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Asymmetric Catalytic Synthesis of Optically Active Organoboron Compounds with Chiral Borylcopper Species

Research Project

Project/Area Number 20350043
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionHokkaido University

Principal Investigator

ITO Hajime  Hokkaido University, 大学院・工学研究院, 教授 (90282300)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥20,020,000 (Direct Cost: ¥15,400,000、Indirect Cost: ¥4,620,000)
Fiscal Year 2010: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2008: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Keywords不斉合成 / 合成化学 / 有機化学 / 触媒・化学プロセス / 銅
Research Abstract

Novel methods for efficient synthesis of optically active organoboron compounds with chiral copper(I)-catalyst have been developed. The reactions, which include copper(I) salts and chiral phosphine ligands, promote various borylation reaction to produce optically active organoboron compounds with high enantioselectivity. This method enables the asymmetric catalytic synthesis of unprecedented chiral cyclopropyl-, ally- and homoallyboronates, which will facilitate the synthesis of intermediates for medicines.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (69 results)

All 2011 2010 2009 2008 Other

All Journal Article (24 results) (of which Peer Reviewed: 24 results) Presentation (37 results) Book (1 results) Remarks (7 results)

  • [Journal Article] Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond : Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates2011

    • Author(s)
      Sasaki, Y., Horita, Y., Zhong, C., Sawamura, M., Ito, H.
    • Journal Title

      Angew.Chem., Int.Ed.

      Volume: 50 Pages: 2778-2782

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of trans-Aryl- and -Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative2010

    • Author(s)
      Zhong C.; Kunii S.; Kosaka Y.; Sawamura M.; Ito H.
    • Journal Title

      J. Am. Chem. Soc. 132

      Pages: 11440-11440

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes : Synthesis of Enantioenriched Cyclic Homoallyl- and Allylboronates2010

    • Author(s)
      Sasaki Y.; Zhong C.; Sawamura M.; Ito H.
    • Journal Title

      J. Am. Chem. Soc. 132

      Pages: 1226-1226

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative2010

    • Author(s)
      Ito H.; Toyoda T.; Sawamura M.
    • Journal Title

      J. Am. Chem. Soc. 132

      Pages: 5990-5990

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes2010

    • Author(s)
      Ito H.; Okura T.; Matsuura K.; Sawamura M.
    • Journal Title

      Angew. Chem., Int. Ed. 49

      Pages: 560-560

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Direct Enantio-Convergent Transformation of Racemic Ssubstrates without Racemization or Symmetrization2010

    • Author(s)
      Ito H.; Kunii S.; Sawamura M.
    • Journal Title

      Nature Chemistry 2

      Pages: 972-972

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of trans-Aryl- and -Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphate s with a Diboron Derivative2010

    • Author(s)
      Zhong, C., Kunii, S., Kosaka, Y., Sawamura, M., Ito, H.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 11440-11442

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes : Synthesis of Enantioenriched Cyclic Homoallyl- and Allylboronates2010

    • Author(s)
      Sasaki, Y., Zhong, C., Sawamura, M., Ito, H.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 1226-1227

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative2010

    • Author(s)
      Ito, H., Toyoda, T., Sawamura, M.
    • Journal Title

      J.Am.Chem.Soc.

      Volume: 132 Pages: 5990-5992

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylatio n of Aldehydes2010

    • Author(s)
      Ito, H., Okura, T., Matsuura, K., Sawamura, M.
    • Journal Title

      Angew.Chem., Int.Ed.

      Volume: 49 Pages: 560-563

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct Enantio-Convergent Transformation of Racemic Substrates without Racemization or Symmetrization2010

    • Author(s)
      Ito, H., Kunii, S., Sawamura, M.
    • Journal Title

      Nature Chemistry

      Volume: 2 Pages: 972-976

    • NAID

      120002973850

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper(I)-Catalyzed Asymmetric Monoborylation of 1, 3-Dienes : Synthesis of Enantioenriched Cyclic Homoallyl- and Allylboron ates2010

    • Author(s)
      Sasaki, Y. ; Zhong, C. ; Sawamura, M. ; Ito, H.
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 1226-1227

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Desymmetrization of meso-2-Alkene-1, 4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes2010

    • Author(s)
      Ito, H. ; Okura, T. ; Matsuura, K. ; Sawamura, M
    • Journal Title

      Angew.Chem.,Int.Ed. 49

      Pages: 560-563

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Synthesis of Allenes by Cu(I)-Catalyzed Regio- and Stereoselective Reduction of Propargylic Carbonates with Hydrosilanes2009

    • Author(s)
      Zhong C.; Sasaki Y.; Ito H.; Sawamura M.
    • Journal Title

      Chem. Commun.

