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A GENERAL METHOD FOR THE SYNTHESIS OF POLYCYCLIC AROMATIC HYDROCARBONS BASED ON SEQUENCIAL CATIONIC CYCLIZATIONS

Research Project

Project/Area Number 20350016
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionUniversity of Tsukuba (2009-2011)
Ibaraki University (2008)

Principal Investigator

ICHIKAWA Junji  筑波大学, 数理質系, 教授 (70184611)

Project Period (FY) 2008 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥19,370,000 (Direct Cost: ¥14,900,000、Indirect Cost: ¥4,470,000)
Fiscal Year 2011: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2010: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2009: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2008: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
Keywordsカルボカチオン / フルオロアルケン / フルオロアレン / 分子内環化 / Friedel-Crafts反応 / 縮合 / 芳香族化合物 / 縮合環 / ナフタレン / ヘリセン / 合成有機化学 / S_N2'型反応 / 脱水素 / 分子内還化 / パラジウム触媒 / SN2'型反応
Research Abstract

Fluorine substituent has an α-cation-stabilizing effect as well as a leaving-group ability as a fluoride ion. Using these two properties in combination allows α-fluoro carbocations to be readily generated from fluoroalkenes and fluoroallenes. We have succeeded in highly efficient and selective domino and tandem cyclizations, which proceed via the α-fluoro carbocations to construct PAHs such as helicenes and acenes including higher-order helicenes. Moreover, fluorinated PAHs are produced by our methods. In the course of study, we have also established facile methods for the syntheses of 1, 1-difluoroalkenes and 1, 1-difluoroallenes as starting materials of our cyclizations.

Report

(6 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report   Self-evaluation Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (57 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (29 results) (of which Peer Reviewed: 29 results) Presentation (23 results) Remarks (5 results)

  • [Journal Article] Facile Synthesis of Substituted1, 1-Difluoroallenes via CarbonylDifluorovinylidenation2012

    • Author(s)
      Oh, K.; Fuchibe, K.; Yokota, M.; Ichikawa, J.
    • Journal Title

      Synthesis

      Volume: 44 Issue: 06 Pages: 857-861

    • DOI

      10.1055/s-0031-1290157

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] J.NHC-Catalyzed Generation of Difluorocarbene and its Application to Difluoromethylation of Oxygen Nucleophiles2012

    • Author(s)
      K.; Koseki, Y.; Aono, T.; Sasagawa, H.; Ichikawa
    • Journal Title

      J. Fluorine Chem

      Volume: 133 Pages: 52-60

    • URL

      http://dx.doi.org/10.1016/j.jfluchem.2011.0

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] J. NHC-Catalyzed Difluorocarbene Generation and Its Application to Aryl Difluoromethyl Ether Synthesis2011

    • Author(s)
      Fuchibe, K.; Koseki, Y.; Sasagawa, H.; Ichikawa
    • Journal Title

      Chem. Lett

      Volume: 40 Issue: 10 Pages: 986-988

    • DOI

      10.1246/cl.2011.1189

    • NAID

      10029683941

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] J Facile Synthesis of β, β-Difluorostyrenes via the Negishi Coupling of Thermally Stable 2, 2-Difluorovinyl Zinc-TMEDA Complex2011

    • Author(s)
      Fujita, T.; Ichitsuka, T.; Fuchibe, K.; Ichikawa
    • Journal Title

      Chem. Lett

      Volume: 40 Issue: 43 Pages: 986-988

    • DOI

      10.1002/chem.201100618

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Illusory molecular expression of "Penrose stairs" by an aromatic hydrocarbon2011

    • Author(s)
      Nakanishi, W.; Matsuno, T.; Ichikawa, J.; Isobe, H.
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 50 Issue: 27 Pages: 6048-6051

    • DOI

      10.1002/anie.201102210

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 5-Endo-Trig Cyclization of 1, 1-Difluoro-1-Alkenes : Synthesis of 3-Butyl-2-Fluoro-1-Tosylindole (1H-Indole, 3-Butyl-2-Fluoro-1-[(4-Methylphenyl)Sulfo nyl]-)2011

    • Author(s)
      Ichikawa, J
    • Journal Title

      Org. Synth

      Volume: 88 Pages: 162-167

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 1, 1-Difluoroallenes from Commercially Available 1, 1, 1-Trifluoro-2-iodoethane2011

    • Author(s)
      Oh, K.; Fuchibe, K.; Ichikawa, J
    • Journal Title

      Synthesis

      Volume: 2011 Issue: 06 Pages: 881-886

    • DOI

      10.1055/s-0030-1258438

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of β,β-Difluorostyrenes via the Negishi Coupling of Thermally Stable 2,2-Difluorovinyl Zinc-TMEDA Complex2011

    • Author(s)
      Fujita, T.; Ichitsuka, T.; Fuchibe, K.; Ichikawa, J.
    • Journal Title

      Chem.Lett.

