06-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] AlPO_4-5のHF未添加合成環境における高収率化・高品質化・結晶サイズ増大化2008

    • Author(s)
      小平哲也, 池田拓史
    • Organizer
      第24回ゼオライト研究発表会(ゼオライト学会)
    • Place of Presentation
      東京
    • Year and Date
      2008-11-27
    • Related Report
      2010 Final Research Report
  • [Presentation] AlPO-NSの高温加熱に伴う構造変化と物性2008

    • Author(s)
      池田拓史, 小平哲也
    • Organizer
      第24回ゼオライト研究発表会(ゼオライト学会)
    • Place of Presentation
      東京
    • Year and Date
      2008-11-27
    • Related Report
      2010 Final Research Report
  • [Presentation] AlPO_4-5のHF未添加合成環境における高収率化・高品質化・結晶サイズ増大化2008

    • Author(s)
      小平哲也, 池田拓史
    • Organizer
      第24回ゼオライト研究発表会(ゼオライト学会)
    • Place of Presentation
      東京都江戸川区船堀(タワーホール船堀)
    • Year and Date
      2008-11-27
    • Related Report
      2008 Annual Research Report
  • [Presentation] AlPO-NSの高温加熱に伴う構造変化と物性2008

    • Author(s)
      池田拓史, 小平哲也
    • Organizer
      第24回ゼオライト研究発表会(ゼオライト学会)
    • Place of Presentation
      東京都江戸川区船堀(タワーホール船堀)
    • Year and Date
      2008-11-27
    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] AFI型アルミノリン酸塩多孔性結晶自立膜及びその製造方法2010

    • Inventor(s)
      小平哲也, 眞子祥子, 池田拓史
    • Industrial Property Rights Holder
      (独)産業技術総合研究所
    • Industrial Property Number
      2010-208672
    • Filing Date
      2010-09-17
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] AH型アルミノリン酸塩多孔性結晶自立膜及びその製造方法2010

    • Inventor(s)
      小平哲也, 眞子祥子, 池田拓史
    • Industrial Property Rights Holder
      産業技術総合研究所
    • Industrial Property Number
      2010-208672
    • Filing Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] AFI型アルミノリン酸塩の多孔性結晶自立膜およびその製造方法2010

    • Inventor(s)
      小平 哲也, 眞子 祥子, 池田 拓史
    • Industrial Property Rights Holder
      (独)産業技術総合研究所
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2010-208672
    • Filing Date
      2010-09-17
    • Related Report
      Products Report
  • [Patent(Industrial Property Rights)] コバルト骨格置換アルミノシリケート型ゼオライト、及びその金属錯体共存下での製造方法2009

    • Inventor(s)
      加藤正直, 池田拓史, 小平哲也
    • Industrial Property Rights Holder
      国立高等専門学校機構, (独)産業技術総合研究所
    • Industrial Property Number
      2009-201065
    • Filing Date
      2009-08-31
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 多孔性アルミノリン酸塩結晶AlPO_4-5の合成方法2008

    • Inventor(s)
      小平哲也, 池田拓史
    • Industrial Property Rights Holder
      (独)産業技術総合研究所
    • Industrial Property Number
      2008-299608
    • Filing Date
      2008-11-25
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 多孔性アルミノリン酸トリエチルアミン結晶及びその製造方法2008

    • Inventor(s)
      小平哲也, 池田拓史
    • Industrial Property Rights Holder
      (独)産業技術総合研究所
    • Industrial Property Number
      2008-290471
    • Filing Date
      2008-11-13
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 多孔性アルミノリン酸塩結晶AlPO_4-5の合成方法2008

    • Inventor(s)
      小平・池田
    • Industrial Property Rights Holder
      産総研
    • Industrial Property Number
      2008-299608
    • Filing Date
      2008-11-25
    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] 多孔性アルミノリン酸トリエチルアミン結晶及びその製造方法2008

    • Inventor(s)
      小平・池田
    • Industrial Property Rights Holder
      産総研
    • Industrial Property Number
      2008-290471
    • Filing Date
      2008-11-13
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-09-09  

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