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Electronic structure of superconductive diamond and related materials : Band insulator-metal transition and superconductivity

Research Project

Project/Area Number 20340091
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionOkayama University

Principal Investigator

YOKOYA Takayoshi  Okayama University, 大学院・自然科学研究科, 教授 (90311646)

Co-Investigator(Renkei-kenkyūsha) MURAOKA Yuji  岡山大学, 大学院・自然科学研究科, 准教授 (10323635)
WAKITA Takanori  岡山大学, 大学院・自然科学研究科, 特任助教 (10423279)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2008: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
Keywords高濃度ホウ素ドープダイヤモンド超伝導体 / 半導体-金属転移 / 電子状態 / 光電子分光 / 高濃度リンドープダイヤモンド / ピセン超伝導体 / ダイヤモンド超伝導
Research Abstract

We have investigated evolution of electronic structure across semiconductor to metal transition of boron(B)-doped diamond and its related compounds by using photoemission spectroscopy. Soft x-ray angle-resolved photoemission spectroscopy has revealed valence band electronic dispersions of heavily B-doped superconductive diamond. Core level photoemission spectroscopy has showed multiple chemical sites of dopant atoms for heavily B- and phosphorous-doped diamond. For new superconductors, CaC_6 and potassium doped picene, evolution of electronic structure near the Fermi level due to intercalation and doping, respectively, have been observed directly, which provide insight into the mechanism of the superconductivity.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (41 results)

All 2011 2010 2009 2008 Other

All Journal Article (16 results) (of which Peer Reviewed: 16 results) Presentation (24 results) Remarks (1 results)

  • [Journal Article] Photoemission Study of Electronic Structure Evolution across the Metal-Insulator Transition of Heavily B-doped Diamond2011

    • Author(s)
      H.Okazaki, T.Arakane, K.Sugawara, T.Sato, T.Takahashi, T.Wakita, M.Hirai, Y.Muraoka, Y.Takano, S.Ishii, S.Iriyama, H.Kawarada, T.Yokoya
    • Journal Title

      J.Phys.Chem.Solids 72

      Pages: 582-584

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multiple phosphorus chemical sites in heavily phosphorus-doped diamond2011

    • Author(s)
      H.Okazaki, R.Yoshida, T.Muro, T.Nakamura, T.Wakita, Y.Muraoka, M.Hirai, H.Kato, S.Yamasaki, Y.Takano, S.Ishii, T.Oguchi, T.Yokoya
    • Journal Title

      Appl.Phys.Lett. 98

      Pages: 82107-82107

    • NAID

      120004724414

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Multiple phosphorus chemical sites in heavily phosphorus-doped diamond2011

    • Author(s)
      H.Okazaki, et al.
    • Journal Title

      Appl.Phys.Lett.

      Volume: 98

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic structure of pristine and K-doped picene: Nonrigid band change and its implication for electron-intramolecular-vivration interaction2010

    • Author(s)
      H.Okazaki, T.Wakita, T.Muro, Y.Kaji, X.Lee, H.Mitamura, N.Kawasaki, Y.Kubozono, Y.Yamanari, T.kambe, T.Kato, M.Hirai, Y.Muraoka, T.Yokoya
    • Journal Title

      Phys.Rev.B 82

      Pages: 195114-195114

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoemission study of Ca-intercalated graphite superconductor CaC_52010

    • Author(s)
      H.Okazaki, et al.
    • Journal Title

      PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS

      Volume: 470

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Angle-resolved photoemission study of Si electronic structure : Boron concentration dependence2010

    • Author(s)
      T.Wakita, et al.
    • Journal Title

      PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS

      Volume: 470

    • NAID

      120004724423

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic structure of pristine and K-doped picene : Nonrigid band change and its implication for electron-intramolecular-vivration interaction2010

    • Author(s)
      H.Okazaki, et al.
    • Journal Title

      Phys.Rev.B

      Volume: 82

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic evidence of the existence of substantial Ca 3d derived states at the Fermi level in the Ca-intercalated graphite superconductor CaC_62009