      Volume: 40 Issue: 9 Pages: 986-988

    • DOI

      10.1246/cl.2011.986

    • NAID

      10029522357

    • URL

      https://www.jstage.jst.go.jp/article/cl/40/9/40_9_986/_article

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rapid and Slow Generation of 1-Trifluoromethylvinyl-lithium : Syntheses and Applications of CF3-Containing Allylic Alcohols, Allylic Amines, and Vinyl Ketones2010

    • Author(s)
      Nadano, R.; Fuchibe, K.; Ikeda, M.; Takahashi, H.; Ichikawa, J
    • Journal Title

      Chem. Asian J

      Volume: 5 Issue: 8 Pages: 1875-1883

    • DOI

      10.1002/asia.201000139

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Indium (III)-catalyzed Coupling between Alkynes and Aldehydes to α, β-Unsaturated Ketones2010

    • Author(s)
      Miura, K.; Yamamoto, K.; Yamanobe, A.; Ito, K.; Kinoshita, H.; Ichikawa, J; Hosomi, A
    • Journal Title

      Chem. Lett

      Volume: 39 Issue: 7 Pages: 766-767

    • DOI

      10.1246/cl.2010.766

    • NAID

      130004425911

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Transition-metal-catalyzed Electrophilic Activation of 1,1-Difluoro-1-alkenes: Oxindole Synthesis via Intramolecular Amination2010

    • Author(s)
      Tanabe, H.; Ichikawa, J
    • Journal Title

      Chemistry Letters

      Volume: 39 Issue: 3 Pages: 248-249

    • DOI

      10.1246/cl.2010.248

    • NAID

      130004425781

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxidative Arylation Mediated by Naphthalene-1,8-diylbis(diphenylmethylium): Synthetic Route to Triarylsulfonium Salts2010

    • Author(s)
      Tanabe, H.; Kawai, T.; Saitoh, T.; Ichikawa, J
    • Journal Title

      Chemistry Letters

      Volume: 39 Issue: 1 Pages: 56-57

    • DOI

      10.1246/cl.2010.56

    • NAID

      10027176598

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthetic Methods for Heterocycles and Carbocycles Bearing Fluorinated One-Carbon Units (=CF_2, CHF_2, or CF_3) : Intramolecular Reaction of 2-Trifluoromethy1-1-alkenes2010

    • Author(s)
      J.Ichikawa
    • Journal Title

      J.Synth.Org.Chem.Jpn. 68

      Pages: 1175-1184

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Rapid and Slow Generation of 1-Trifluoromethylvinyllithium : Syntheses and Applications of CF_3-Containing Allylic Alcohols, Allylic Amines, and Vinyl Ketones2010

    • Author(s)
      R.Nadano, K.Fuchibe, M.Ikeda, H.Takahashi, J.Ichikawa
    • Journal Title

      Chem.Asian J. 5

      Pages: 1875-1883

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Transition-metal-catalyzed Electrophilic Activation of 1, 1-Difluoro-1-alkenes : Oxindole Synthesis via Intramolecular Animation2010

    • Author(s)
      H.Tanabe, J.Ichikawa
    • Journal Title

      Chem.Lett. 39

      Pages: 248-249

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Oxidative Arylation Mediated by Naphthalene-1, 8-diylbis (diphenylmethylium) : Synthetic Route to Triarylsulfonium Salts2010

    • Author(s)
      H.Tanabe, T.Kawai, T.Saitoh, J.Ichikawa
    • Journal Title

      Chem.Lett. 39

      Pages: 56-57

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Rapid and Slow Generation of 1-Trifluoromethylvinyllithium : Syntheses and Applications of CF, -Containing Allylic Alcohols, Allylic Amines, and Vinyl Ketones2010

    • Author(s)
      Nadano, R., Fuchibe, K., Ikeda, M.,Takahashi, H., Ichikawa, J.
    • Journal Title

