Approach to versatile synthesis of heterofullerenes
Project/Area Number |
20350022
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic chemistry
|
Research Institution | Institute for Molecular Science |
Principal Investigator |
SAKURAI Hidehiro Institute for Molecular Science, 分子スケールナノサイエンスセンター, 准教授 (00262147)
|
Project Period (FY) |
2008 – 2010
|
Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2010: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2009: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2008: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
|
Keywords | ヘテラフラーレン / バッキーボウル / ヘテラバッキーボウル / パラジウムクラスター / ヘテロフラーレン / トリアザスマネン / ボウル反転 / ヘテロバッキーボウル / アザノルボルナン / 求核置換反応 / S_N1反応 / マイクロ波反応 / キラルバッキーボウル / 環化三量化 / 環状トリアミド / マイクロ波 |
Research Abstract |
We succeeded in the construction of the general and versatile route to the C3 symmetric buckybowls, and in the first synthesis of nitrogen-containing heterabuckybowl "triazasumanene". These results will lead to the development of the synthesis of heterafullerenes, which are expected to the various unique properties as well as the ultimate goal for the synthestic organic chemistry.
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Report
(4 results)
Research Products
(32 results)
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[Presentation] Bowl Chirality2010
Author(s)
H.Sakurai
Organizer
6th IUPAC International Symposium on Novel Materials and their Synthesis and 20th International Symposium on Fine Chemistry and Functional Polymers
Place of Presentation
Wuhan, China(Plenary Lecture)
Year and Date
2010-10-11
Related Report
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