    • Author(s)
      H.Okazaki, R.Yoshida, K.Iwai, K.Noami, T.Muro, T.Nakamura, T.Wakita, Y.Muraoka, M.Hirai, F.Tomioka, Y.Takano, A.Takenaka, M.Toyoda, T.Oguchi, T.Yokoya
    • Journal Title

      Phys.Rev.B 80

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Soft X-Ray Core-Level Photoemission Study of Boron Sites in Heavily Boron-Doped Diamond Films2009

    • Author(s)
      H.Okazaki, R.Yoshida, T.Muro, T.Wakita, M.Hirai, Y.Muraoka, Y.Takano, S.Iriyama, H.Kawarada, T.Oguchi, T.Yokoya
    • Journal Title

      J.Phys.Soc.Jpn. 78

      Pages: 34703-34703

    • NAID

      110007138874

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic evidence of the existence of substantial Ca 3d derived states at the Fermi level in the Ca-intercalated graphite superconductor CaC62009

    • Author(s)
      H.Okazaki, et al.
    • Journal Title

      Physical Review B 80

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The electronic structure of Ca-intercalated superconducting graphite CaC62009

    • Author(s)
      H.Okazaki, et al.
    • Journal Title

      Physica C 469

      Pages: 1041-1044

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ishizaka et al. Reply2009

    • Author(s)
      K.Ishizaka, et al.
    • Journal Title

      Physical Review Letters 102

      Pages: 199702-199702

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Soft X-Ray Core-Level Photoemission Study of Boron Sites in Heavily Boron-Doped Diamond Films2009

    • Author(s)
      H. Okazaki, et al.
    • Journal Title

      J. Phys. Soc. Jpn. 78

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Near E_F electronic structure of heavily boron-doped superconducting diamond2008

    • Author(s)
      H.Okazaki, T.Yokoya, J.Nakamura, N.Yamada, T.Nakamura, T.Muro, Y.Tamenori, T.Matsudhita, Y.Takata, T.Tokushima, S.Shin, Y.Takano, N.Nagao, T.Takenouchi, H.Kawarada, T.Oguchi
    • Journal Title

      J.Phys.Chem.Soilds 69

      Pages: 2978-2981

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Temperature-dependent localized excitations of doped carriers in superconducting diamond2008

    • Author(s)
      K. Ishizaka, et al.
    • Journal Title

      Physical Review Letters 77

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ・Near EF electronic structure of heavily boron-doped superconducting diamond2008

    • Author(s)
      H. Okazaki, et al.
    • Journal Title

      J. Phys. Chem. Solids 69

      Pages: 2978-2981

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] ホットフィラメント化学気相成長法を用いた高濃度ホウ素ドープダイヤモンド膜の作製と物性評価2011

    • Author(s)
      平松千明, 他
    • Organizer
      日本物理学会第66回年次大会
    • Place of Presentation
      新潟大学
    • Year and Date
      2011-03-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Siの光電子分光:空準位の効果2010

    • Author(s)
      脇田高徳, 他
    • Organizer
      日本物理学会2010年秋季大会
    • Place of Presentation
      大阪府立大学中百舌鳥キャンパス
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] TaCフィラメントを用いたHFCVD法による高濃度ホウ素ドープ超伝導ダイヤモンド膜の作製2010

    • Author(s)
      土居智彰, 他
    • Organizer
      応用物理学会中国四国支部日本物理学会中国支部・四国支部日本物理教育学会中国四国支部2010年度支部学術講演会
    • Place of Presentation
      高知大学朝倉キャンパス
    • Year and Date
      2010-07-31
    • Related Report
      2010 Annual Research Report
  • [Presentation] Photoemission Study of The Electronic Structure Evolution across Metal-Insulator Transition of Heavily B-doped Diamond2010