      Chemistry-Asian Journal

      Volume: 5 Pages: 1875-1883

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthetic Methods for Heterocycles and Carbocycles Bearing Fluorinated One-Carbon Units (=CF_2, CHF_2, or CF_3) : Intramolecular Reaction of 2-Trifluoromethyl-1-alkenes2010

    • Author(s)
      Ichikawa, J.
    • Journal Title

      Journal of Synthetic Orgnic Chemistry, Japan

      Volume: 68 Pages: 1175-1184

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Facile Synthesis of 1, 1-Difluoroallenes from Commercially Available 1, 1, 1-Trifluoro-2-iodoethane2010

    • Author(s)
      Oh, K., Fuchibe, K., Ichikawa, J.
    • Journal Title

      Synthesis

      Pages: 881-886

    • NAID

      120007137324

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transition-metal-catalyzed Electrophilic Activation of 1,1-Difluoro-1-alkenes : Oxindole Synthesis via Intramolecular Amination2010

    • Author(s)
      H.Tanabe, J.Ichikawa
    • Journal Title

      Chemistry Letters 39

      Pages: 248-249

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Concise Synthesis of Halogenated Chrysenes ([4]Phenacenes) That Favor π-Stack Packing in Single Crystals2009

    • Author(s)
      Isobe, H.; Hitosugi, S.; Matsuno, T.; Iwamoto, T.; Ichikawa, J
    • Journal Title

      Org. Lett

      Volume: 11 Issue: 17 Pages: 4026-4028

    • DOI

      10.1021/ol901693y

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of 1, 1-Difluoroallenes via the Difluorovinylidenation of Aldehydes and Ketones2009

    • Author(s)
      Yokota, M.; Fuchibe, K.; Ueda, M.; Mayumi, Y.; Ichikawa, J
    • Journal Title

      Org. Lett

      Volume: 11 Issue: 17 Pages: 3994-3997

    • DOI

      10.1021/ol9016673

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Concise Synthesis of Halogenated Chrysenes ([4]Phenacenes) that Favor p-Stack Packing in Single Crystals2009

    • Author(s)
      H.Isobe, S.Hitosugi, T.Matsuno, T.Iwamoto, J.Ichikawa
    • Journal Title

      Org.Lett. 11

      Pages: 4026-4028

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of 1,1-Difluoroallenes via the Difluorovinylidenation of Aldehydes and Ketones2009

    • Author(s)
      M.Yokota, K.Fuchibe, M.Ueda, Y.Mayumi, J.Ichikawa
    • Journal Title

      Org.Lett. 11

      Pages: 3994-3997

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Facile Synthesis of 1,1-Difluoroallenes via the Difluorovinylidenation of Aldehydes and Ketones2009

    • Author(s)
      M.Yokota, K.Fuchibe, M.Ueda, Y.Mayumi, J.Ichikawa
    • Journal Title

      Organic Letters 11

      Pages: 3994-3997

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Concise Synthesis of Halogenated Chrysenes([4]Phenacenes)that Favor π-Stack Packing in Single Crystals2009

    • Author(s)
      H.Isobe, S.Hitosugi, T.Matsuno, T.Iwamoto, J.Ichikawa
    • Journal Title

      Organic Letters 11

      Pages: 4026-4028

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Efficient Helicene Synthesis : Friedel-Crafts-Type Cyclization of 1, 1-Difluoro-1-alkenes2008

    • Author(s)
      Ichikawa, J.; Yokota, M.; Kudo, T.; Umezaki, S
    • Journal Title

      Angew. Chem. Int

      Volume: 47 Issue: 26 Pages: 4870-4873

    • DOI

      10.1002/anie.200801396

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A New Class of Substrates for Nucleophilic 5-endo-trig Cyclization, 2-Trifluoromethyl-1-alkenes : Synthesis of Five-Membered Hetero-and Carbocycles That Bear Fluorinated One-Carbon Units2008

    • Author(s)
      Ichikawa, J.; Iwai, Y.; Nadano, R.; Mori, T.; Ikeda, M. J
    • Journal Title

      Chem. Asian J

      Volume: 3 Issue: 2 Pages: 393-406

    • DOI

      10.1002/asia.200700324

    • NAID

      120007138872

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Facile Synthesis of 1,1-Difluoroallenes from Commercially Available 1,1,1-Trifluoro-2-iodoethane