      Pages: 5850-5850

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Gold(I) Hydride Intermediate in Catalysis : Dehydrogenative Alcohol Silylation Catalyzed by Gold(I) Complex2009

    • Author(s)
      Ito H.; Saito T.; Miyahara T.; Zhong C.; Sawamura, M.
    • Journal Title

      Organometallics 28

      Pages: 4829-4829

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Synthesis of Allenes by Cu(I)-catalyzed Regio- and Stereoselective Reduction of Propargylic Carbonates with Hydrosilanes2009

    • Author(s)
      Zhong, C. ; Sasaki, Y. ; Ito, H. ; Sawamura, M.
    • Journal Title

      Chem.Commun.

      Pages: 5850-5852

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gold(I)Hydride Intermediate in Catalysis : Dehydrogenative Alcohol Silylation Catalyzed by Gold(I)Complex2009

    • Author(s)
      Ito, H. ; Saito, T. ; Miyahara, T. ; Zhong, C. ; Sawamura, M.
    • Journal Title

      Organometallics 28

      Pages: 4829-4840

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron : Selective Synthesis of Multisubstituted Allenylboronates2008

    • Author(s)
      Ito H.; Sasaki Y.; Sawamura M.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 15774-15774

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Mechanochromic Luminescence of [(C_6F_5Au)_2(μ-1,4-diisocyanobenzene)]2008

    • Author(s)
      Ito H.; Saito T.; Oshima N.; Kitamura N.; Ishizaka S.; Hinatsu Y.; Wakeshima M.; Kato M.; Tsuge K.; Sawamura M.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 10044-10044

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative2008

    • Author(s)
      Ito H.; Kosaka Y.; Nonoyama K.; Sasaki Y.; Sawamura M.
    • Journal Title

      Angew. Chem., Int. Ed. 47

      Pages: 7424-7424

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron : Selective Synthesis of Multi-Substituted Allenvlboronates2008

    • Author(s)
      Ito, H. ; Sasaki, Y. ; Sawamura, M.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 15774-15775

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Mechanochromic Luminescence of [(C_6F_5Au)_2(η-1, 4-diisocyanobenzene)]2008

    • Author(s)
      Ito, H. ; Saito, T. ; Oshima, N. ; Kitamura, N. ; Ishizaka, S. ; Hinatsu, Y. ; Wakeshima, M. ; Kato, M. ; Tsuge, K. ; Sawamura, M.
    • Journal Title

      J. Am. Chem. Soc. 130

      Pages: 10044-10045

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative2008

    • Author(s)
      Ito, H. ; Kosaka, Y. ; Nonoyama, K. ; Sasaki, Y. ; Sawamura, M.
    • Journal Title

      Angew. Chem., Mt. Ed. 47

      Pages: 7424-7427

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Addition of Terminal Alkynes to Aromatic Aldehydes Catalyzed by Cu(I) Complexes with Wide Bite-Angle Chiral Bisphosph ine Ligands : Optimization, Scope and Mechanistic Studies2008

    • Author(s)
      Asano, Y. ; Ito, H. ; Hara, K. ; Sawamura, M.
    • Journal Title

      Organometallics 47

      Pages: 7424-7427

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] トリエチレングリコール鎖を有する金イソシアニド錯体のメカノクロミック発光2011

    • Author(s)
      矢貝史樹, 青沼宏明, 唐津孝, 北村彰英, 大倉拓真, 榑沼紗也佳, 澤村正也, 伊藤肇
    • Organizer
      第91日本化学会春季年会
    • Place of Presentation
      神奈川大学、横浜市
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規アリール金イソシアニド錯体の合成とメカノクロミック発光2011

    • Author(s)
      室本麻衣, 澤村正也, 伊藤肇
    • Organizer
      第91日本化学会春季年会
    • Place of Presentation
      神奈川大学、横浜市
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] 銅(I)触媒によるジボロンを用いたホウ素化反応の高活性化と簡便化2011

    • Author(s)
      宮貴紀, 澤村正也, 伊藤肇
    • Organizer
      第91日本化学会春季年会
    • Place of Presentation
      神奈川大学、横浜市
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 銅(I)触媒を用いた1-シリル-2-ポリルシクロブタンの不斉合成2011

    • Author(s)
      國井峻, 澤村正也, 伊藤肇
    • Organizer
      第91日本化学会春季年会
    • Place of Presentation
      神奈川大学、横浜市
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] Asymmetric synthesis of chiral organoboron compounds through copper(I) catalysis with diboron2010

    • Author(s)
      伊藤肇
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-20
    • Related Report
      2010 Final Research Report
  • [Presentation] Asymmetric synthesis of chiral organoboron compounds through copper(I) catalysis with diboron2010

    • Author(s)
      Ito, H
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Hawaii Convention Center Honolulu, USA 招待講演
    • Year and Date
      2010-12-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mechanochromic and nonmechanochromic photoluminescence of gold(I) is ocyanide complexes2010