    • Author(s)
      Hiroyuki Okazaki, Takayuki Arakane, Katsuaki Sugawara, Takahumi Sato, Takashi Takahashi, Takanori Wakita, Masaaki Hirai, Yuji Muraoka, Yoshihiko Takano, Satoshi Ishii, Shingo Iriyama, Hiroshi Kawarada, Takayoshi Yokoya
    • Organizer
      the 9th International Conference on Spectroscopies in Novel Superconductors (SNS2010) (5/23-5/28/2010)
    • Place of Presentation
      Shanghai, Chaina
    • Year and Date
      2010-05-24
    • Related Report
      2010 Final Research Report
  • [Presentation] Photoemission Study of The Electronic Structure Evolution across Metal-Insulator Transition of Heavily B-doped Diamond2010

    • Author(s)
      Hiroyuki Okazaki, et al.
    • Organizer
      the 9th International Conference on Spectroscopies in Novel Superconductors (SNS2010)
    • Place of Presentation
      中国 上海
    • Year and Date
      2010-05-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] Si(111)1x1水素終端面の角度分解共鳴光電子分光2010

    • Author(s)
      脇田高徳, 他
    • Organizer
      日本物理学会 第65回年次大会
    • Place of Presentation
      岡山大学津島キャンパス(岡山県)
    • Year and Date
      2010-03-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] 光電子分光によるポタシウムドープピセンの電子状態2010

    • Author(s)
      岡崎宏之, 他
    • Organizer
      日本物理学会 第65回年次大会
    • Place of Presentation
      岡山大学津島キャンパス(岡山県)
    • Year and Date
      2010-03-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] ホットフィラメントCVD法を用いた溶液原料からの高濃度ホウ素ドープダイヤモンド膜の作製2010

    • Author(s)
      土居智彰, 他
    • Organizer
      2010年春季 第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学湘南キャンパス(神奈川県)
    • Year and Date
      2010-03-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] 光電子分光による芳香族多環縮合炭化水素ピセンの電子状態2009

    • Author(s)
      岡崎宏之, 他
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学黒髪キャンパス(熊本県)
    • Year and Date
      2009-09-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] グラファイトインターカレーション超伝導体CaC6の共鳴光電子分光2009

    • Author(s)
      岡崎宏之, 他
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学黒髪キャンパス(熊本県)
    • Year and Date
      2009-09-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Photoemission Study of Ca-intercalated Graphite Superconductor CaC62009

    • Author(s)
      H.Okazaki, et al.
    • Organizer
      The 9th International Conference on Materials and Mechanisms of Superconductivity(M2S-IX)
    • Place of Presentation
      Keio Plaza Hotel, Tokyo, Japan,
    • Year and Date
      2009-09-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Photoemission Spectroscopy of Doped Band Insulators and Related Superconductors2009

    • Author(s)
      T.Yokoya, et al.
    • Organizer
      The 9th International Conference on Materials and Mechanisms of Superconductivity(M2S-IX)
    • Place of Presentation
      Keio Plaza Hotel, Tokyo, Japan,
    • Year and Date
      2009-09-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] 熱フィラメントCVD法による高濃度ホウ素ドープダイヤモンド膜の作製2009

    • Author(s)
      土居智彰, 他
    • Organizer
      応用物理学会中国四国支部、日本物理学会中国支部、四国支部2009年度支部学術講演会
    • Place of Presentation
      広島大学東広島キャンパス(広島県)
    • Year and Date
      2009-08-01
    • Related Report
      2009 Annual Research Report
  • [Presentation] シリコンの光電子分光 : ボロン濃度依存性II2009

    • Author(s)
      脇田高徳, 他
    • Organizer
      日本物理学会(第64回年次大会)
    • Place of Presentation
      立教学院池袋キャンパス
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 光電子分光による高濃度ホウ素ドープダイヤモンドの金属-絶縁体転移前後の電子状態の観測2009

    • Author(s)
      岡崎宏之, 他
    • Organizer
      日本物理学会(第64回年次大会)
    • Place of Presentation
      立教学院池袋キャンパス
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] Photoemission Spectroscopy of Doped Band Insulators and Related Superconductors2009