    • Author(s)
      K.Oh, K.Fuchibe, J.Ichikawa
    • Journal Title

      Synthesis 2011

      Pages: 881-886

    • NAID

      120007137324

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Presentation] Metal-Catalyzd Domino Difluorocyclo-propanation.Ring Expansion of 2-Siloxy-1, 3-dienes2011

    • Author(s)
      Aono, T.; Sasagawa, H.; Fuchibe, K.; Ichikawa, J
    • Organizer
      Synthesis of Fluorinated Cyclic Silyl Enol Ethers
    • Place of Presentation
      ISOR-10, Yokohama
    • Year and Date
      2011-11-02
    • Related Report
      2011 Final Research Report
  • [Presentation] Sequential Substitutions of 2-Trifluoromethyl-1-alkenes2011

    • Author(s)
      Takahashi, M.; Hattori, M.; Fuchibe, K.; Ichikawa, J
    • Organizer
      Regioselective Synthesis of 3-Fluoropyrazoles
    • Place of Presentation
      ISOR-10, Yokoham
    • Year and Date
      2011-11-02
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of F-PAHs by In (III)-Catalyzed Domino Cyclization2011

    • Author(s)
      Fuchibe, K.; Zhao, N.; Mayumi, Y.; Ichikawa, J
    • Organizer
      Ring Expansion of 1, 1-Difluoroallenes
    • Place of Presentation
      ISIS-7, Kobe
    • Year and Date
      2011-10-10
    • Related Report
      2011 Final Research Report
  • [Presentation] Electrophilic Cyclization of Fluoro Alkenes Directed toward PAH Synthesis2011

    • Author(s)
      Ichikawa, J.
    • Organizer
      242nd ACS National Meeting
    • Place of Presentation
      Denver, U.S.A(招待講演)
    • Year and Date
      2011-08-29
    • Related Report
      2011 Annual Research Report
  • [Presentation] Electrophilic Cyclization of Fluoro Alkenes Directed toward PAH Synthesis2011

    • Author(s)
      Ichikawa, J
    • Organizer
      [Invited] 242nd ACS National Meeting
    • Place of Presentation
      Denver
    • Year and Date
      2011-08-28
    • Related Report
      2011 Final Research Report
  • [Presentation] Electrophilic Cyclization of Fluoro Alkenes Directed toward PAH Synthesis2011

    • Author(s)
      Ichikawa, J
    • Organizer
      NTU-JSPS Joint Symposium
    • Place of Presentation
      Singapor
    • Year and Date
      2011-08-02
    • Related Report
      2011 Final Research Report
  • [Presentation] Electrophilic Cyclization of Fluoro Alkenes Directed toward PAH Synthesis2011

    • Author(s)
      Ichikawa, J.
    • Organizer
      NTU-JSPS JOINT SEMINAR 2011
    • Place of Presentation
      Singapore, Singapore(招待講演)
    • Year and Date
      2011-08-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] In (III)-Catalyzed Synthesis of F-PAHs2011

    • Author(s)
      Fuchibe, K.; Zhao, N.; Mayumi, Y.; Ichikawa, J
    • Organizer
      Domino Cyclization. Ring Expansion Reactions of 1, 1-Difluoroallenes
    • Place of Presentation
      OMCOS-16, Shanghai
    • Year and Date
      2011-07-24
    • Related Report
      2011 Final Research Report
  • [Presentation] Transformation of C-F bonds via electrophilic activation of fluoro alkenes2010

    • Author(s)
      Ichikawa, J
    • Organizer
      Invited
    • Place of Presentation
      Pacifichem 2010Honolulu, Hawaii
    • Year and Date
      2010-12-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Indium (III)-Catalyzed Cyclization of 1, 1-Difluoroallenes2010

    • Author(s)
      uchibe, K.; Mayumi, Y.; Wang, K.;Yokota, M.; Ichikawa, J
    • Organizer
      Construction of Naphthalene and Phenanthrene Frameworks
    • Place of Presentation
      Pacifichem 2010, Honolulu, Hawaii
    • Year and Date
      2010-12-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Cationic palladium (II)-catalyzed Friedel. Crafts-type cyclizations of 1, 1-difluoro-1-alkenes2010

    • Author(s)
      Fuchibe, K.; Morikawa, T.; Ichitsuka, T.; Fujita, D.; Tanabe, H.; Yokota, M.; Ichikawa, J
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2010-12-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Transformation of C-F bonds via electrophilic activation of fluoro alkenes2010

