Synthetic studies on well conjugated oligocetylenes
| Project/Area Number |
20350020
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Tokyo Metropolitan University |
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Principal Investigator |
SUGIURA Ken-ichi Tokyo Metropolitan University, 理工学研究科, 教授 (60252714)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2008: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
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| Keywords | 構造有機化学 / アセチレン / 分子ワイヤー / パイ電子系 / ポルフィリン |
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| Research Abstract |
This project aimed at the synthetic studies on structurally well defined oligoacetylenes (OAs). OAs had been attracting much attention because of their simple conjugation manner of pai-electrons. However, their kinetic instability prevented the progress of this class of materials. This project adopted metalloporphyrins as the kinetic-protecting group terminating OAs. This strategy enabled to isolate a series of OAs with the number of acetylenes, 2, 4, 6, 8, and 10.
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Report
(4 results)
Research Products
(23 results)