    • Author(s)
      Takayoshi Yokoya, Hiroyuki Okazaki, Takanori Wakita, Rikiya Yoshida, Masaaki Hirai, Yuji Muraoka
    • Organizer
      The 9th International Conference on Materials and Mechanisms of Superconductivity (M^2S-IX)
    • Place of Presentation
      Keio Plaza Hotel, Tokyo, Japan
    • Related Report
      2010 Final Research Report
  • [Presentation] Photoemission Study of Ca-intercalated Graphite Superconductor CaC_62009

    • Author(s)
      H.Okazaki, R.Yoshida, K.Iwai, K.Noami, T.Muro, T.Nakamura, T.Wakita, Y.Muraoka, M.Hirai, F.Tomioka, Y.Takano, A.Takenaka, M.Toyoda, T.Oguchi, T.Yokoya
    • Organizer
      The 9th International Conference on Materials and Mechanisms of Superconductivity (M^2S-IX)
    • Place of Presentation
      Keio Plaza Hotel, Tokyo, Japan
    • Related Report
      2010 Final Research Report
  • [Presentation] 光電子分光による芳香族多環縮合炭化水素ピセンの電子状態2009

    • Author(s)
      岡崎宏之、室隆桂之、為則雄祐、脇田高徳、村岡祐治、平井正明、川崎菜穂子、加地由美子、久保園芳博、山成悠介、神戸高志、横谷尚睦
    • Organizer
      日本物理学会2009年秋季大会
    • Place of Presentation
      熊本大学黒髪キャンパス
    • Related Report
      2010 Final Research Report
  • [Presentation] Photoemission spectroscopy study of heavily boron doped diamond and silicon electronic structures2008

    • Author(s)
      T.Wakita, H.Okazaki, K.Saeki, M.Ono, T.Eguchi, T.Okuda, A.Harasawa, I.Matsuda, Y.Hasegawa, Y.Takano, M.Hirai, Y.Muraoka, T.Yokoya
    • Organizer
      The 2nd International Symposium on Anomalous Quantum Materials (ISAQM2008) and the 7th Asia-Pacific Workshop
    • Place of Presentation
      東京大学本郷キャンパス
    • Year and Date
      2008-11-09
    • Related Report
      2010 Final Research Report
  • [Presentation] Photoemission spectroscopy study of heavily boron doped diamond and siliconelectronic structures.2008

    • Author(s)
      T. Wakita, et al.
    • Organizer
      The 2nd International Symposium on Anomalous Quantum Materials(ISAQM2008)and the 7th Asia-Pacific Workshop
    • Place of Presentation
      東京大学本郷キャンパス
    • Year and Date
      2008-11-09
    • Related Report
      2008 Annual Research Report
  • [Presentation] The electronic structure of Ca-intercalated superconducting graphite CaC62008

    • Author(s)
      H. Okazaki, et al.
    • Organizer
      21th International Symposium on Superconductivity (ISS2008)
    • Place of Presentation
      エポカルつくば
    • Year and Date
      2008-10-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] 高分解能光電子分光によるグラフアイトインターカレーション超伝導体CaC6の電子状態2008

    • Author(s)
      岡崎宏之, 他
    • Organizer
      日本物理学会(2008年秋季大会)
    • Place of Presentation
      岩手大学上田キャンパス
    • Year and Date
      2008-09-21
    • Related Report
      2008 Annual Research Report
  • [Presentation] シリコンの光電子分光 : ボロン濃度依存性.2008

    • Author(s)
      脇田高徳, 他
    • Organizer
      日本物理学会(2008年秋季大会)
    • Place of Presentation
      岩手大学上田キャンパス
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] グラフアイトインクーカレーション超伝導体C6Caの高分解能光電子分光2008

    • Author(s)
      岡崎宏之, 他
    • Organizer
      応用物理学会中国四国支部 日本物理学会中国支部・四国支部日本物理教育学会中国四国支部 2008年度支部学術講演会
    • Place of Presentation
      愛媛大学
    • Year and Date
      2008-08-02
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://film.rlss.okayama-u.ac.jp/

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2020-05-15  

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