    • Author(s)
      Ito, H
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Hawaii Convention Center Honolulu, USA
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Cu(I)-Catalyzed Regio- and Enantioselective Monoborylation of 1,3-Dienes2010

    • Author(s)
      Sasaki, Y., Horita, Y., Sawamura, M., Ito, H
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Hawaii Convention Center Honolulu, USA
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 11 族金属触媒による有機ホウ素化合物の不斉合成反応2010

    • Author(s)
      伊藤肇
    • Organizer
      2010 年度 触媒学会北海道地区札幌講演会
    • Year and Date
      2010-12-03
    • Related Report
      2010 Final Research Report
  • [Presentation] 11族金属触媒による有機ホウ素化合物の不斉合成反応2010

    • Author(s)
      伊藤肇
    • Organizer
      2010年度触媒学会北海道地区札幌講演会
    • Place of Presentation
      北海道大学、札幌市 招待講演
    • Year and Date
      2010-12-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] 発光性金(I)イソシアニド錯体の新たな合成法とメカノクロミズム特性2010

    • Author(s)
      榑沼紗也佳, 澤村正也, 伊藤肇
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター、大阪市
    • Year and Date
      2010-09-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金(I)イソシアニド錯体の発光性メカノクロミズム:多晶性およびナノ構造との関連2010

    • Author(s)
      伊藤肇
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター、大阪市 招待講演
    • Year and Date
      2010-09-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金(I)二核錯体およびその集積錯体の吸収発光スベクトルに関する理論的研究2010

    • Author(s)
      中尾嘉秀, 山田裕, 榊茂好, 伊藤肇, 澤村正也
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター、大阪市
    • Year and Date
      2010-09-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] 銅(I)触媒よる1,3-ジエンへの位置およびエナンチオ選択的モノホウ素化反応2010

    • Author(s)
      佐々木悠祐, 澤村正也, 伊藤肇
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学多摩キャンパス八王子市
    • Year and Date
      2010-09-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 発光性金(I)イソシアニド錯体の合成とメカノクロミズム特性2010

    • Author(s)
      榑沼紗也佳, 大倉拓真, 澤村正也, 伊藤肇
    • Organizer
      第23回万有札幌シンポジウム
    • Place of Presentation
      北海道大学、札幌市
    • Year and Date
      2010-07-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] Cu(I)-catalyzed Asymmetric Synthesis of Organoboron Compounds2010

    • Author(s)
      伊藤肇
    • Organizer
      Catalytic Asymmetric Synthesis-2010
    • Place of Presentation
      Beijing, China
    • Year and Date
      2010-05-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Cu(I)-catalyzed Asymmetric Synthesis of Organoboron Compounds2010

    • Author(s)
      佐々木悠祐, 澤村正也, 伊藤肇
    • Organizer
      Catalytic Asymmetric Synthesis-2010
    • Place of Presentation
      Beijing International Convention Center、Beijing China 招待講演
    • Year and Date
      2010-05-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] 金(I)イソシアニド錯体の有機ホウ素化合物を用いた合成と発光特性2010

    • Author(s)
      榑沼紗也佳;青沼宏明;矢貝史樹;澤村正也;伊藤肇
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 銅(I)触媒を用いた不飽和有機化合物の位置選択的モノホウ素化反応2010

    • Author(s)
      堀田優子;佐々木悠祐;伊藤肇;澤村正也
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 不斉銅(I)触媒を用いた1,3-ジエン類のモノホウ素化による光学活性有機ホウ素化合物の合成2010

    • Author(s)
      佐々木悠祐;伊藤肇;澤村正也
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Controlled Solid State Luminescence of Perfluorophenylgold(I)-lsocyanide Complexes2009

    • Author(s)
      Ito, H.
    • Organizer
      International Kyoto Conference on New Aspects of Organic Chemistry(IKCOC-11)
    • Place of Presentation
      リーガロイヤルホテル(京都市)
    • Year and Date
      2009-11-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] アルコールの脱水素シリル化反応における金ヒドリド触媒中間体の生成と反応2009

    • Author(s)
      伊藤肇;齋藤智久;宮原崇泰;仲崇民;澤村正也
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学(長崎市)
    • Year and Date
      2009-09-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] 銅(I)錯体触媒を用いたメソ型アリル炭酸エステルからのアリルホウ素化合物の不斉合成2009

    • Author(s)
      大倉拓真;伊藤肇;澤村正也
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学(長崎市)
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] 銅(I)錯体触媒を用いた光学活性アリルホウ素化合物の合成とアルデヒド付加による四級不斉炭素構築2009

    • Author(s)
      國井峻;伊藤肇;澤村正也
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学(長崎市)
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] π電子系をもつ金錯体の固体状態における集積と発光機能2009

