| Budget Amount *help |
¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
Fiscal Year 2010: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2009: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2008: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
|
|---|
| Research Abstract |
We focus on multiple bistability which has more than two thermodynamically stable phases. In this work, polynuclear complexes with multiple bistabilities were investigated in order to develop and elucidate functional materials due to spin transitions and electron transfer phenomena. Cyanide-bridged cobalt-iron complexes show electron transfer coupled spin transition in the region of room temperature. Moreover, multiple spin transitions were observed in iron(II) polynuclear system with a grid structure.
|