    • Author(s)
      市川淳士
    • Organizer
      Pacifichem 2010
    • Year and Date
      2010-12-15
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Transformation of C-F bonds via electrophilic activation of fluoro alkenes2010

    • Author(s)
      Ichikawa, J.
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2010-12-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] New Entry to Fluorinated PAHs : Palladium (II)-Catalyzed Electrophilic Cyclization of 1, 1-Difluoro-1-alkenes2010

    • Author(s)
      Ichikawa, J
    • Organizer
      6th International Symposium on Integrated Synthesis (ISIS-6)
    • Place of Presentation
      Kobe
    • Year and Date
      2010-10-23
    • Related Report
      2011 Final Research Report
  • [Presentation] Friedel-Crafts Cyclizations of Fluro Alkenes Directed toward Polycyclic Aromatic Hydrocarbon (PAH) Synthesis2010

    • Author(s)
      Ichikawa, J
    • Organizer
      [Invited] 3rd Korea.Japan.China Joint Seminar on Fluorine Chemistry
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      2010-09-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Friedel-Crafts Cyclizations of Fluro Alkenes Directed toward Polycyclic Aromatic Hydrocarbon (PAH) Synthesis2010

    • Author(s)
      市川淳士
    • Organizer
      3rd Korea-Japan-China Joint Seminar on Fluorine Chemistry
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      2010-09-09
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Friedel-Crafts Cyclizations of Fluro Alkenes Directed toward Polycyclic Aromatic Hydrocarbon(PAH)Synthesis2010

    • Author(s)
      Ichikawa, J.
    • Organizer
      3rd Korea-Japan-China Joint Seminar on Fluorine Chemistry
    • Place of Presentation
      Daejeon, Korea
    • Year and Date
      2010-09-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] Electrophilic Activation and Cyclizatious of 1,1-Difluoroalkenes with CaNmiic Palladium(II) Catalyst2009

    • Author(s)
      H.Tanabe, T.Morikawa, D.Fujita, M.Yokota, K.Fuchibe, J.Ichikawa
    • Organizer
      The International Conference on Fluorine Chemistry'09 Kyoto
    • Place of Presentation
      京都テルサ(京都)
    • Year and Date
      2009-05-21
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Electrophilic Activation and Cyclizations of 1,1-Difluoroalkenes with Cationic Palladium(II)Catalyst2009

    • Author(s)
      H.Tanabe, T.Morikawa, D.Fujita, M.Yokota, K.Fuchibe, J.Ichikawa
    • Organizer
      The International Conference on Fluorine Chemistry '09 Kyoto
    • Place of Presentation
      (京都テルサ)京都
    • Year and Date
      2009-05-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] 1,1-ジフルオロアレンへの求核付加反応による1,1-ジフルオロ-1-アルケンの合成2009

    • Author(s)
      渕辺耕平、上田美喜子、横田実咲、市川淳士
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学(船橋)
    • Year and Date
      2009-03-29
    • Related Report
      2010 Self-evaluation Report 2008 Annual Research Report
  • [Presentation] 二価パラジウム触媒による1,1-ジフルオロ-1-アルケンの活性化:分子内環化によるオキシインドール合成2009

    • Author(s)
      田辺寛幸、市川淳士
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学(船橋)
    • Year and Date
      2009-03-29
    • Related Report
      2010 Self-evaluation Report 2008 Annual Research Report
  • [Presentation] Electrophilic Activation and Cyclizations of 1,1-Difluoroalkenes with Cationic Palladium(II) Catalyst2008

    • Author(s)
      K.Fuchibe, M.Yokota, D.Fujita, H.Tanabe, J.Ichikawa
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2008-10-29
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Electrophilic Activation and Cyclizations of 1,1-Difluoroalkenes with Cationic Palladium(II) Catalyst.2008

    • Author(s)
      K. Fuchibe, M. Yokota, D. Fujita, H. Tanabe, J. Ichikawa,
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2008-10-29
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.tsukuba.ac.jp/junji/

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.tsukuba.ac.jp/junji/

    • Related Report
      2011 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://www.chem.tsukuba.ac.jp/junji/

    • Related Report
      2010 Self-evaluation Report
  • [Remarks]

    • URL

      http://www.chem.tsukuba.ac.jp/junji/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.chem.tsukuba.ac.jp/junji/

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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