    • Author(s)
      伊藤肇
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学(長崎市)
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金(I)イソシアニド錯体の分子間相互作用と固体発光性2009

    • Author(s)
      國井峻;伊藤肇;澤村正也
    • Organizer
      九州大学先導物質化学研究所「ユビキタス情報化社会を支える光利用有機・高分子化学」
    • Place of Presentation
      九州大学(福岡県春日市)
    • Year and Date
      2009-09-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] 銅(I)触媒を用いた1-シリル-2-ホリルシクロフタンの立体選択的合成2009

    • Author(s)
      豊田昂;澤村正也;伊藤肇
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      京都大学(京都市)
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] Reversible Mechanochromic Photoluminescence and Supramolecular Structure of Au(I)-lsocyanide Complexes2009

    • Author(s)
      Ito, H.
    • Organizer
      JSPS Asian CORE Program China-Japan Joint Symposium on Functional Supramolecular Architectures
    • Place of Presentation
      アパホテル&リゾート(札幌市)
    • Year and Date
      2009-08-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] Reversible Mechanochromic Luminescence of Gold(I)lsocyanide Complex2009

    • Author(s)
      Ito, H.
    • Organizer
      18th International Symposium on the Photochemistry and Photophysics of Coordination Compounds
    • Place of Presentation
      ガトーキングダム(札幌市)
    • Year and Date
      2009-07-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] 機能性有機金属錯体:金イソシアニド錯体の発光性メカノクロミズム2009

    • Author(s)
      伊藤肇
    • Organizer
      第42回有機金属若手の会夏の学校
    • Place of Presentation
      十八楼(岐阜県湊町)
    • Year and Date
      2009-07-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] ホウ素-銅(I)反応剤を用いた1-シリル-2-ボリルシクロブタン誘導体の立体選択的合成2009

    • Author(s)
      豊田昂, 伊藤肇, 澤村正也
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋市
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 銅(I)触媒を用いたメソ型アリル炭酸ジエステルからのアリルホウ素化合物の触媒的不斉合成2009

    • Author(s)
      大倉拓真, 伊藤肇, 澤中正也
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋市
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] アリルアルコール誘導体の速度論的光学分割を経る光学活性ナーリルホウ素化合物の合成とアルデヒドへの付加による四級不斉炭素構築2009

    • Author(s)
      國井峻, 伊藤肇, 澤村正也
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋市
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 銅(I)触媒を用いたアリルおよびプロパルギルエステル類のヒドロシランによる位置選択的還元2009

    • Author(s)
      仲崇民, 伊藤肇, 澤村正也
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋市
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] 金(I)-イソシアニド錯体の発光性メカノクロミズム2008

    • Author(s)
      伊藤肇, 齋藤智久, 大島直哉, 喜多村〓, 石坂昌司, 日夏幸雄, 分島亮, 加藤昌子, 柘植清志, 澤中正也
    • Organizer
      第55回有機金属化学討論会
    • Place of Presentation
      堺市
    • Year and Date
      2008-09-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] 金(1)-イソシアニド錯体における発光性メカノクロミズムの発現2008

    • Author(s)
      伊藤肇, 齋藤智久, 大島直哉, 喜多村〓, 石坂昌司, 日夏幸雄, 分島亮, 加藤昌子, 柘植清志, 澤村正也
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢市
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] 11 族金属触媒のσ結合メタセシス反応を基軸とする合成反応2008

    • Author(s)
      伊藤肇
    • Organizer
      第25 回有機合成化学セミナー
    • Place of Presentation
      阿蘇市
    • Year and Date
      2008-09-08
    • Related Report
      2010 Final Research Report
  • [Book] 使える!有機合成反応 241 実践ガイド(丸岡啓二,野崎京子,石井康敬,大寺純蔵,富岡清 編著)2010

    • Author(s)
      澤村正也,伊藤肇
    • Publisher
      化学同人
    • Related Report
      2010 Final Research Report
  • [Remarks] ホームページ等

    • URL

      http://labs.eng.hokudai.ac.jp/labo/organoelement/

    • Related Report
      2010 Final Research Report
  • [Remarks] 新聞報道等

    • Related Report
      2010 Final Research Report
  • [Remarks] 「光学活性化合物新合成法を開発」北海道新聞2010年8月30日

    • Related Report
      2010 Final Research Report
  • [Remarks] 「ラセミ化合物から直接合成」化学工業日報2010年8月31日

    • Related Report
      2010 Final Research Report
  • [Remarks] 「直接エナンチオ収束反応の開発」北海道医療新聞2010年12月10日

    • Related Report
      2010 Final Research Report
  • [Remarks] 「北海道大学、医薬品などの開発に役立つ光学活性化合物の新合成法を開発」日経プレスリリース2010年8月30日

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://labs.eng.hokudai.ac.jp/labo/organoelement/

    • Related Report
      2010 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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